Advancement in oxide utilization for li rechargeable batteries /

Oxide materials will play a significant role in the development of rechargeable batteries. They have been shown to be effective cathode materials since the 1980s, however, due to their unusual properties their use in anodes and as solid-state electrolytes has recently gathered global scientific inte...

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Bibliographic Details
Corporate Author:	Knovel (Firm)
Other Authors:	Singh, Jitendra Pal (Editor), Lee, Sangsul (Editor), Franger, Sylvain (Editor), Dixit, Ambesh (Editor)
Format:	eBook
Language:	English
Published:	Cambridge : Royal Society of Chemistry, 2025.
Series:	Sustainable Energy Series.
Subjects:	Lithium ion batteries > Materials. Oxides > Electric properties. Oxides > Industrial applications. Batteries au lithium-ion > Matériaux. Oxydes > Applications industrielles. Energy. Physical & Theoretical. Chemistry. SCIENCE. Electricity. Physics. TECHNOLOGY & ENGINEERING. Alternative & Renewable. Power Resources. Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Cover
Copyright
Preface
Contents
Section I: Introduction
Chapter 1 Section I: Introduction
1.1 Introduction
1.2 Metal Oxides in LIBs
1.2.1 Principles and Applications of LIBs
1.2.2 Electrodes Used in LIBs Consisting of Metal Oxide
1.2.2.1 Metal Oxide-based Anode Electrodes for LIBs
1.2.2.2 Thin Films on Metal Oxide Anodes
1.2.3 Metal Oxide-based Cathode Electrodes for LIBs
1.2.4 Lithium Transition Metal Oxide-based Cathodes
1.2.4.1 Surface Coatings of Li-rich Layered Oxide Cathodes
1.3 Improved Chemistry and Materials for Li-based Batteries
1.4 Conclusion
Abbreviations
References
Chapter 2 Physics and Chemistry of Li-ion Rechargeable Batteries
2.1 Journey of Li-ion Batteries
2.2 LIB Components and Materials Selection Criteria
2.2.1 LIB Components
2.2.2 Materials Selection Criteria for Electrodes and Electrolyte
2.3 Chemistry of LIBs
2.3.1 Chemistry of the Anode Materials
2.3.1.1 Graphite (Carbon-based)
2.3.1.2 Silicon (Si)
2.3.1.3 Lithium Titanate (Li4Ti5O12)
2.3.1.4 Metallic Lithium (Li)
2.3.2 Chemistry of the Cathode Materials
2.3.2.1 Lithium Cobalt Oxide (LCO/LiCoO2)
2.3.2.2 Lithium Iron Phosphate (LFPO/LiFePO4)
2.3.2.3 Lithium Manganese Oxide (LMO/LiMn2O4)
2.3.2.4 Nickel-Cobalt-Manganese (NCM) Based Cathode Materials
2.3.3 Transport of Li+ Across the Electrolyte and Separator
2.4 Physics of Li-ion Batteries
2.4.1 Electrochemical Potential of Electrodes and Open Circuit Voltage (OCV)
2.4.2 Diffusion and Migration
2.4.3 Theoretical Capacity or Energy Density
2.5 Types of Cells Used So Far in LIB Technology
2.6 Physics and Chemistry of Electrochemical Performance Degradation Factors
2.7 Major Challenges and Future Prospects of LIBs
2.8 Conclusion
Acknowledgments
References
Chapter 3 Lithium-based All-solid-state Thin-film Micro-batteries
3.1 Introduction
3.2 The Development of the All-solid-state Battery
3.3 Fabrication Process for TFBs
3.3.1 Sputtering
3.3.2 Evaporation
3.3.3 Pulsed Laser Deposition (PLD)
3.3.4 Chemical Vapour Deposition (CVD)
3.3.5 Atomic Layer Deposition (ALD)
3.3.6 Electrodeposition
3.3.7 Hydrothermal
3.3.8 Sol-Gel
3.3.9 Solvent Casting
3.3.10 Patterning
3.3.11 Wet Etching
3.3.12 Dry Etching
3.3.13 Lift-off
3.4 Design Considerations
3.4.1 2D and 3D Lateral Cell
3.4.2 2D and 3D Vertical Cell
3.4.3 Cell Stacking
3.5 Materials for Thin-film Batteries
3.5.1 Physics of Electrodes
3.5.1.1 Thermodynamics for Insertion and Alloying Electrodes
3.5.1.2 Ion Diffusion in Solids
3.5.1.3 Electron Conduction in Solids
3.5.1.4 Ion-transfer and Electron-transfer Reaction
3.5.2 Cathode Materials
3.5.2.1 LiCoO2 (LCO)
3.5.2.2 LiFePO4 (LFP)
3.5.2.3 LiMn2O4
3.5.2.4 LiNiO2
3.5.2.5 LiVxOy
3.5.2.5.1 LiV3O8
3.5.2.5.2 LiV2O5
3.5.2.6 LixMoO3
3.5.2.7 Conclusion on Cathode Materials for TFBs