Electrochemical energy storage technologies beyond Li-ion batteries : fundamentals, materials, devices /

Electrochemical Energy Storage Technologies Beyond Li-ion Batteries: Fundamentals, Materials, Devices focuses on an overview of the current research directions to enable the commercial translation of electrochemical energy storage technologies. The principles of energy storage mechanisms and device...

Full description

Bibliographic Details
Corporate Author:	ScienceDirect (Online service)
Other Authors:	He, Guanjie (Editor)
Format:	eBook
Language:	English
Published:	Amsterdam : Elsevier, [2025]
Subjects:	Storage batteries. Energy storage. Accumulateurs. Énergie > Stockage. batteries (electrical) Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Intro
Electrochemical Energy Storage Technologies Beyond Li-ion Batteries: Fundamentals, Materials, Devices
Copyright
Contents
Contributors
Preface
Part 1: Fundamentals of electrochemical energy storage technologies
Chapter 1: Fundamental electrochemical energy storage mechanisms
1. Overview
2. Electron transfer and mass transport
3. Electrochemistry of electrolyte
3.1. Aqueous electrolyte
3.2. Organic electrolytes
3.3. Ionic liquids
3.4. Solid/quasisolid electrolytes
3.5. Solid polymer electrolytes
3.6. Gel polymer electrolytes
4. Electrochemistry of electrode
5. Interface
References
Chapter 2: Configurations of electrochemical energy storage devices
1. Overview
2. Device configuration design principles
2.1. Type of alkali metal ion battery
2.2. Cylindrical battery
2.3. Pouch cells
2.4. Square aluminum shell battery
2.5. Design principle of alkali metal ion battery
2.6. Negative/positive capacity ratio
2.7. Compaction density
2.8. Material and specification of separator
2.9. Amount of electrolyte added
2.10. Safety management principles
3. Redox flow batteries (RFBs)
3.1. All-vanadium RFBs
3.2. Zinc-based RFBs
3.3. Zinc-air RFBs
3.4. Zinc-iron RFBs
4. The function of separators
4.1. The action mechanism of separator in batteries
4.2. The main parameters influence separators performances
4.3. Polyolefin-based separator and functional membrane
4.4. Separators beyond polyolefins with extra active functions
4.5. Separators for sodium-ion battery
4.6. Synthesis of separators for sodium-ion battery
4.7. Modification of sodium-ion battery separators
References
Chapter 3: Material characterization and electrochemical test techniques
1. Introduction.
2. Basic characterization and electrochemical test techniques
2.1. X-ray diffraction
2.2. X-ray absorption spectroscopy
2.3. X-ray photoelectron spectroscopy
2.4. Scanning electron microscopy
2.5. Transmission electron microscopy
2.6. Fourier transform infrared spectroscopy
2.7. Raman spectroscopy
2.8. Electrochemical impedance spectroscopy
2.9. Cyclic voltammetry
3. Advanced characterization and electrochemical test techniques
3.1. Neutron powder diffraction
3.2. Neutron total scattering
3.3. Neutron reflection
3.4. Neutron imaging
3.5. Electrochemical quartz crystal microbalance
4. Conclusion
References
Chapter 4: Selected quantum chemical studies on the surfaces and interfaces of carbon materials for applications in&amp
s
1. Introduction
1.1. Architecture of lithium-ion batteries
1.2. Reactions in LIBs
1.3. Other group I elements as alternatives to Li
2. A brief introduction to density functional theory (DFT)
2.1. Hohenberg-Kohn theorems
2.2. Kohn-Sham equations
2.3. Exchange and correlation functional
3. The interaction of Li, Na, and K with carbon materials
3.1. Interaction with PAHs
3.2. Graphite intercalation compounds
3.3. Graphene with defects and doped graphene
3.4. Graphite oxides and graphene oxides
4. Concluding remarks and perspectives
Acknowledgment
References
Part 2: Non-lithium-ion rocking chair batteries: Candidate materials and device design considerations
