http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Higee Chemical Reaction Engineering systematically discusses the fundamentals, principles, and methods of molecular mixing and reaction process intensification. The book demonstrates the implementation approach, process, and effectiveness of Higee chemical reaction engineering through novel industrial case studies that help industrial technicians select reaction intensification technology route more scientifically. Sections cover the innovation and development process of Higee chemical reaction engineering, hydrodynamics behavior in Higee reactors, equipment design principles and methods, multiphase reaction of liquid-liquid, gas-liquid, gas-solid, gas-liquid-solid and reactive crystallization process intensification principles and effectiveness. Higee Chemical Reaction Engineering is a systematic summary of several national award and key projects, such as the State Technological Innovation Award, State Science and Technology Advancement Award, National Natural Science Foundation of China, National key R&D Program of China, National ''863'' Program of China, National ''973'' Program of China, and also some international cooperation.
Intro -- Higee Chemical Reaction Engineering -- Copyright -- Contents -- About the author -- Preface -- Chapter 1: Introduction to high-gravity reaction engineering -- 1.1. Introduction to chemical reaction engineering -- 1.2. High-gravity intensification technology -- 1.3. High-gravity reaction engineering -- 1.3.1. Creating cross-scale molecular reaction engineering model and proposing new way to intensify high-gravity reaction -- 1.3.2. Establishing scientific scale-up method for high-gravity reactor and making breakthroughs in key technology for la ... -- 1.3.3. Creating series of new high-gravity intensification technologies and achieving scale-up applications -- 1.3.3.1. New high-gravity technology for multiphase reaction enhancement and industrial applications -- 1.3.3.2. New high-gravity technology for reactive crystallization and industrial applications -- 1.4. Future development -- 1.4.1. Application of high-gravity process intensification technology in industrial catalysis -- 1.4.2. Application of high-gravity process intensification technology in polymerization reaction -- 1.4.3. Application of high-gravity intensification technology in intrinsic safety and process reengineering in chemical p ... -- 1.4.4. Application of high-gravity intensification technology in preparation of nanomaterial and nanodispersion -- References -- Chapter 2: Hydrodynamic behavior in high-gravity reactors -- 2.1. Phenomenon and description of fluid flow in high-gravity reactors -- 2.1.1. Flow pattern of fluid in the packing -- 2.1.2. Uneven distribution of liquid in the packing -- 2.1.3. Flow pattern of liquid in the cavity area -- 2.2. Characteristic parameters of fluid flow in high-gravity reactors -- 2.2.1. Characteristics of liquid flow in RPB -- 2.2.1.1. Flow characteristics of droplets in the packing area -- Droplet diameter in the packing area.
Droplet flight time and velocity in the packing area -- 2.2.1.2. Liquid line flow characteristics in the packing area -- The number of liquid lines in the packing area -- Line speed and diameter of liquid in packing area -- 2.2.1.3. Flow characteristics of liquid film in the packing area -- Thickness of liquid film on packing surface -- Thickness of liquid film in packing space -- 2.2.1.4. Droplet diameter in the cavity area -- 2.2.1.5. Droplet velocity in the cavity area -- 2.2.2. Characteristics of gas-phase flow in RPB -- 2.2.2.1. Establishment of the gas-phase flow field simulation method -- 2.2.2.2. Dry bed pressure drop -- 2.2.2.3. Wet-bed pressure drop -- 2.3. Liquid holdup in high-gravity reactor -- 2.3.1. Overview of liquid holdup and measurement methods -- 2.3.2. Research on liquid holdup in RPB -- 2.4. The residence time of liquid in a high-gravity reactor -- References -- Chapter 3: Design principles and methods of high-gravity reactor -- 3.1. General design information of high-gravity reactor -- 3.2. Structural design of high-gravity reactor -- 3.2.1. Determination of the geometric dimensions of the main components -- 3.2.1.1. Gas-liquid inlet and outlet pipe diameters -- 3.2.1.2. Form and size of spray pipe -- 3.2.1.3. Dimensions of the packing bed layer -- Determination of the inner radius -- Determination of bed height -- Determination of the outer radius -- 3.2.2. Structural design and strength calculation of the drum -- 3.2.2.1. Structural design of rotating drum -- 3.2.2.2. Strength calculation of drum -- Strength calculation of a cylindrical open drum -- Strength calculation of a squirrel cage drum -- 3.2.3. Comparison of the two forms of drums -- 3.3. High-gravity reactor power calculation -- 3.3.1. Liquid dumping power -- 3.3.2. Gas resistance losses -- 3.3.3. Mechanical losses -- 3.4. High-gravity reactor structure.
