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Nonequilibrium thermodynamics : transport and rate processes in physical, chemical and biological systems /

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This fully updated and revised fifth edition of Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical, and Biological Systems emphasizes the unifying role of thermodynamics and their use in transport processes and chemical reactions in physical, chemical, and biological s...

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Bibliographic Details
Main Authors: Demirel, Yaşar, Gerbaud, Vincent (Author)
Corporate Author: ScienceDirect (Online service)
Format: eBook
Language:English
Published: Amsterdam : Elsevier, [2025].
Edition:Fifth edition
Subjects:
Nonequilibrium thermodynamics.
Rate processes.
Transport theory.
Chemical systems.
Biological systems.
Thermodynamique irréversible.
Vitesse des processus (Théorie quantique)
Théorie du transport.
Systèmes chimiques.
Systèmes biologiques.
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Front Cover
  • Nonequilibrium Thermodynamics
  • Nonequilibrium Thermodynamics Transport and Rate Processes in Physical, Chemical and Biological Systems
  • Copyright
  • Dedication
  • Contents
  • Preface to the fifth edition
  • Preface to the fourth edition
  • List of symbols
  • 1
  • Fundamentals of thermodynamics
  • 1 . Fundamentals of equilibrium thermodynamics
  • 1.1 Introduction
  • 1.2 Basic definitions
  • 1.2.1 Systems
  • 1.2.1.1 Systems with microscopic and macroscopic states
  • 1.2.2 Process
  • 1.2.3 Reversible and irreversible processes
  • 1.2.3.1 Some properties of reversible processes
  • 1.2.3.2 Some properties of irreversible processes
  • 1.2.4 Thermodynamic properties
  • 1.2.5 Time derivative of thermodynamic properties
  • 1.2.5.1 Total differential
  • 1.2.5.2 Substantial derivative
  • 1.2.6 Energy
  • 1.2.7 Entropy
  • 1.2.7.1 Boltzmann entropy
  • 1.2.7.2 Gibbs entropy
  • 1.2.8 Equilibrium and stability
  • 1.2.8.1 Various equilibrium states
  • 1.2.9 Arrow of time
  • 1.2.10 Thermodynamic potentials
  • 1.2.11 Statistical ensembles
  • 1.2.12 Chemical potential
  • 1.2.12.1 Chemical potential of nonideal solutions
  • 1.2.12.2 Gradient of chemical potential at constant temperature
  • 1.2.13 Chemical affinity
  • 1.2.14 Joule-Thomson coefficient
  • 1.2.15 Maxwell relations
  • 1.3 Change in thermodynamic properties
  • 1.3.1 Thermal expansion
  • 1.3.2 Isothermal compressibility
  • 1.3.3 Changes in enthalpy, entropy, and volume in terms of temperature and pressure
  • 1.3.4 Change of internal energy and entropy in terms of temperature and volume
  • 1.4 Entropy changes
  • 1.4.1 Throttling process
  • 1.4.2 Entropy change of an ideal gas
  • 1.4.2 Entropy change of an ideal gas
  • 1.4.3 Entropy change of phase transformation
  • 1.4.4 Entropy change of expansion of a real gas
  • 1.4.5 Entropy change in a two-compartment system.
