Cover Image

Hybrid nanofillers for polymer reinforcement : synthesis, assembly, characterization and applications /

This book provides a comprehensive overview of hybrid nanofillers and their applications in polymer reinforcement. Edited by experts in the field, it covers the synthesis, assembly, and various applications of hybrid nanofillers, highlighting their role in enhancing material properties across indust...

Full description

Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Format: eBook
Language:English
Published: Amsterdam, Netherlands ; Oxford, United Kingdom ; Cambridge MA : Elsevier, [2024]
Series:Micro & nano technologies.
Subjects:
Nanostructured materials.
Polymers.
Nanomatériaux.
Polymères.
polymers.
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Front Cover
  • Hybrid Nanofillers for Polymer Reinforcement
  • Copyright Page
  • Dedication
  • Contents
  • List of contributors
  • About the editors
  • Foreword
  • Preface
  • 1 Introduction to hybrid nanostructures and systems
  • 1 Introduction to hybrid nanomaterials: future perspective and applications
  • 1.1 Introduction
  • 1.2 Microcomposites versus nanocomposites
  • 1.2.1 Microsized filler composites
  • 1.2.1.1 Advantages of microsized filler composites
  • 1.2.2 Nanosized filler composites
  • 1.2.2.1 Advantages of nanosized filler composites
  • 1.2.3 Advantages and disadvantages of microsized and nanosized filler composites
  • 1.2.3.1 Advantages of microsized filler composites
  • 1.2.3.2 Disadvantages of microsized filler composites
  • 1.2.3.3 Advantages of nanosized filler composites
  • 1.2.3.4 Disadvantages of nanosized filler composites
  • 1.2.4 Single filler filled polymer composites
  • 1.2.5 Hybrid filler filled polymer composites
  • 1.2.6 Single filler filled polymer composites versus hybrid filler filled polymer composites
  • 1.2.6.1 Single filler filled polymer composites
  • 1.2.6.1.1 Advantages Enhanced mechanical properties: The addition of fillers can significantly improve the mechanical prope...
  • 1.2.6.1.2 Disadvantages Limited property enhancement: Single filler composites may have limitations in achieving a wide ran...
  • 1.2.6.2 Hybrid filler filled polymer composites
  • 1.2.6.2.1 Advantages Enhanced property range: Hybrid composites offer a wider range of enhanced properties compared to sing...
  • 1.2.6.2.2 Disadvantages Increased complexity: The incorporation of multiple types of fillers increases the complexity of th...
  • 1.2.7 Unique properties of nanomaterials
  • 1.2.8 Unique properties of nanomaterials making them suitable to be used as fillers in polymer composites
  • 1.2.9 Sizes of nanomaterials.
  • 1.2.10 Shapes of nanomaterials
  • 1.2.11 Impact of nanomaterial size on structural and functional properties of polymer composites
  • 1.2.12 Impact of nanomaterial shapes on structural and functional properties of polymer composites
  • 1.2.12.1 Impact of nanoparticle shape, that is, spheres, rods, and platelets, on structural and functional properties of po...
  • 1.2.13 Synergistic effect
  • 1.2.14 Synergistic effects in polymer composites
  • 1.2.15 Synergistic effects of nanomaterials in polymer composites
  • 1.2.16 Synergistic effect of nanomaterials with different sizes
  • 1.2.16.1 Synergistic effect of nanomaterials with different sizes in polymer composites
  • 1.2.16.2 Synergistic effect of nanoparticles with different sizes in polymer composites
  • 1.2.17 Synergistic effect of nanomaterials with different shapes
  • 1.2.17.1 Synergistic effect of nanomaterials with different shapes in polymer composites
  • 1.2.17.2 Synergistic effect of nanoparticles with different shapes in polymer composites
  • 1.2.18 Synergistic effect of nanomaterials with different surface characteristics
  • 1.2.18.1 Synergistic effect of combining nanomaterials with different surface characteristics in polymer composites
  • 1.2.19 Challenges associated with dispersion of nanomaterials
  • 1.2.20 Challenges associated with dispersion of nanomaterials in polymer composites
  • 1.2.20.1 Challenges associated with dispersion of nanoparticles
  • 1.2.20.1.1 Challenges associated with dispersion of fillers based on sizes
  • 1.2.20.1.2 Challenges associated with dispersion of fillers based on shapes
  • 1.2.21 Examples of combinations of hybrid nanomaterials fillers that can be used in the fabrication of polymer composite ma...
