http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Advances in Heterocyclic Chemistry series, highlights new advances in the field, with this new volume presenting interesting chapters. Each chapter is written by an international board of authors.- Provides the latest information on heterocyclic chemistry research- Offers outstanding and original reviews on a range of heterocyclic chemistry research topics- Serves as an indispensable reference for researchers and students alike.
Intro -- Advances in Heterocyclic Chemistry -- Copyright -- Contents -- Contributors -- Preface -- Chapter One: The chemistry and application of benzo[b]phosphole oxides -- 1. Introduction -- 2. Structure -- 3. Properties -- 3.1. General properties -- 3.2. Electronic properties -- 3.3. Molecular structures -- 3.4. Photophysical properties -- 3.4.1. Absorbance -- 3.4.2. Fluorescence in solution -- 3.4.3. Fluorescence in the solid state -- 3.5. Electrochemical properties -- 3.6. Photochromism -- 4. Synthetic approaches to 2,3-disubstituted benzo[b]phosphole oxides -- 4.1. [4+1] Cycloaddition -- 4.2. Intramolecular cyclization -- 4.3. [3+2] Approaches -- 4.4. One-pot multicomponent reaction using organometallic reagents -- 4.5. Direct ortho-alkenylation and cyclization of arylthiophoshinamides -- 4.6. Catalytic cross-coupling reactions -- C-H bond activation reactions -- 4.8. Radical addition/cyclization -- 4.9. Other methods -- 5. Synthesis of 2-substituted benzo[b]phosphole oxides -- 5.1. Intramolecular cyclization -- 5.2. Catalytic cross-coupling reactions -- 5.3. Other methods -- 6. Synthesis of 3-arylbenzo[b]phosphole oxides -- 6.1. Suzuki-Miyaura cross-coupling -- Double C-P bond formation -- 6.3. Cu-mediated intramolecular cyclization -- 7. Synthesis of 1-phenylbenzo[b]phosphole oxide -- 7.1. Diels-Alder reactions -- 7.2. Phospha-Friedel-Crafts cyclization -- 7.3. [4+1] Approaches -- 7.4. Ring-closing metathesis (RCM) -- 7.5. 2-Silyl group removal -- 7.6. Ag-promoted radical cycloisomerization -- 8. Reactivity of benzo[b]phosphole oxides -- 8.1. Functionalization at the phosphorus atom -- 8.2. Halogenation -- C-H bond activation -- 8.4. Friedel-Crafts reaction -- 8.5. Ring-closing metathesis (RCM) -- 8.6. Ring opening -- 8.7. Cycloaddition reactions -- 8.8. Other reactions -- 9. Applications -- 9.1. Fluorescent dyes.
9.2. Optoelectronic and photovoltaic devices -- 9.3. Synthesis of metal complexes -- 9.4. Synthesis of polymers -- 9.5. Ligands in asymmetric synthesis -- 10. Conclusions -- Acknowledgments -- References -- Chapter Two: The Thorpe-Ziegler reaction: A powerful strategy for the synthesis of heterocycles -- 1. Introduction -- 2. The Thorpe-Ziegler Reaction -- 2.1. Synthesis of five-membered heterocycles -- 2.2. Synthesis of six-membered heterocycles -- 2.3. Synthesis of seven-membered heterocycles -- 3. Conclusion -- Acknowledgment -- References -- Chapter Three: N-Bridgehead pyrrolodiazines (1998-2023) -- 1. Introduction -- 2. Pyrrolo[1,2-b]pyridazines -- 2.1. Syntheses starting from pyrroles -- 2.2. Syntheses starting from pyridazines -- 2.2.1. From pyridazines and acetylenic esters -- 2.2.2. From hydrogenated pyridazine and cyclopropanes -- 2.2.3. From pyridazine and alkylidenecyclopropanes -- 2.2.4. From pyridazines and cyclopropenones -- 2.2.5. Electrooxidation of 2-substituted pyridazine -- 2.2.6. From pyridazines and spirocyclopropenes -- 2.2.7. The [3+2] cycloaddition reaction of mesoionic oxazolo[3,2-b]pyridazines -- 2.2.8. Intramolecular cyclization of tetrahydropyridazines -- 2.2.9. [3+2] Cycloaddition reaction of pyridazinium N-ylides to olefinic and acetylenic dipolarophiles -- 2.2.9.1. From perfluoroalkanes -- 2.2.9.2. From activated alkenes -- 2.2.9.3. From alkynes -- 2.3. Miscellaneous pyrrolo[1,2-b]pyridazine syntheses -- 2.4. Applications -- 3. Pyrrolo[1,2-a]pyrimidines -- 3.1. Syntheses from pyrroles -- 3.2. Syntheses from pyrimidines -- 3.3. Syntheses from heterocyclic ketene aminals -- 3.4. Retro Diels-Alder reaction -- 3.5. Miscellaneous syntheses -- 3.6. Naturally occurring pyrrolo[1,2-a]pyrimidines -- 3.7. Applications -- 4. Pyrrolo[1,2-c]pyrimidines -- 4.1. Syntheses from pyrroles -- 4.1.1. From pyrroles.
5.7.6. Amination of pyrrolo[1,2-a]pyrazines -- 5.7.7. Metallation -- 5.7.8. Pyrrolo[1,2-a]pyrazines as dipolarophiles -- 5.7.9. Reaction with activated alkynes -- 5.7.10. Reaction with polysulfur heterocycles -- 5.7.11. Condensation with amines -- 5.7.12. Oxidation -- 5.8. Applications -- 5.9. Naturally occurring pyrrolo[1,2-a]pyrazines -- 5.9.1. Bicyclic 2,5-diketopiperazine alkaloids -- 5.9.2. Bicyclic monoketopiperazine(pyrroloketopiperazine) alkaloids -- References -- Chapter Four: Se NMR spectroscopy of selenium adducts of N-heterocyclic carbenes -- 1. Introduction -- 2. Overview of probes for characterization of electronic properties of NHCs -- 2.1. Tolman electronic parameter (TEP) -- 2.2. Huynh electronic parameter (HEP) -- 2.3. Carbene relative energy of formation (CREF) -- 2.4. P NMR spectroscopy of carbene-phosphinidene adducts -- 2.5. JC,Se coupling constants -- 2.6. Additional methods for the characterization of electronic properties of NHCs -- 3. The characterization of NHCs by means of Se NMR spectroscopy -- 3.1. General aspects -- 3.2. The influence of the referencing method -- 3.3. Solvent effects on Se NMR resonance frequencies of NHC-selenium adducts -- 3.4. Influence of the concentration of the solute on the Se NMR chemical shifts -- 3.5. Temperature dependence of Se NMR chemical shifts -- 3.6. Dependence of the Se NMR shifts on the pH value -- 3.7. Substituent effects on the Se NMR resonance frequencies -- 3.7.1. Sterically demanding substituents -- 3.7.2. Conjugation -- 3.7.3. Cationic N-heterocyclic carbenes -- 3.7.4. Anionic N-heterocyclic carbenes -- 4. Se NMR resonance frequencies of selenoethers and selenenyls -- 5. Conclusion -- 6. Tabular compilation of spectroscopic data of selenones of N-heterocyclic carbenes -- References -- Index.
Eric F. V. Scriven and Christopher A. Ramsden.
Includes bibliographical references and index.
Advances in Heterocyclic Chemistry Series