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Catalytic Reactions in Hydrogen Energy Production
Catalytic Reactions in Hydrogen Energy Production: Physicochemical Fundamentals elucidates the activation mechanism of molecular chemical bonds, the construction law of catalytic site orientation and the catalytic mechanism in the catalytic reaction processes involved in hydrogen energy production (including electrocatalysis, photocatalysis and.
Front Cover -- Catalytic Reactions in Hydrogen Energy Production -- Catalytic Reactions in Hydrogen Energy Production -- Copyright -- Contents -- I -- Hydrogen energy and electrocatalysis -- 1 -- Introduction to hydrogen energy and electrocatalysis -- 1.1 Introduction -- 1.2 Fundamental principles of electrocatalysis -- 1.3 Relationship between hydrogen energy and electrocatalysis -- 1.4 Summary -- Acknowledgments -- References -- 2 -- Basic principle of hydrogen production by electrolysis of water -- 2.1 Introduction -- 2.2 Basic principle of cathode hydrogen evolution -- 2.3 Basic principle of anodic oxygen evolution -- 2.3.1 Adsorption evolution mechanism (AEM) -- 2.3.2 Lattice oxygen mechanism (LOM) -- 2.3.3 Oxide path mechanism (OPM) -- 2.4 Basic principle of full water electrolysis -- 2.5 Summary -- Acknowledgments -- References -- 3 -- Performance evaluation of hydrogen production by electrolysis of water -- 3.1 Introduction -- 3.2 Thermodynamics and kinetics -- 3.2.1 Thermodynamics -- 3.2.1.1 Basic theories and equations -- 3.2.1.2 Thermodynamic basis of HER -- 3.2.1.3 Thermodynamic basis of OER -- 3.2.2 Kinetics -- 3.2.2.1 Kinetic basis of electrode reaction -- 3.2.2.2 Kinetic loss in electrolyzer -- 3.3 Overpotential principle and test -- 3.3.1 Overpotential principle -- 3.3.2 Overpotential test -- 3.3.2.1 Cyclic voltammetry (CV) -- 3.3.2.2 Linear sweep voltammetry (LSV) -- 3.4 Tafel curve principle and test -- 3.4.1 Tafel curve principle -- 3.4.2 Tafel curve test -- 3.5 Stability principle and test -- 3.6 Faraday efficiency (FE) -- 3.7 Turnover frequency (TOF) -- 3.8 Electrochemical impedance curve (EIS) -- 3.9 Electric double layer capacitance (Cdl) -- 3.10 Test system and three-electrode cell -- 3.11 Summary -- Acknowledgments -- References -- 4 -- Catalytic materials for electrolysis of water to hydrogen production -- 4.1 Introduction.
4.2 Cathode hydrogen evolution catalytic materials -- 4.2.1 Precious metal HER catalyst -- 4.2.2 Non-precious metal HER catalyst -- 4.3 Anodic oxygen evolution catalytic material -- 4.3.1 Basic design principles of OER electrocatalysts -- 4.3.2 Basic categories and active sites of OER electrocatalysts -- 4.3.3 Typical research cases of OER electrocatalysts -- 4.3.3.1 Ni3S2 electrocatalysts -- 4.3.3.2 LDHs electrocatalysts -- 4.3.3.3 NiCo2O4 electrocatalysts -- 4.3.3.4 Heteroatom doping electrocatalysts -- 4.4 Bifunctional catalytic materials -- 4.5 Summary -- Acknowledgments -- References -- 5 -- Design of catalytic materials for electrolysis of water -- 5.1 Introduction -- 5.2 Nanoscale design -- 5.2.1 Low dimensional nanomaterials -- 5.2.2 High-curvature nanomaterials -- 5.2.3 High-porosity nanomaterials -- 5.3 Composite interface design -- 5.4 Doping modification control -- 5.5 Vacancy defect engineering -- 5.6 Atomic structure design -- 5.7 Electronic structure regulation -- 5.7.1 Charge transfer effect -- 5.7.2 d-band center theory -- 5.7.3 Electron metal-support interaction (EMSI) -- 5.8 Summary -- Acknowledgments -- References -- 6 -- The coupling design of water electrolysis and other systems -- 6.1 Introduction -- 6.2 Coupling design of electrolytic water and organic matter oxidation -- 6.3 Coupling design of electrolytic water and gas reduction -- 6.4 Design of solar powered water electrolysis system -- 6.5 Design of wind powered water electrolysis system -- 6.6 Design of hydraulically driven electrolytic water system -- 6.7 Summary -- Acknowledgments -- References -- 7 -- Design of other electrolytic hydrogen production system -- 7.1 Introduction -- 7.2 Hydrogen production by electrolysis of sodium borohydride solution -- 7.3 Hydrogen production by electrolysis of ammonia solution -- 7.4 Hydrogen production by electrolysis of seawater.