  • 1.2.21.1 Latest and popular combinations of nanomaterials used in fabrication of polymer composite materials
  • 1.2.21.1.1 Graphene oxide hybrid composites.
  • 1.2.21.1.2 Graphene hybrid composites
  • 1.2.21.1.3 Nanocellulose hybrid composites
  • 1.2.21.1.4 Metal nanoparticles hybrid composites
  • 1.2.21.1.5 CNTs hybrid composites
  • 1.2.21.1.6 Nanoclay hybrid composites
  • 1.2.21.1.7 Silica nanoparticles hybrid composites
  • 1.2.21.1.8 nHA hybrid composites
  • 1.2.21.1.9 Metal oxide nanoparticles hybrid composites
  • 1.2.22 Future prospects of using nanomaterials as hybrid fillers in polymer composites
  • 1.3 Conclusions
  • AI disclosure
  • References
  • 2 Synthesis of hybrid nanostructures of polymer
  • 2.1 Introduction
  • 2.2 Synthetic methods
  • 2.2.1 Solution mixing
  • 2.2.1.1 Metal nanoparticles
  • 2.2.1.2 Carbon nanotubes
  • 2.2.1.3 Graphene
  • 2.2.2 Melt mixing
  • 2.2.2.1 Metal nanoparticles
  • 2.2.2.2 Carbon nanotubes
  • 2.2.2.3 Graphene
  • 2.2.3 In-situ polymerization
  • 2.2.3.1 Metal nanoparticles
  • 2.2.3.2 Carbon nanotubes
  • 2.2.3.3 Graphene
  • 2.2.4 Electrospinning
  • 2.2.4.1 Metal nanoparticles
  • 2.2.4.2 Carbon nanotubes
  • 2.2.4.3 Graphene
  • 2.2.5 Electrochemically synthesized nanocomposites
  • 2.2.5.1 Metal nanoparticles
  • 2.2.5.2 Carbon nanotubes
  • 2.2.5.3 Graphene
  • 2.2.6 Layer-by-layer assembly
  • 2.2.6.1 Metal nanoparticles
  • 2.2.6.2 Carbon nanotubes
  • 2.2.6.3 Graphene
  • 2.2.7 In-situ chemical methods
  • 2.2.7.1 Metal nanoparticles
  • 2.2.7.2 Carbon nanotubes
  • 2.2.7.3 Graphene
  • 2.3 Conclusion
  • References
  • 3 Specific interactions in nanohybrid systems
  • 3.1 Introduction
  • 3.1.1 Overview of nanohybrid systems
  • 3.1.1.1 Synthesis of nanohybrid systems
  • 3.1.1.1.1 Physical methods
  • 3.1.1.1.2 Chemical methods
  • 3.1.1.2 Types of nanohybrid systems
  • 3.1.1.2.1 Organic-inorganic nanohybrids
  • 3.1.1.2.2 Inorganic-inorganic nanohybrids
  • 3.1.1.2.3 Hybrid nanomaterials with biomolecules
  • 3.1.1.3 Properties and characterization.