3.4.1. Development of high-gravity equipment structure -- 3.4.2. New high-gravity equipment -- 3.4.2.1. Liquid-liquid premixed high-gravity equipment -- 3.4.2.2. Gas-liquid high-efficiency high-gravity equipment -- Guided plate type high-gravity equipment -- Built-in high-gravity equipment with baffle ring -- Segmented feed type high-gravity equipment -- 3.4.2.3. Multistage counterflow high-gravity equipment -- References -- Chapter 4: Liquid-liquid reaction system enhancement by high-gravity and engineering application -- 4.1. Molecular mixtures and their modeling -- 4.1.1. The concept of molecular mixing and microscopic visualization -- 4.1.2. Experimental study on molecular mixing -- 4.1.2.1. Experimental research system -- 4.1.2.2. Molecular mixing efficiency of high-gravity reactor -- Determination of molecular mixing efficiency by azotization experimental system -- Measuring molecular mixing efficiency by iodide-iodate experimental system -- 4.1.2.3. Effect of macro mixing on molecular mixing -- 4.1.2.4. Molecular mixing characteristic time -- 4.1.3. Molecular mixing model of high-gravity reactor -- 4.1.3.1. Molecular mixing model in high-gravity environment -- 4.1.3.2. Molecular mixing reaction coupling model in high-gravity environment -- 4.2. Enhancement of high-gravity condensation reaction and industrial application -- 4.2.1. Overview of condensation reaction -- 4.2.2. New process of high-gravity condensation reaction -- 4.2.2.1. Effect of rotation speed of high-gravity reactor on feedstock conversion and target product yield -- 4.2.2.2. Effect of molar ratio of aldehyde to ketone on feedstock conversion and target product yield -- 4.2.2.3. Effect of molar ratio of aldehyde to alkali on feedstock conversion and target product yield -- 4.2.2.4. Effect of molar ratio of aldehyde to alcohol on feedstock conversion and target product yield.
4.2.2.5. Effect of reaction temperature on feedstock conversion and target product yield -- 4.2.3. Industrial application and effectiveness -- 4.3. Enhancement of high-gravity sulfonation reaction and industrial application -- 4.3.1. Overview of sulfonation reaction -- 4.3.2. New process of high-gravity sulfonation reaction -- 4.3.2.1. High-gravity liquid-liquid sulfonation method with fuming sulfuric acid as sulfonating agent -- Effect of rotation speed on sulfonation process -- Effect of mass ratio of solvent to distillate oil -- Effect of mass ratio of sulfonating agent to distillate oil -- Effect of reaction temperature -- Effect of reaction time -- 4.3.2.2. High-gravity liquid-liquid sulfonation method with liquid sulfur trioxide as sulfonating agent -- Effect of rotation speed -- Effect of mass ratio of solvent to distillate oil -- Effect of the mass ratio of sulfonating agent to distillate oil -- Effect of reaction temperature -- Effect of reaction time -- 4.3.2.3. Industrial application and effectiveness -- 4.4. High-gravity enhanced polymerization -- 4.4.1. Overview of polymerization -- 4.4.2. New process of high-gravity enhanced polymerization -- 4.4.2.1. New polymerization process of high-gravity reinforced butyl rubber -- 4.4.2.2. Influence of different process conditions on polymerization reaction -- Effect of temperature on polymerization reaction -- Effect of rotation speed on polymerization reaction -- Effect of packing layers on polymerization process -- Effect of monomer flow rate on polymerization process -- Effect of catalyst concentration on IIR molecular weight and molecular weight distribution -- Effect of isobutene concentration on IIR molecular weight and molecular weight distribution -- Effect of isoprene concentration on molecular weight and molecular weight distribution of IIR.
Effect of monomer to catalyst flow ratio on IIR molecular weight and molecular weight distribution -- 4.4.2.3. Comparison between the new process of high-gravity polymerization enhancement and the traditional process -- 4.5. Enhancement of high-gravity alkylation reaction -- 4.5.1. Overview of alkylation reaction -- 4.5.2. New process of high-gravity alkylation reaction enhancement -- 4.5.2.1. C4 alkylation catalyzed by chloroaluminate ionic liquid enhanced by high-gravity -- 4.5.2.2. High-gravity enhanced concentrated sulfuric acid catalyzed C4 alkylation -- 4.6. Enhanced halogenation reaction by high-gravity technology -- 4.6.1. Introduction of halogenation reaction -- 4.6.2. The new process for high-gravity technology enhanced halogenation reaction -- References -- Chapter 5: Reaction enhancement and industrial application of high-gravity technology in gas-liquid system -- 5.1. Mass transfer behavior and modeling in high-gravity reactor -- 5.1.1. Research on gas-liquid mass transfer behavior in high-gravity reactor -- 5.1.2. Modeling of mass transfer behavior in high-gravity reactor -- 5.1.2.1. Classical theoretical model of gas-liquid mass transfer -- Two-film theory -- Solute permeation theory -- Surface renewal theory -- 5.1.2.2. Variable droplet size mass transfer model for low-viscosity system -- 5.1.2.3. Surface renewal mass transfer model for medium-viscosity system -- 5.1.2.4. Liquid film mass transfer model for high-viscosity system -- 5.1.3. CFD simulation of gas-liquid two-phase flow in high-gravity reactor -- 5.1.3.1. Physical model and grid division -- 5.1.3.2. Calculation model and parameter setting -- 5.1.3.3. Boundary conditions -- 5.1.3.4. Simulation results -- 5.2. High-gravity reaction absorption technology -- 5.2.1. Removal of CO2 by high-gravity reaction -- 5.2.1.1. Research progress of high-gravity decarbonization process.