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00000cam a2200000 i 4500 |
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20260327180725.5 |
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m o d |
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cr cnu---unuuu |
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241126s2025 ne o 001 0 eng d |
| 040 |
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|a OPELS
|b eng
|e rda
|e pn
|c OPELS
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|d SFB
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|z 9780443240386
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|a (OCoLC)1473750750
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|a TK2931
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|a 621.31/2429
|2 23/eng/20241126
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| 049 |
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|a TXAM
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| 100 |
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|a Kumar, Anuj,
|c Dr.,
|e author.
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| 245 |
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|a Fuel cells technology and electrode materials for a sustainable future /
|c Anuj Kumar, Ram K. Gupta.
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| 264 |
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1 |
|a Amsterdam, Netherlands :
|b Elsevier,
|c [2025]
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| 300 |
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|a 1 online resource.
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| 336 |
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a Fuel Cells Technology and Electrode Materials for Sustainable Future presents an up-to-date review of the latest advancements in fuel cell technology and materials, including a comprehensive examination of the synthesis, characterization, and application of electrode materials for fuel cells. With a focus on the fundamentals of electrochemical behavior and their relevance to fuel cells, the book delves into novel techniques and advanced technologies currently being employed in the field. Presenting a well-defined theoretical approach to the design of new electrocatalysts, the book provides extensive information on the designs and modeling of electrocatalysts and catalyst layers for the PEMCs, the fundamentals of PEMFCs working, catalyst deterioration and diagnosis, and techniques for reducing failure modes. Sustainability and cost considerations are included throughout. In addition, it discusses promising and significant future directions for fuel cells development. Within each chapter, detailed figures, images, and reference data have been included to make the book accessible for new entrants to the topic.
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| 500 |
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|a Includes index.
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|a Online resource; title from PDF title page (ScienceDirect, viewed November 26, 2024).
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|a Front Cover -- Fuel Cells Technology and Electrode Materials for a Sustainable Future -- Copyright Page -- Contents -- 1 Basics of fuel cells -- 1.1 Introduction -- 1.1.1 Historical biography of fuel cells -- 1.1.2 What makes fuel cells necessary -- 1.1.3 Sustainability and cost analysis -- 1.2 Fuel cells-types, cell components, materials, and chemistry -- 1.2.1 Proton exchange membrane fuel cells -- 1.2.2 Alkaline fuel cells -- 1.2.3 Phosphoric acid fuel cells -- 1.2.4 Molten carbonate fuel cells -- 1.2.5 Solid oxide fuel cells -- 1.2.6 Microbial fuel cells -- 1.2.7 Materials for fuel cells -- 1.3 Conclusion -- References -- 2 Thermodynamic chemistry of proton exchange membrane fuel cell -- 2.1 Introduction -- 2.2 Heat of reaction -- 2.3 Reversible fuel cell potential -- 2.4 Open circuit voltage -- 2.5 Fuel cell efficiency -- 2.6 Conclusion -- References -- 3 Electrode kinetics -- 3.1 Introduction -- 3.2 Reaction rate -- 3.3 Exchange current density -- 3.4 Arrhenius equation and transition state theory -- 3.5 Butler-Volmer equation -- 3.6 Butler-Volmer model of kinetics -- 3.7 Activation overpotential -- 3.8 Tafel equation -- 3.9 Significance of exchange current density -- 3.9.1 Low current density -- 3.9.2 High current density -- 3.10 Significance of charge transfer coefficient -- 3.11 Conclusions -- References -- 4 Concentration polarization -- 4.1 Introduction -- 4.2 Transport phenomenon in fuel cells -- 4.3 Revisiting some of the basic concepts -- 4.4 Concept of average and diffusion velocity -- 4.5 Diffusion law -- 4.6 Newton's law of viscosity (momentum transport) -- 4.7 Fourier's law -- 4.8 Quantifying concentration polarization -- 4.9 Nernst equation analysis -- 4.10 Conclusions -- References -- 5 Characterization of fuel cells -- 5.1 Introduction -- 5.2 In-situ characterization techniques.
