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Homogeneous carbonylation and hydroformylation reactions.

Homogeneous Carbonylation and Hydroformylation Reactions with Homogeneous Catalysts and Process Development, a volume is in the Advances in Catalysis series, is split into two sections. The first covers the homogeneous carbonylation of various chemicals, such as methanol, methyl acetate, esters and...

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Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Rahimpour, Mohammad Reza, Makarem, Mohammad Amin, Roostaie, Tayebeh, Meshksar, Maryam
Format: eBook
Language:English
Published: Amsterdam : Elsevier, 2024.
Series:Advances in homogeneous catalysis ; v. 3
Subjects:
Heterogeneous catalysis.
Catalyse hétérogène.
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Front Cover
  • Homogeneous Carbonylation and Hydroformylation Reactions
  • Homogeneous Carbonylation and Hydroformylation Reactions
  • Copyright
  • Contents
  • Contributors
  • About the editors
  • Preface
  • Reviewer acknowledgments
  • I
  • Carbonylation with homogeneous catalysts
  • 1
  • An overview of carbonylation systems and processes with homogeneous catalysts
  • 1. Introduction
  • 1.1 Historical background of carbonylation with homogeneous catalysts
  • 2. Carbonylation reactions in metal catalysts
  • 2.1 Homogeneous catalysis with nickel
  • 2.2 Homogeneous catalysis with cobalt
  • 2.3 Homogeneous catalysis with rhodium
  • 3. Carbonylation reactions in organic synthesis
  • 3.1 Carbonylation of dimethyl carbonate (and diethyl carbonate)
  • 3.2 Carbonylation of polycarbonate
  • 3.3 Carbonylation of alcohols
  • 4. Conclusion and future outlooks
  • Abbreviations and symbols
  • References
  • 2
  • Homogeneous methanol carbonylation
  • 1. Introduction
  • 2. Processes
  • 2.1 Rhodium-catalyzed Monsanto process [3-5,11,12]
  • 2.2 Iridium-catalyzed Cativa process
  • 3. Current applications and cases
  • 3.1 Modification of homogeneous rhodium(I) catalyst
  • 3.2 Modification of homogeneous iridium(I) catalyst
  • 3.3 Supported molecular catalysts
  • 4. Conclusion and future outlooks
  • Abbreviations and symbols
  • References
  • 3
  • Higher alcohols carbonylation using homogeneous catalysts
  • 1. Introduction
  • 2. Homogeneous catalysts for ketones and esters carbonylation to higher alcohols
  • 2.1 Carbonylation of 1-(4-isobutylphenyl) ethanol
  • 2.2 Carbonylation of 1-(6'-methoxy-2'-naphthyl)ethanol
  • 3. Application metal-catalyzed carbonation in higher alcohol
  • 3.1 Rhodium-catalyzed carbonylations
  • 4. Conclusion and future outlooks
  • Abbreviations and symbols
  • References
  • Further reading
  • 4
  • Carbonylation of aryl halides using homogeneous catalysts
  • 1. Introduction
  • 2. Principles and procedures
  • 3. Processes
  • 4. Current applications and cases
  • 4.1 Carbonylative coupling involving heteroatom nucleophiles
  • 4.1.1 Alkoxycarbonylation
  • 4.1.2 Aminocarbonylation
  • 4.1.3 Reductive aminocarbonylation
  • 4.1.4 Thiocarbonylation
  • 4.1.5 Reductive thiocarbonylation
  • 4.2 Carbonylative coupling involving carbon-centered nucleophiles
  • 4.2.1 Carbonylative Sonogashira coupling
  • 4.2.2 Carbonylative Suzuki coupling
  • 4.3 Miscellaneous reactions
  • 5. Conclusion and future outlooks
  • Abbreviations and symbols
  • Acknowledgments
  • References
  • 5
  • Oxidative carbonylation with homogeneous catalysts
  • 1. Introduction
  • 1.1 Homogeneous and heterogeneous catalysis with OC
  • 2. OC in organic synthesis with homogeneous catalysts
  • 2.1 Carbonylation of alcohol
  • 2.2 Carbonylation of amines
  • 2.3 Carbonylation of alkynes
  • 3. Application of ligands in OC of homogeneous catalyst
  • 4. Conclusion and future outlooks
  • Abbreviations and symbols
  • References
  • 6
  • Water-gas shift reaction with homogeneous catalysts