Lignin-drivin advanced materials : the state-of-the art.
Lignin-driven Advanced Materials: The State-of-the-Art offers a pioneering approach to address the multifaceted challenges in the production of lignin-derived materials.This comprehensive book covers the creation of value-added products such as carbon materials, nanoparticles, energy storage materia...
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| Format: | eBook |
| Language: | English |
| Published: |
[S.l.] :
Elsevier,
2025.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Front Cover
- Lignin-Driven Advanced Materials: The State-of-the-Art
- Copyright Page
- Contents
- List of contributors
- Preface
- 1 Lignin: the fundamentals
- 1.1 Introduction
- 1.2 Chemical composition of lignin
- 1.2.1 Phenolic lignin
- 1.2.2 Catechyl lignin
- 1.3 Lignin variations in plant species
- 1.4 Structural characteristics of the macromolecular architecture of lignin
- 1.5 Lignin biosynthesis
- 1.5.1 Phenylpropanoid pathway
- 1.5.2 Genetic regulation
- 1.6 Monomeric building blocks of lignin
- 1.7 Properties of structural functionality of lignin
- 1.8 Conclusions
- Acknowledgments
- References
- 2 Pretreatment methods for lignin fractionation
- 2.1 Introduction
- 2.2 Overview of pretreatment techniques for lignin extraction
- 2.3 Physical pretreatment methods
- 2.4 Chemical pretreatment methods
- 2.4.1 Acid-based pretreatments
- 2.4.2 Alkali-based pretreatments
- 2.4.3 Solvent-based pretreatment
- 2.4.3.1 Organosolv pretreatment
- 2.4.3.2 Deep eutectic solvent pretreatments
- 2.4.3.3 Ionic liquid pretreatments
- 2.5 Physico-chemical pretreatment methods
- 2.6 Challenges and limitations in pretreatment for lignin extraction
- 2.7 Future perspectives in lignin extraction pretreatment
- 2.8 Conclusions
- References
- 3 Advanced analytical tools for lignin characterization
- 3.1 Introduction to lignin characterization
- 3.2 Traditional analytical methods for lignin characterization
- 3.2.1 Lignin content and functional group abundance determination
- 3.2.2 Wet chemical methods
- 3.3 Spectroscopic techniques
- 3.3.1 Infrared spectroscopy
- 3.3.2 Ultraviolet-visible absorption spectroscopy
- 3.3.3 Raman spectroscopy
- 3.3.4 Nuclear magnetic resonance spectroscopy
- 3.4 Chromatographic techniques
- 3.4.1 Gel permeation chromatography
- 3.4.2 Gas chromatography
- 3.4.3 Liquid chromatography.
- 3.5 Pyrolysis techniques
- 3.5.1 Pyrolysis-gas chromatography/mass spectrometry
- 3.5.2 Thermal analysis
- 3.6 Imaging techniques
- 3.6.1 Electron microscopy
- 3.6.2 Fluorescence microscopy
- 3.6.3 Combination of spectroscopic techniques and microscopy
- 3.7 Advanced computational approaches
- 3.7.1 Lignin model based on deduction
- 3.7.2 Lignin model based on statistical simulation
- 3.7.3 Lignin model based on molecular simulation
- 3.8 Emerging technologies and future perspectives
- 3.8.1 Coherent anti-Stokes Raman scattering microscopy
- 3.8.2 Stimulated Raman scattering microscopy
- 3.8.3 Advanced solid-state nuclear magnetic resonance
- 3.8.4 Operando spectroscopy
- 3.9 Conclusion
- References
- 4 Requirements and features of lignin for advanced materials
- 4.1 Introduction
- 4.2 Physicochemical properties of lignin
- 4.2.1 Molecular weight
- 4.2.2 Glass transition temperature
- 4.2.3 Thermal decomposition
- 4.2.4 Solubility
- 4.2.5 Ultraviolet resistance and antioxidant properties
- 4.2.5.1 Ultraviolet resistance
- 4.2.5.2 Antioxidant properties
- 4.3 Influence of extraction method on physicochemical properties
- 4.3.1 Sulfur-containing lignin
- 4.3.1.1 Kraft lignin
- 4.3.1.2 Lignosulfonates
- 4.3.2 Sulfur-free lignin
- 4.3.2.1 Organosolv lignin
- 4.3.2.2 Alkali lignin
- 4.4 Lignin modification and functionalization for advanced materials
- 4.4.1 Esterification
- 4.4.2 Urethanization
- 4.4.3 Amination
- 4.4.4 Phenolization
- 4.5 Lignin value-added materials
- 4.6 Outlook and features
- 4.7 Conclusion
- References
- 5 Lignin-based carbon fiber
- 5.1 Introduction
- 5.2 Carbon fibers and lignin-based carbon fibers
- 5.3 Lignin production from lignocellulose biomass and pretreatment approaches
- 5.3.1 Chemical pretreatment
- 5.3.2 Physicochemical treatment
- 5.3.3 Biological treatment.