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| 505 |
8 |
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|a 5.2.1 Evaluation criteria and approaches for electrode reactions -- 5.2.2 Overpotential -- 5.2.3 Tafel slope investigations -- 5.2.4 Exchange current density -- 5.2.5 Turnover frequency -- 5.2.6 Faraday efficiency -- 5.2.7 Electrochemically active surface area -- 5.2.8 Mass and specific activities -- 5.2.9 Stability investigations -- 5.3 Ex-situ characterization techniques -- 5.4 Porosity measurements -- 5.5 BET surface area measurements -- 5.6 Gas permeability studies -- 5.7 Structure investigations -- 5.8 Chemical investigations -- 5.9 Conclusions -- References -- 6 Electrocatalytic oxygen reduction reaction -- 6.1 Introduction -- 6.2 Electrochemical oxygen reduction reaction -- 6.3 Oxygen reduction reaction kinetics -- 6.4 Oxygen reduction reaction mechanisms -- 6.5 Factors affecting oxygen reduction reaction -- 6.5.1 Role of central metal ion -- 6.5.1.1 Role of ligands -- 6.5.1.2 The pH Effect -- 6.5.1.3 Electrocatalysts for oxygen reduction reaction -- 6.6 Conclusions -- References -- 7 Emerging materials for oxygen reduction reaction -- 7.1 Introduction -- 7.2 Noble-metal-based ORR electrocatalysts -- 7.3 Noble metal-free ORR electrocatalysts -- 7.4 Atomically dispersed metals-based catalysts for ORR -- 7.5 Molecular catalysts for ORR -- 7.6 Conclusion and perspectives -- References -- 8 Electrocatalytic hydrogen oxidation reaction -- 8.1 Introduction -- 8.2 Electrochemical hydrogen oxidation reaction -- 8.3 Kinetics of the hydrogen oxidation reaction -- 8.4 Factors affecting hydrogen oxidation reaction -- 8.4.1 H-adsorption behavior -- 8.4.2 HOR kinetic parameters -- 8.5 Conclusions -- References -- 9 Emerging materials for hydrogen oxidation reaction -- 9.1 Introduction -- 9.2 Noble metal-based catalysts for hydrogen oxidation reaction -- 9.3 Non-noble metal-based catalysts for hydrogen oxidation reaction.
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| 505 |
8 |
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|a 9.4 Atomically dispersed metals-based catalysts for hydrogen oxidation reaction -- 9.5 Molecular catalysts for hydrogen oxidation reaction -- 9.6 Conclusions -- References -- 10 Electrocatalytic oxidation of methanol and ethanol -- 10.1 Introduction -- 10.2 Methanol electrooxidation -- 10.3 Ethanol electrooxidation -- 10.4 Factors affecting oxidation of methanol and ethanol -- 10.4.1 Synergy between electrocatalysis and electrode -- 10.4.2 Electronically conductive polymer supports -- 10.5 Conclusions -- References -- 11 Emerging materials for alcohol oxidation reaction -- 11.1 Introduction -- 11.2 Nobel metal-based catalysts for AOR -- 11.3 Non-nobel metal-based catalysts for AOR -- 11.4 Atomically dispersed metals-based catalysts for AOR -- 11.5 Molecular catalysts for AOR -- 11.6 Conclusions -- References -- 12 Single-atom catalysts for oxygen reduction reaction and alcohol oxidation reaction -- 12.1 Introduction -- 12.2 ORR scaling relationship with single-atom catalysts -- 12.3 Strategies to break scaling relationship for oxygen reduction reaction -- 12.4 Optimization for single-atom catalysts -- 12.4.1 Optimizations for improving single-atom catalysts performance -- 12.4.2 Optimization of metal center types -- 12.4.3 Optimization of coordination environments -- 12.4.4 Optimization of supports -- 12.5 Carbon and noncarbon supported single-atom catalysts for oxygen reduction reaction -- 12.5.1 Carbon-supported single-atom catalysts -- 12.5.2 Noncarbon supports for single-atom catalysts -- 12.5.2.1 Metals (alloys) -- 12.5.2.2 Metal oxides -- 12.5.2.3 Metal hydroxides -- 12.5.2.4 Metal chalcogenides -- 12.5.2.5 Carbides -- 12.5.2.6 Nitrides -- 12.5.2.7 Microporous materials -- 12.6 Single-atom catalysts for alcohol oxidation reaction -- 12.7 Conclusions -- References.
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| 505 |
8 |
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|a 13 Dual-atom catalysts for oxygen reduction reaction and alcohol oxidation reaction -- 13.1 Introduction -- 13.2 Breaking the ORR scaling relationship with dual-atom catalysts -- 13.3 Optimization for dual-atom catalysts -- 13.4 Calculations using DFT and machine learning for predicting effective DACs -- 13.5 Optimization of electronic and geometric structure -- 13.6 Optimization of synthesis method -- 13.7 Advances in dual-atom catalysts for ORR -- 13.8 Bonded dual-atom ORR catalysts -- 13.9 Dual-atom catalysts for AOR -- 13.10 Conclusions -- References -- Index -- Back Cover.
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| 650 |
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0 |
|a Fuel cells.
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| 650 |
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|a Fuel cells
|x Electrodes
|x Materials.
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| 650 |
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6 |
|a Piles à combustible
|x Électrodes
|x Matériaux.
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| 655 |
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7 |
|a Electronic books.
|2 local
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| 700 |
1 |
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|a Gupta, Ram K.,
|e author.
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| 710 |
2 |
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|a ScienceDirect (Online service)
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| 856 |
4 |
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|u http://proxy.library.tamu.edu/login?url=https://www.sciencedirect.com/science/book/9780443240386
|z Connect to the full text of this electronic book
|t 0
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| 955 |
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|a Elsevier ScienceDirect 2026-2027
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| 994 |
|
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|a 92
|b TXA
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| 999 |
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| 952 |
f |
f |
|a Texas A&M University
|b College Station
|c Electronic Resources
|s www_evans
|d Available Online
|t 0
|e TK2931
|h Library of Congress classification
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| 998 |
f |
f |
|a TK2931
|t 0
|l Available Online
|