Deep Eutectic Solvents.
Deep Eutectic Solvents highlights well-established research and technology on applications of DESs in corrosion sciences, protein chemistry, and organic synthesis, as well as separation science.This book provides state-of-the-art research that will revolutionize modern practices.
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| Other Authors: | , , , |
| Format: | eBook |
| Language: | English |
| Published: |
Chantilly :
Elsevier,
2024.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Intro
- Deep Eutectic Solvents
- Copyright
- Contents
- Contributors
- Chapter 1: Navigating neoteric solvents: An overview for sustainable chemistry
- 1. Introduction
- 2. Definition of DES
- 3. History
- 4. Types of DESs
- 5. Classification based on the source and nature of constituents
- 5.1. Natural deep eutectic solvents (NADESs)
- 5.2. Therapeutic deep eutectic solvents (THEDESs)
- 5.3. Polymeric deep eutectic solvents (PODESs)
- 6. Classification based on water miscibility
- 6.1. Hydrophilic DESs
- 6.2. Hydrophobic DESs
- 6.3. Hydrophilic vs hydrophobic
- 7. Preparation methods of DESs
- 8. Characterization and physicochemical properties of DES
- 8.1. Infrared spectroscopy
- 8.2. Raman spectroscopy
- 8.3. Nuclear magnetic resonance (NMR) spectroscopy
- 8.4. Thermogravimetric analysis (TGA)
- 8.5. Differential scanning calorimetry (DSC)
- 8.6. Neutron scattering
- 8.7. Fluorescence spectroscopy
- 9. Role of deep eutectic solvents in selected applications
- 9.1. DESs for metal separation and recovery
- 9.2. DESs for electrochemistry
- 9.3. Extraction of dyes, pesticide residues and other micropollutants from the aqueous phase
- 9.4. DES for biomass pretreatment
- 9.5. DES for CO2 capture
- 9.6. DES for organic synthesis
- 10. Toxicity and biodegradability
- 11. Challenges and future perspectives of DES
- 12. Conclusions
- References
- Chapter 2: Applications of DES in nanomaterials
- 1. Introduction
- 2. History of DES
- 3. History of nanomaterials
- 4. Applications
- 4.1. Renewable energy field
- 4.2. Electrochemical sensing
- 4.3. Metal processing
- 4.3.1. Metal accumulation
- Cr plating
- Zn plating
- Composite plating
- Alloy coating
- 4.3.2. Electropolishing of metal
- 4.3.3. Processing of metals
- 4.4. Drug delivery
- 5. Future challenges of DES in nanomaterials
- 6. Conclusion
- References
- Chapter 3: Synthesis of sulfur-containing compounds in deep eutectic solvents
- 1. Introduction
- 2. Thiophene
- 3. Thiazoles
- 4. Thiazolidinones
- 5. Thiazolidinediones
- 6. Sulfides
- 7. Sulfoxides
- 8. Sulfites
- 9. Dithiocarbamates
- 10. Thiirane
- 11. Thiazolo[3,2-a]indole-3(2H)-one
- 12. Carbon-sulfur cross-coupling reactions
- 13. Conclusions and future outlook
- References
- Chapter 4: How DESs can be used as corrosion inhibitors
- 1. Introduction
- 2. Chemical composition of DESs
- 3. Characteristics of DESs
- 3.1. Lower volatility
- 3.2. Higher density and viscosity
- 3.3. Reduced toxicity
- 3.4. Nonflammability
- 3.5. Better solubility
- 3.6. Formation of stable complexes
- 3.7. Higher thermal stability
- 3.8. Enhanced biodegradability with better tunability
- 3.9. Higher ionic conductivity
- 3.10. Capability of formation of shielding layer on metals surface
- 3.11. Economic viability
- 3.12. Easier to extract from natural sources
- 3.13. Wide array of applications