Chapter 5: Sodium-ion batteries
1. Introduction
2. Anode materials
2.1. Intercalation anodes
2.1.1. Carbon-based materials
2.1.2. Graphite
2.1.3. HC/soft carbon
2.1.4. Graphene and rGO
2.1.5. MXenes
2.1.6. Titanium-based anodes
2.1.7. Titanium dioxide (TiO2)
2.1.8. Sodium titanate (Na2Ti3O7)
2.1.9. Lithium titanate (Li4Ti5O12).
2.2.4. Vanadium-based cathode materials
2.2.4.1. V2O5 cathode materials
2.2.4.2. VxOy cathode materials
2.2.4.3. MxVyOz vanadate cathode materials
2.3. Electrolytes
2.3.1. Aqueous electrolyte
2.3.2. Concentrated electrolytes
2.3.3. Gel electrolyte
2.4. Current collector
2.5. Separators
2.6. Conclusion and perspectives
References
Chapter 8: Rechargeable magnesium-ion batteries: From mechanism to emerging materials
1. Introduction
2. Working mechanism and main challenges
3. Cathode
3.1. Polyanionic cathode materials
3.2. Spinel cathode materials
3.3. Transition metal oxides
3.4. Transition metal sulfides
3.5. Transition metal selenides
4. Anode
4.1. Alloy anode
4.2. Mg metal anode
4.3. Metal oxide anode
4.4. Carbon-based anode
5. Electrolyte
5.1. Mg(TFSI)2
5.2. Nonnucleophilic electrolyte
5.3. Some other electrolytes
6. Summary and outlooks
Acknowledgments
References
Chapter 9: Aluminum-ion batteries
1. Introduction of rechargeable aluminum-ion batteries
2. Cathode materials
2.1. AlCl4- intercalation cathode materials
2.2. Al3+ intercalation cathode materials
2.3. Conversion-type cathode materials
2.4. Summary
3. Electrolytes
3.1. Nonaqueous liquid electrolytes
3.2. Aqueous electrolytes
3.3. Gel polymer electrolytes
3.4. Summary
4. Al metal anode and related technologies
5. Other materials
5.1. Binders
5.2. Current collector
5.3. Separator
5.4. Summary
6. Conclusion and perspectives
References
Chapter 10: Calcium-ion batteries
1. A general introduction to this technology
2. Challenges in developing modern CIBs
3. Anode materials
3.1. Metallic calcium anodes
3.2. Alloy anodes
3.3. Intercalation anodes
3.4. Organic anodes
4. Cathode
4.1. Prussian blue analogs.
4.2. Oxides
4.3. Chalcogenides
4.4. Organic materials
4.5. Other cathode materials
5. Perspectives
5.1. Advanced computation for screening electrode materials
5.2. Surface modification
5.3. Defects engineering
5.4. Designing nanostructure for fast Ca2+ diffusion
5.5. Multiion strategies
5.6. Optimization of testing conditions
References
Chapter 11: Materials electrochemistry for dual-ion batteries
1. Understanding of dual-ion batteries
1.1. Introduction
1.2. Fundamentals of dual-ion batteries
2. Positive electrode design
2.1. Graphite
2.1.1. Electrochemistry and fundamentals in graphite
2.1.2. Influencing factors and strategies
2.2. Other cathode candidates
3. Negative electrode design
3.1. Intercalation- and conversion-type anodes
3.2. Alloying-type anodes
3.3. Metallic and organic materials
4. Electrolyte design
4.1. Standard liquid electrolyte
4.2. Solvation effect of anions
4.3. Functional additives
4.4. High-concentration electrolytes
4.5. Quasi-solid-state and gel polymer electrolytes
5. Conclusion and perspectives
References
Part 3: Emerging metal-air batteries and fuel cells: Candidate materials and device design considerations
Chapter 12: Lithium-air batteries
1. Introduction
2. Anode materials
2.1. Oxygen-selective membranes and their positive effects on Li metal anode
2.2. In situ protective layers
2.3. External anodic hydrophobic protective coatings
2.4. Lithium liquid metal as the anode
3. Air-cathode materials
3.1. Carbon-based catalyst
3.2. Transition metal oxide-based catalyst
3.3. Spinel oxide-based catalysts
3.4. Perovskite oxide catalysts
4. Electrolytes
4.1. Nonaqueous electrolyte
4.2. Aqueous electrolyte
4.3. Solid-state electrolyte
5. Other components
5.1. Current collectors.