  • 1.5 Transforming thermodynamic derivatives
  • 1.6 The thermodynamic laws
  • 1.6.1 The zeroth law of thermodynamics
  • 1.6.2 The first law of thermodynamics
  • 1.6.3 The second law of thermodynamics
  • 1.7 Balance equations
  • 1.7.1 Mass balance
  • 1.7.2 Energy balance
  • 1.7.3 Entropy balance
  • 1.8 Euler's theorem
  • 1.9 The Gibbs equation
  • 1.9.1 Gibbs-Duhem relations
  • 1.9.2 Gibbs energy for irreversible process
  • 1.10 Legendre transformations
  • 1.11 The fundamental equations
  • 1.12 Fluid phase equilibrium
  • 1.12.1 The phase rule
  • 1.12.2 The Clapeyron equation
  • 1.12.3 Excess thermodynamic properties
  • 1.12.4 Residual properties
  • 1.12.5 Mixing functions
  • 1.12.6 Fugacity
  • 1.12.7 Activity coefficient models
  • 1.12.8 Vapor-liquid equilibria
  • 1.12.9 Henry's law
  • 1.12.10 Equations of state
  • 1.12.10.1 Intermolecular forces
  • 1.12.11 Virial equation of state
  • 1.12.12 Cubic equations of state
  • 1.12.13 Azeotropes
  • 1.12.13 Azeotropes
  • 1.12.14 Osmotic equilibrium
  • 1.12.15 Generalized correlations for gases
  • Problems
  • References
  • Further reading
  • 2 . Fundamentals of nonequilibrium thermodynamics
  • 2.1 Introduction
  • 2.2 Nonequilibrium systems
  • 2.2.1 Thermodynamic branch
  • 2.2.2 Local thermodynamic equilibrium
  • 2.3 Balance equations
  • 2.3.1 The mass balance equations
  • 2.3.2 The momentum balance equations
  • 2.3.3 The energy balance equations
  • 2.3.4 The entropy balance equations
  • 2.4 Entropy production equation
  • 2.4.1 Independent flows and forces
  • 2.4.2 Entropy productions in different tensorial ranks
  • 2.4.3 Curie-Prigogine principle
  • 2.4.4 Rate of entropy production
  • 2.4.5 Dissipation function
  • 2.4.6 Entropy production in stationary states
  • 2.5 Linear nonequilibrium thermodynamic postulates
  • 2.6 Linear phenomenological equations
  • 2.6.1 Flows
  • 2.6.2 Thermodynamic forces.
  • 2.6.3 Nonlinear flow and forces relations
  • 2.6.4 Onsager's relations
  • 2.6.5 Transformation of forces and flows
  • 2.6.6 Validity of linear phenomenological equations
  • 2.7 Time variation of entropy production
  • 2.8 Minimum entropy production
  • 2.8.1 Entropy production in viscous flow
  • 2.8.2 Entropy production in heat conduction
  • 2.8.3 Entropy production in molar and mass diffusion
  • 2.8.4 Entropy production in an electrical circuit
  • Problems
  • References
  • Further reading
  • 3 . Nonequilibrium thermodynamics approaches
  • 3.1 Introduction
  • 3.2 Kinetic approach
  • 3.3 Microscopic and macroscopic domains
  • 3.4 Boltzmann's H-theorem
  • 3.5 Network thermodynamics with bond graph methodology
  • 3.6 Mosaic nonequilibrium thermodynamics
  • 3.7 Rational thermodynamics
  • 3.8 Shortcomings of classical nonequilibrium thermodynamics
  • 3.9 Extended nonequilibrium thermodynamics
  • 3.9.1 Some considerations
  • 3.9.2 Extended nonequilibrium polymer solutions
  • 3.10 GENERIC metriplectic formulation
  • 3.11 Matrix model
  • 3.12 Internal variables
  • 3.13 Mesoscopic nonequilibrium thermodynamics
  • 3.14 Fluctuation theorems
  • 3.15 Quantum thermodynamics
  • References
  • Further reading
  • 2
  • Fundamentals of coupled transport and rate processes
  • 4 . Transport phenomena and chemical reactions
  • 4.1 Introduction
  • 4.2 Transport phenomena
  • 4.2.1 Transport coefficients
  • 4.3 Momentum transfer
  • 4.3.1 Newtonian fluids
  • 4.3.2 Non-Newtonian fluids
  • 4.3.3 Estimation of viscosity of gases at low density
  • 4.3.4 Effect of pressure and temperature on viscosity of gases
  • 4.3.5 Estimation of viscosity of pure liquids
  • 4.3.6 Estimation of viscosity in suspension and slurry
  • 4.4 Heat transfer
  • 4.4.1 Combined energy flow
  • 4.4.2 Thermal diffusivity
  • 4.4.3 Estimation of thermal conductivity.