  • 3.1.1.3.1 Structural and morphological analysis
  • 3.1.1.3.2 Physical and chemical properties
  • 3.1.1.4 Applications of nanohybrid systems
  • 3.1.1.4.1 Energy and environment
  • 3.1.1.4.2 Electronics and optoelectronics
  • 3.1.1.4.3 Biomedical and healthcare
  • 3.1.1.4.4 Nanotechnology and nanoelectronics
  • 3.1.1.5 Challenges and future perspectives
  • 3.1.2 Importance of interactions in nanohybrid systems
  • 3.1.2.1 Synergistic effects
  • 3.1.2.2 Tailoring properties
  • 3.1.2.3 Stability and durability
  • 3.1.2.4 Energy transfer and conversion
  • 3.1.2.5 Responsive behavior
  • 3.1.3 Objectives of the chapter
  • 3.1.3.1 Characterizing interactions
  • 3.1.3.2 Interfacial phenomena
  • 3.1.3.3 Applications and functionalities
  • 3.1.3.4 Design and synthesis
  • 3.1.3.5 Future directions and challenges
  • 3.2 Fundamentals of nanohybrid systems
  • 3.2.1 Definition and characteristics of nanohybrid systems
  • 3.2.1.1 Definition of nanohybrid systems
  • 3.2.1.2 Characteristics of nanohybrid systems
  • 3.2.1.2.1 Enhanced properties
  • 3.2.1.2.2 Tunable properties
  • 3.2.1.2.3 Interface effects
  • 3.2.1.2.4 Multifunctionality
  • 3.2.1.2.5 Synergistic applications
  • 3.2.2 Types of nanohybrid systems
  • 3.2.2.1 Organic-inorganic nanohybrids
  • 3.2.2.1.1 Organic-inorganic hybrid nanoparticles
  • 3.2.2.1.2 Hybrid nanocomposites with organic matrix
  • 3.2.2.1.3 Organic-inorganic nanocomposite films
  • 3.2.2.1.4 Polymer-inorganic hybrid materials
  • 3.2.2.2 Inorganic-inorganic nanohybrids
  • 3.2.2.2.1 Metal-semiconductor hybrid nanomaterials
  • 3.2.2.3 Fundamental principles
  • 3.2.2.3.1 Metals
  • 3.2.2.3.2 Semiconductors
  • 3.2.2.3.3 Synergistic interactions
  • 3.2.2.3.4 Metal-oxide hybrid nanoparticles
  • 3.2.2.3.5 Semiconductor-oxide hybrid nanostructures
  • 3.2.2.3.6 Core-shell nanohybrids
  • 3.2.2.4 Hybrid nanomaterials with biomolecules.
  • 3.2.2.4.1 Protein-based nanohybrids
  • 3.2.2.4.2 DNA-functionalized nanomaterials
  • 3.2.2.4.3 Peptide-based nanohybrids
  • 3.2.2.4.4 Enzyme-nanomaterial hybrids
  • 3.2.3 Synthesis and fabrication methods of nanohybrid systems
  • 3.2.3.1 Physical methods
  • 3.2.3.1.1 Coprecipitation
  • 3.2.3.1.2 Sol-gel synthesis
  • 3.2.3.1.3 Hydrothermal/solvothermal methods
  • 3.2.3.1.4 Electrodeposition
  • 3.2.3.1.5 Laser ablation
  • 3.2.3.1.6 Physical vapor deposition
  • 3.2.3.2 Chemical methods
  • 3.2.3.2.1 Sequential deposition
  • 3.2.3.2.2 Self-assembly
  • 3.2.3.2.3 Surface modification and functionalization
  • 3.2.3.2.4 Covalent or noncovalent linkage
  • 3.2.3.2.5 Layer-by-layer assembly
  • 3.2.3.2.6 Polymer blending
  • 3.3 Interactions in nanohybrid systems
  • 3.3.1 Physical interactions
  • 3.3.1.1 Van der Waals interactions
  • 3.3.1.2 Electrostatic interactions
  • 3.3.1.3 Hydrogen bonding
  • 3.3.1.4 Magnetic interactions
  • 3.3.1.5 Optical interactions
  • 3.3.1.6 Phonon interactions
  • 3.3.1.7 Surface interactions
  • 3.3.2 Mechanical interactions
  • 3.3.3 Thermal interactions
  • 3.3.4 Optical interactions
  • 3.3.5 Chemical interactions
  • 3.3.5.1 Surface chemistry and interface interactions
  • 3.3.5.2 Chemical reactions and catalytic interactions
  • 3.3.6 Electrical and electronic interactions
  • 3.3.6.1 Electronic structure and charge transfer interactions
  • 3.3.6.2 Electrical conductivity and dielectric interactions
  • 3.4 Characterization techniques for studying interactions
  • 3.4.1 Spectroscopic techniques
  • 3.4.1.1 UV-visible spectroscopy
  • 3.4.1.2 Fourier-transform infrared spectroscopy spectroscopy
  • 3.4.1.3 Raman spectroscopy
  • 3.4.2 Microscopy techniques
  • 3.4.2.1 Scanning electron microscopy
  • 3.4.2.2 Transmission electron microscopy
  • 3.4.2.3 Atomic force microscopy
  • 3.4.2.4 Scanning tunneling microscopy.