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Advances in Organometallic Chemistry.

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Bibliographic Details
Main Author: Perez, Pedro J.
Corporate Author: ScienceDirect (Online service)
Other Authors: Pedro J. Pérez
Format: eBook
Language:English
Published: Chantilly : Elsevier Science & Technology, 2024.
Edition:1st ed.
Series:Issn Series.
Subjects:
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Front Cover
  • Advances in Organometallic Chemistry
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Chapter One: Ni(I) complexes relevant to synthetic organic catalysis
  • 1 Introduction
  • 2 Characterization of Ni(I) complexes
  • 2.1 Magnetic susceptibility of Ni(I) complexes
  • 2.2 Nuclear magnetic resonance (NMR) analysis of Ni(I) complexes
  • 2.3 X-ray diffraction (XRD) analysis of Ni(I) complexes
  • 3 Electron paramagnetic resonance (EPR) analysis of Ni(I) complexes
  • 3.1 EPR background
  • 3.2 The g-value
  • 3.3 Hyperfine splitting
  • 3.4 Interpreting EPR spectra of Ni(I) complexes
  • 3.5 Spin coupling in Ni(I) dimers
  • 4 Ni(I) complexes relevant to catalysis
  • 4.1 Ni(I) phosphine complexes
  • 4.2 General conclusions for Ni(I) phosphine complexes
  • 4.3 Ni(I) complexes with polypyridyl and other N-donor ligands
  • 4.4 General conclusions for Ni(I) complexes with N-donor ligands
  • 4.5 Ni(I) complexes with N-heterocyclic carbene (NHC) ligands
  • 4.6 General conclusions for Ni(I) complexes with NHC ligands
  • References
  • Chapter Two: Modern mechanistic approaches for the depolymerization of commodity plastics via organometallic catalysis
  • 1 Introduction
  • 2 Resin code 1: polyethylene terephthalate (PET)
  • 2.1 Hydrogenolysis
  • 2.2 Hydrosilylation
  • 2.3 Hydroboration
  • 3 Resin codes 2 and 4: polyethylene (HDPE and LDPE)
  • 3.1 Dehydrogenation-metathesis
  • 3.2 Dehydrogenation/isomerizing ethenolysis
  • 3.3 Dehydrobromination-metathesis
  • 4 Resin code 3: polyvinyl chloride (PVC)
  • 4.1 Dehalogenation
  • 4.2 Dehydrochlorination/acyclic diene metathesis (including ethenolysis)
  • 5 Resin code 5: polypropylene
  • 7.7 Polysiloxanes
  • 8 Conclusions and future outlook
  • Acknowledgments
  • References
  • Chapter Three: Functionalization of fullerenes by transition metal catalyzed cyclization reactions: Insights into the mechanisms
  • 1 Introduction
  • 2 Tsuji-Trost-type reactions
  • 3 Cyclization via palladium-catalyzed C-X/C-H activation
  • 3.1 Palladium-catalyzed C-X activation
  • 3.2 Palladium-catalyzed C-H activation
  • 4 [2 + 1] Cycloaddition
  • 5 [3 + 2] Cycloaddition
  • 6 [2 + 2 + 1] Cycloaddition
  • 7 [2 + 2 + 2] Cycloaddition
  • 8 Cascade reactions
  • 8.1 Involving [2 + 2] cycloaddition