Deep Eutectic Solvents.

Deep Eutectic Solvents highlights well-established research and technology on applications of DESs in corrosion sciences, protein chemistry, and organic synthesis, as well as separation science.This book provides state-of-the-art research that will revolutionize modern practices.

Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Jawaid, Mohammad, Bahadur, Indra, Singh, Prashant, Akhter Siddique, Jamal
Format: eBook
Language:English
Published: Chantilly : Elsevier, 2024.
Subjects:
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Intro
  • Deep Eutectic Solvents
  • Copyright
  • Contents
  • Contributors
  • Chapter 1: Navigating neoteric solvents: An overview for sustainable chemistry
  • 1. Introduction
  • 2. Definition of DES
  • 3. History
  • 4. Types of DESs
  • 5. Classification based on the source and nature of constituents
  • 5.1. Natural deep eutectic solvents (NADESs)
  • 5.2. Therapeutic deep eutectic solvents (THEDESs)
  • 5.3. Polymeric deep eutectic solvents (PODESs)
  • 6. Classification based on water miscibility
  • 6.1. Hydrophilic DESs
  • 6.2. Hydrophobic DESs
  • 6.3. Hydrophilic vs hydrophobic
  • 7. Preparation methods of DESs
  • 8. Characterization and physicochemical properties of DES
  • 8.1. Infrared spectroscopy
  • 8.2. Raman spectroscopy
  • 8.3. Nuclear magnetic resonance (NMR) spectroscopy
  • 8.4. Thermogravimetric analysis (TGA)
  • 8.5. Differential scanning calorimetry (DSC)
  • 8.6. Neutron scattering
  • 8.7. Fluorescence spectroscopy
  • 9. Role of deep eutectic solvents in selected applications
  • 9.1. DESs for metal separation and recovery
  • 9.2. DESs for electrochemistry
  • 9.3. Extraction of dyes, pesticide residues and other micropollutants from the aqueous phase
  • 9.4. DES for biomass pretreatment
  • 9.5. DES for CO2 capture
  • 9.6. DES for organic synthesis
  • 10. Toxicity and biodegradability
  • 11. Challenges and future perspectives of DES
  • 12. Conclusions
  • References
  • Chapter 2: Applications of DES in nanomaterials
  • 1. Introduction
  • 2. History of DES
  • 3. History of nanomaterials
  • 4. Applications
  • 4.1. Renewable energy field
  • 4.2. Electrochemical sensing
  • 4.3. Metal processing
  • 4.3.1. Metal accumulation
  • Cr plating
  • Zn plating
  • Composite plating
  • Alloy coating
  • 4.3.2. Electropolishing of metal
  • 4.3.3. Processing of metals
  • 4.4. Drug delivery
  • 5. Future challenges of DES in nanomaterials
  • 6. Conclusion
  • References
  • Chapter 3: Synthesis of sulfur-containing compounds in deep eutectic solvents
  • 1. Introduction
  • 2. Thiophene
  • 3. Thiazoles
  • 4. Thiazolidinones
  • 5. Thiazolidinediones
  • 6. Sulfides
  • 7. Sulfoxides
  • 8. Sulfites
  • 9. Dithiocarbamates
  • 10. Thiirane
  • 11. Thiazolo[3,2-a]indole-3(2H)-one
  • 12. Carbon-sulfur cross-coupling reactions
  • 13. Conclusions and future outlook
  • References
  • Chapter 4: How DESs can be used as corrosion inhibitors
  • 1. Introduction
  • 2. Chemical composition of DESs
  • 3. Characteristics of DESs
  • 3.1. Lower volatility
  • 3.2. Higher density and viscosity
  • 3.3. Reduced toxicity
  • 3.4. Nonflammability
  • 3.5. Better solubility
  • 3.6. Formation of stable complexes
  • 3.7. Higher thermal stability
  • 3.8. Enhanced biodegradability with better tunability
  • 3.9. Higher ionic conductivity
  • 3.10. Capability of formation of shielding layer on metals surface
  • 3.11. Economic viability
  • 3.12. Easier to extract from natural sources
  • 3.13. Wide array of applications