- 5.4 Formation of lignin-based carbon fibers
- 5.4.1 Spinning processing of lignin
- 5.4.1.1 Electrospinning
- 5.4.1.2 Chemical vapor deposition method
- 5.4.2 Stabilization step
- 5.4.3 Carbonization step
- 5.4.4 Graphitization and surface treatment
- 5.5 Applications of lignin-based carbon fibers and lignin-based carbon nanofibers
- 5.5.1 Energy storage field
- 5.5.2 Heat resistant products
- 5.5.3 Environmental fields
- 5.6 Some considerations regarding the lignin carbon fiber products
- 5.6.1 Environmental consideration
- 5.6.2 Enhancement of lignin purity
- 5.6.3 Development of the pipeline steps and scalability
- 5.6.4 Construction of new scientific significance
- 5.6.5 Required properties
- 5.7 Conclusion
- References
- 6 Lignin-based antimicrobial materials
- 6.1 Introduction
- 6.2 Potential of lignin as an antimicrobial agent
- 6.2.1 Lignin as a sustainable alternative to conventional metal-based compounds
- 6.2.2 Antimicrobial mechanism, activity, and determination methods
- 6.2.2.1 Agar diffusion
- 6.2.2.2 Broth microdilution
- 6.2.2.3 Agar dilution
- 6.2.3 Factors influencing the antimicrobial activity of lignin
- 6.2.3.1 Source and extraction methods
- 6.2.3.2 Influence of functional groups
- 6.2.3.3 Zeta potential
- 6.2.3.4 Bacterial structures
- 6.2.4 Antiviral properties of lignin
- 6.3 Utilization of lignin-based materials
- 6.3.1 Food packaging
- 6.3.2 Medical devices and implants
- 6.3.3 Wound healing and infection control
- 6.3.4 Water treatment and purification
- 6.4 Conclusion and future direction
- Acknowledgments
- References
- 7 Lignin-based rechargeable batteries and supercapacitors
- 7.1 Introduction
- 7.2 Lignin in nature and industry
- 7.2.1 Electrochemical properties of lignin
- 7.3 Applications of lignin-based batteries
- 7.3.1 Lignin-based materials in the anode.
- 7.3.2 Lignin-based materials in the cathode
- 7.3.3 Lignin-based polymer in the electrolyte
- 7.3.4 Lignin-based binder
- 7.3.5 Lignin-based separator
- 7.3.6 Lignin-based supercapacitor electrodes
- 7.4 Conclusion
- References
- 8 Lignin-based films and coatings
- 8.1 Introduction
- 8.2 Properties of lignin relevant to film and coating applications
- 8.2.1 Thermal stability and mechanical properties of lignin
- 8.2.2 Barrier and functional properties of lignin
- 8.3 Applications of lignin-based films and coatings
- 8.3.1 Packaging materials for food products
- 8.3.2 Biodegradable mulches and agricultural films
- 8.3.3 Surface coatings for wood and composites
- 8.3.4 Biomedical and pharmaceutical applications
- 8.3.5 Textile industries
- 8.4 Environmental benefits and challenges
- 8.4.1 Carbon footprint reduction for sustainability
- 8.4.2 Biodegradability and end-of-life considerations
- 8.4.3 Challenges and limitations in commercialization
- 8.5 Future prospects and emerging trends
- 8.5.1 Advances in lignin modification techniques
- 8.5.2 Integration with nanotechnology and other polymers
- 8.5.3 Market outlook and potential growth areas
- 8.6 Conclusion
- References
- 9 Lignin-based composites
- 9.1 Introduction
- 9.2 Lignin modification for composite applications
- 9.3 Lignin-based composites: development and benefits
- 9.3.1 Early research and exploration
- 9.3.2 Advances in lignin isolation and purification
- 9.3.3 Development of thermoplastic and thermoset lignin composites
- 9.3.4 Benefits of lignin in composites
- 9.4 Properties of lignin composites
- 9.5 Processing of lignin composites
- 9.5.1 Mixing methods
- 9.5.2 Fabrication techniques
- 9.5.3 Advancements in processing and functionalization
- 9.6 Applications of lignin-based composites
- 9.7 Commercialization and industrial applications.
- 9.7.1 Current commercial products and market
- 9.7.2 Challenges and strategies for commercialization
- 9.7.3 Emerging industrial applications
- 9.8 Future perspectives and challenges
- 9.8.1 Emerging trends and research directions
- 9.8.2 Technological and economic challenges
- 9.8.3 Environmental and sustainability considerations
- 9.9 Conclusions
- References
- 10 Lignin-based hydrogels, aerogels, and adhesives
- 10.1 Introduction
- 10.2 Synthesis of lignin-based hydrogels
- 10.2.1 Synthesis of lignin-based hydrogels
- 10.2.2 Biomedical applications of lignin-based hydrogels
- 10.2.3 Cross-linking strategies
- 10.3 Lignin-based aerogels: fabrication and characterization
- 10.3.1 Sol-gel processing of lignin aerogels
- 10.3.2 Structural characterization techniques
- 10.3.3 Thermal and mechanical properties of lignin aerogels
- 10.4 Adhesive formulations using lignin
- 10.4.1 Lignin as a bio-based adhesive component
- 10.4.2 Bonding mechanisms and strength
- 10.4.2.1 Several factors influence the bonding strength of lignin-based adhesives Lignin type
- 10.4.2.1.1 Lignin type
- 10.4.2.2 Modification methods
- 10.4.2.3 Application conditions
- 10.4.3 Lignin-based additives: a sustainable alternative
- 10.4.4 Applications of lignin-based additives
- 10.5 Challenges and future directions
- 10.6 Conclusions
- References
- 11 Lignin-based thermoplastic
- 11.1 Introduction
- 11.2 Lignin-based thermoplastic: fabrication and characterization
- 11.2.1 Lignin-based renewable epoxy resin synthesis
- 11.2.2 Lignin-based green polyurethanes and polyesters synthesis
- 11.2.3 Thermal and mechanical properties of lignin thermoplastic
- 11.3 Applications of lignin-based thermoplastic
- 11.3.1 Lignin as a vital thermoplastic for electric vehicle/tractor supplies
- 11.3.2 Lignin as a vital thermoplastic for packaging materials.