  • 4.4.4 Thermal conductivity of gases at low density
  • 4.4.5 Estimation of thermal conductivity of pure liquids
  • 4.4.6 Effective thermal conductivity in solids
  • 4.4.7 The relaxation theory
  • 4.5 Mass transfer
  • 4.5.1 Estimation of diffusivities
  • 4.5.2 Effect of temperature and pressure on diffusivity
  • 4.5.3 Diffusion in liquids
  • 4.5.4 Diffusivity in liquids
  • 4.6 Maxwell-Stefan equation
  • 4.7 Generalized matrix method
  • 4.7.1 Diffusion in mixtures of ideal gases
  • 4.7.2 Diffusion in nonideal mixtures
  • 4.8 Diffusion in meso- and macro-porous media
  • 4.8.1 Gas diffusion
  • 4.8.2 Diffusion in liquids
  • 4.9 Diffusion of biological solutes in liquids
  • 4.9.1 Prediction of diffusivities of biological solutes
  • 4.9.2 Diffusion in biological gels
  • 4.10 Diffusion in colloidal suspensions
  • 4.11 Diffusion in polymers
  • 4.12 Diffusion in inhomogeneous and anisotropic media
  • 4.13 Electric charge flow
  • 4.13.1 Mobility
  • 4.13.2 Diffusion in electrolyte systems
  • 4.14 Chemical reactions
  • 4.14.1 Enthalpy of chemical reactions
  • 4.14.2 The principle of detailed balance
  • 4.14.2 The principle of detailed balance
  • 4.14.3 Phenomenological approach for chemical reactions
  • 4.14.4 Dissipation for chemical reactions
  • 4.14.4 Dissipation for chemical reactions
  • Problems
  • References
  • Further reading
  • 5 . Coupled transport phenomena and chemical processes
  • 5.1 Introduction
  • 5.2 Coupled transport and rate processes
  • 5.3 Coupled heat and fluid flows
  • 5.4 Coupled heat and mass transfer
  • 5.4 Coupled heat and mass transfer
  • 5.4.1 Combined energy flow
  • 5.4.2 Generalized flows and thermodynamic forces
  • 5.4.3 Heat and mass flows at mechanical equilibrium
  • 5.4.4 Soret effect
  • 5.4.4.1 Separation by thermal diffusion
  • 5.4.4.2 Soret coefficients for aqueous polyethylene glycol solutions
  • 5.4.5 Dufour effect.
  • 5.4.6 Heat of transport
  • 5.4.7 Heat and mass transfer in discontinuous systems
  • 5.4.7 Heat and mass transfer in discontinuous systems
  • 5.4.8 Degree of coupling
  • 5.4.8.1 Transport coefficients and degree of coupling
  • 5.4.8.2 Dissipation function and degree of coupling
  • 5.4.8.2 Dissipation function and degree of coupling
  • 5.5 Coupled phenomena in multicomponent systems
  • 5.5.1 Coupled heat and diffusion systems
  • 5.5.2 Diffusion in gases
  • 5.5.2 Diffusion in gases
  • 5.5.3 Diffusion in liquid and dense gases
  • 5.5.4 Diffusion for nonisothermal systems
  • 5.5.5 Effective diffusivity
  • 5.6 Balance equations for coupled mass and heat transfer
  • 5.6.1 Binary mixtures
  • 5.6.2 Multicomponent mixtures
  • 5.7 Other coupled systems
  • 5.7.1 Thermoelectric effects
  • 5.7.1.1 Seebeck effect
  • 5.7.1.2 Peltier effect
  • 5.7.1.3 Thomson heat
  • 5.7.1.4 Flows and forces in a bimetallic circuit
  • 5.7.2 Electrokinetic effects
  • 5.7.2.1 Electrophoresis
  • 5.7.2.2 Electroosmosis
  • 5.7.2.3 Streaming current
  • 5.7.2.4 Streaming potential
  • 5.7.2.5 Sedimentation potential
  • 5.7.3 Thermomechanical effect
  • 5.7.3.1 Thermal effusion
  • 5.7.3.2 Thermomolecular pressure
  • 5.7.3.3 Thermoosmosis and thermal filtration
  • 5.7.3.4 Osmotic pressure and temperature
  • 5.7.3.5 Methods used for thermomechanical coupling analysis
  • 5.7.3.6 Applications of thermomechanical coupling effect
  • 5.7.4 Chemiosmosis
  • 5.7.5 Membrane potential
  • 5.7.6 Hyperfiltration
  • 5.8 Multiple chemical reactions
  • 5.8.1 Energy conversion efficiency
  • 5.8.2 Entropy production
  • 5.9 Nonisothermal uncoupled reaction-diffusion systems
  • 5.9.1 Balance equations
  • 5.9.2 Mass and energy balances with reaction
  • 5.9.3 Effectiveness factor
  • 5.9.4 External resistance of heat and mass transfer
  • 5.10 Thermodynamic coupling in nonisothermal reaction-diffusion systems.