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Earth-Abundant Transition Metal Catalyzed Reactions /

Earth-Abundant Transition Metal Catalyzed Reactions, Volume 74 in the Advances in Catalysis series, highlights new advances in the field, with this new volume presenting interesting chapters. Each chapter is written by an international board of authors. Chapters in this new release include in Chiral...

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Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Ollevier, Thierry (Editor), Diéguez, Montserrat (Editor)
Format: eBook
Language:English
Published: London : Academic Press, [2024]
Edition:First edition.
Series:Issn Series.
Subjects:
Transition metal catalysts.
Catalyseurs à base de métaux de transition.
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • 9.2 Enantioselective sulfoxidation through asymmetric counteranion-directed iron catalysis
  • 9.3 Enantioselective hetero-Diels-Alder reaction through chiral-at-iron catalysis
  • 10 Conclusions and overview
  • Acknowledgments
  • References
  • About the author
  • Chapter Two: Iron-catalyzed group-transfer reactions with iodine(III) reagents
  • 1 Introduction
  • 2 Oxygenation reactions
  • 3 Nitrogen transfer reactions
  • 3.1 Aziridination of alkenes
  • 3.2 C-H bond amination reactions
  • 3.3 Imination of sulfoxides and sulfides
  • 3.4 Direct formation of amides from aldehydes
  • 4 Azidation reactions
  • 4.1 C-H bond azidation reactions
  • 4.2 Diazidation of alkenes
  • 4.3 Oxiazidation of alkenes
  • 5 Trifluoromethylation reactions
  • 5.1 Trifluoromethylation of alkenes
  • 5.2 Radical cascades
  • 5.3 Trifluoromethylazidation of alkenes
  • 6 Other difunctionalization reactions of alkenes
  • 7 Fluorine transfer reactions
  • 8 Cyano transfer reactions
  • 9 Outlook and future perspectives
  • References
  • About the authors
  • Chapter Three: Iron porphyrins for mediating atom efficient C-C bond formations
  • 1 Introduction: iron porphyrins to promote C-C bond formation
  • 2 C-C bond formation via cyclopropanation reactions
  • 2.1 Diasteroselective cyclopropanation reactions
  • 2.2 Enantioselective cyclopropanation reactions
  • 3 C-C bond formation by C-H bond functionalization
  • 4 Summary and outlook
  • References
  • Chapter Four: Recent advances in Ni-catalyzed functionalization of strong C−O and C−H bonds
  • 1 Chemical properties of nickel
  • 2 Nickel-catalyzed reactions
  • 2.1 Nickel-catalyzed C−O bond functionalization reactions
  • 2.1.1 Nickel-catalyzed C(sp2)−O bond functionalization reactions
  • 2.1.1.1 Aryl esters
  • 2.1.1.2 Aryl methyl ethers
  • 2.1.2 Nickel-catalyzed C(sp3)−O bond functionalization reactions.
  • 2.1.2.1 Benzylic and allylic derivatives
  • 2.1.2.2 Aliphatic C(sp3)−O electrophiles
  • 2.1.2.3 C(sp3)−O bond cleavage strategies using redox-active esters via SET events
  • 2.1.2.4 C(sp3)−O bond cleavage strategies via HAT
  • 2.2 Nickel-catalyzed C−H bond functionalization reactions
  • 2.2.1 Nickel-catalyzed C(sp2)−H bond functionalization reactions
  • 2.2.1.1 Undirected nickel-catalyzed C(sp2)−H bond functionalizations
  • 2.2.1.2 Nickel-catalyzed chelation-assisted C(sp2)−H bond functionalizations
  • 2.2.1.3 Nickel-catalyzed C(sp2)−H bond functionalization via Ni migration
  • 2.2.2 Nickel-catalyzed C(sp3)−H bond functionalization reactions
  • 2.2.2.1 C(sp3)−H bond functionalization via HAT
  • 2.2.2.2 Nickel catalyzed HAT strategies
  • 2.2.2.3 Photocatalyzed HAT strategies
  • 2.2.2.4 Remote C(sp3)−H bond functionalization via chain-walking events
  • 2.3 Proposed intermediates in olefin isomerization
  • 3 Conclusions
  • References
  • Further reading
  • About the authors
  • Chapter Five: Low-valent molecular cobalt complexes for CO2 reduction
  • 1 Introduction
  • 1.1 General considerations on electrochemistry and photochemistry for CO2 reduction
  • 1.1.1 Electrochemical CO2 reduction
  • 1.1.2 Photochemical CO2 reduction
  • 1.2 Molecular design of cobalt complexes with nitrogen ligands
  • 1.3 Mechanistic pathways
  • 2 Complexes based on heme ligands
  • 2.1 Porphyrine and porphine Co complexes
  • 2.2 Phthalocyanine Co complexes
  • 2.3 Corrole and corrin Co complexes
  • 3 Non-heme macrocyclic, polypyridyl and aminopyridyl complexes
  • 3.1 Imino-aminopyridine complexes and related systems
  • 3.2 Amino-aminopyridine complexes
  • 3.3 Catalysts based on polypyridyl ligands
  • 3.3.1 Quaterpyridine ligand and derivates
  • 3.4 Catalyst design to control selectivity with non-heme macrocyclic, polypyridyl and aminopyridyl complexes.
  • 4 Future perspectives and conclusions
  • References
  • About the authors
  • Back Cover.