7.5 Summary -- Acknowledgments -- References -- 8 -- Results and prospects of hydrogen energy and electrocatalysis -- 8.1 Introduction -- 8.2 Results for hydrogen energy and electrocatalysis -- 8.3 Prospects for hydrogen energy and electrocatalysis -- 8.4 Summary -- Acknowledgments -- References -- II -- Hydrogen energy and photocatalysis -- 9 -- Introduction of hydrogen energy and photocatalysis -- 9.1 Introduction -- 9.2 Research progress of photocatalysis -- 9.3 Relationship between hydrogen energy and photocatalysis -- 9.4 Summary -- Acknowledgments -- References -- 10 -- The basic principle of photocatalysis for water splitting -- 10.1 Introduction -- 10.2 Basic principles of photocatalysis -- 10.3 Basic principle of hydrogen production by photocatalytic splitting of water -- 10.4 Basic principle of photocatalytic total decomposition of water -- 10.5 Summary -- Acknowledgments -- References -- 11 -- Performance evaluation of hydrogen production by photolysis of water -- 11.1 Introduction -- 11.2 Thermodynamics and kinetic theory -- 11.2.1 Photocatalytic thermodynamics -- 11.2.2 Photocatalytic kinetics -- 11.3 Principle and evaluation of co-catalysts -- 11.4 Photocatalytic hydrogen production system and performance test -- 11.5 Stability principle and test of photocatalytic hydrogen -- 11.6 Other principle and test -- 11.7 Summary -- Acknowledgments -- References -- 12 -- Catalytic materials for photocatalysis of water splitting -- 12.1 Introduction -- 12.2 Physicochemical basis of photocatalyst -- 12.3 Visible light response catalytic materials -- 12.3.1 Basic classification and characteristics -- 12.3.2 Polymer carbon nitride for visible-light hydrogen production -- 12.3.2.1 Graphite-phase carbon nitride (g-C3N4) -- 12.3.2.2 Poly triazinimide (PTI) -- 12.3.3 Other semiconductors for visible-light hydrogen production -- 12.3.3.1 ZnIn2S.
12.3.3.2 Red phosphorus -- 12.3.3.3 MOFs -- 12.3.3.4 COFs -- 12.4 Near infrared light responsive catalytic materials -- 12.5 Co-catalyst materials for hydrogen and oxygen evolution -- 12.6 Summary -- Acknowledgments -- References -- 13 -- Design of catalytic materials for photocatalysis of water splitting -- 13.1 Introduction -- 13.2 Nanoscale design -- 13.2.1 Nano size control -- 13.2.1.1 Size effect -- 13.2.1.2 Charge separation and migration -- 13.2.1.3 Specific surface area and reactive site -- 13.2.2 Nano dimension control -- 13.2.2.1 2D/2D combination -- 13.2.2.2 Combination of other dimensions -- 13.2.3 Nano crystal face control -- 13.3 Heterogeneous structure design -- 13.3.1 Heterojunction design principle -- 13.3.2 Heterojunction basic classification -- 13.3.3 Heterojunction interfacial electric field -- 13.4 Doping modification control -- 13.5 Vacancy defect engineering -- 13.6 Atomic structure design -- 13.7 Electronic structure regulation -- 13.8 Summary -- Acknowledgments -- References -- 14 -- Results and prospects of hydrogen energy and photocatalysis -- 14.1 Introduction -- 14.2 Hydrogen energy and photocatalysis results -- 14.3 Hydrogen energy and prospects for photocatalysis -- 14.4 Summary -- Acknowledgments -- References -- III -- Hydrogen energy and thermocatalysis -- 15 -- Introduction of hydrogen energy and thermocatalysis -- 15.1 Introduction -- 15.2 Research progress of thermocatalysis -- 15.3 Relationship between hydrogen energy and thermocatalysis -- 15.4 Summary -- Acknowledgments -- References -- 16 -- Principle and catalyst of hydrogen production by water gas shift -- 16.1 Introduction -- 16.2 Basic principle of hydrogen production by water gas shift -- 16.3 Catalyst for water-gas-shift reaction -- 16.3.1 Nano catalysts -- 16.3.2 Cluster catalysts -- 16.3.3 Single atom catalysts -- 16.3.4 Mixed dimension catalysts.
16.4 Regulation and optimization of water-gas-shift reaction -- 16.4.1 Structure-activity relationship -- 16.4.2 Strong metal-support interaction -- 16.4.3 In situ characterization of catalytic mechanisms -- 16.5 Opportunities and challenges of water-gas shift reaction -- 16.5.1 Opportunities for water-gas shift reactions -- 16.5.2 Challenges for water-gas shift reactions -- 16.6 Summary -- Acknowledgments -- References -- 17 -- Principle and catalyst of methane reforming hydrogen production -- 17.1 Introduction -- 17.2 Basic principle of hydrogen production by methane reforming -- 17.2.1 Basic principle of SRM -- 17.2.2 Basic principle of DRM -- 17.2.3 Basic principle of POM -- 17.2.4 Basic principle of CDM -- 17.3 Catalyst for methane reforming reaction -- 17.3.1 Catalyst for SRM -- 17.3.2 Catalyst for DRM -- 17.3.3 Catalyst for POM -- 17.3.4 Catalyst for CDM -- 17.4 Regulation and optimization of methane reforming reaction -- 17.4.1 Design of nanostructured catalysts -- 17.4.2 Design of single atom catalysts -- 17.4.3 Plasma-assisted reforming of methane -- 17.5 Opportunities and challenges of methane reforming reaction -- 17.5.1 Opportunities -- 17.5.1.1 Abundant raw material resources -- 17.5.1.2 Relatively mature technology -- 17.5.1.3 Driven by the growing demand for hydrogen energy -- 17.5.1.4 Compatibility with existing energy infrastructure -- 17.5.2 Challenges -- 17.5.2.1 The problem of carbon emissions -- 17.5.2.2 Less efficient -- 17.5.2.3 Equipment corrosion and carbon accumulation problems -- 17.5.2.4 Pressure of competition -- 17.6 Summary -- Acknowledgments -- References -- 18 -- Principle and catalyst of methanol reforming hydrogen production -- 18.1 Introduction -- 18.2 Basic principle of hydrogen by methanol reforming -- 18.2.1 Methanol steam reforming (MSR) -- 18.2.2 Partial oxidation of methanol (POM).
18.2.3 Autothermal methanol reforming (ATMR).