Metal-Organic Frameworks in Analytical Sample Preparation and Sensing /

Metal-organic Frameworks in Analytical Sample Preparation and Sensing presents all the areas of applications of metal-organic frameworks in analytical sample preparation.Metal-organic frameworks are crystalline coordination polymers with robust and stable crystal structures, high synthetic tunabilit...

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Bibliographic Details
Corporate Author:	ScienceDirect (Online service)
Format:	eBook
Language:	English
Published:	Amsterdam, Netherlands ; London, United Kingdom ; Cambridge MA : Elsevier, [2024]
Subjects:	Metal-organic frameworks. Sample preparation (Chemistry) Préparation de l'échantillon (Chimie) Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Front Cover
Metal-Organic Frameworks in Analytical Sample Preparation and Sensing
Copyright Page
Contents
List of contributors
Acknowledgments
I. Reticular materials: synthesis, characterization, and properties
1 Introduction and general aspects of metal-organic frameworks and other novel reticular materials
1.1 Interest of reticular materials
1.2 Historical development of metal- and covalent-organic frameworks
1.3 Metal-organic frameworks: generic aspects and considerations for their applicability in analytical chemistry
1.4 Covalent-organic frameworks: generic aspects and considerations for their applicability in analytical chemistry
1.5 Adequate characterization of MOFs and COFs: X-ray diffraction and adsorption techniques
1.6 Analytical chemistry applications of MOFs and COFs
1.7 Conclusion
Acknowledgments
References
2 Synthesis of metal-organic frameworks with interest in analytical chemistry
2.1 Introduction
2.2 General concepts
2.3 New synthesis approach
2.3.1 Solvo(hydro)thermal
2.3.2 Electrochemical synthesis
2.3.3 Sonochemical
2.3.4 Mechanochemical
2.3.5 Microwave
2.4 MOF synthesis with interest in the electrochemical sensor
2.5 MOF synthesis with interest in the separation and sample preparation
2.5.1 Membrane
2.5.2 Chromatography
2.6 Summary and outlook
2.6.1 AI disclosure
References
3 Synthesis of composites based on reticular materials with interest in analytical chemistry
3.1 Introduction
3.2 Reticular materials and nanoparticles composites
3.2.1 Reticular materials and magnetic nanoparticles
3.2.2 Reticular materials and non-magnetic nanoparticles
3.3 Reticular materials and polymers composites
3.4 Reticular materials and molecularly imprinted polymers composites.
7.2.1 MOF-based on-fiber SPME coatings
7.2.1.1 Pretreatment of substrates
7.2.1.2 In situ methods
7.2.1.3 Adhesion and sol-gel methods
7.2.1.4 Chemical bonding
7.2.1.5 Electrodeposition method
7.2.2 MOF-based in-tube SPME coatings
7.3 Application of MOFs in SPME
7.4 Conclusion and future remarks
References
8 Metal-organic frameworks in thin film microextraction
8.1 Thin films: general overview
8.2 TF solid-phase microextraction
8.3 Preparation of MOF-TFs
8.3.1 Chemical methods to prepare MOFs-TFs
8.3.1.1 Preparation of MOF-TFs by vapor-phase deposition
8.3.1.2 Solvothermal deposition in liquid phase
8.3.1.3 Preparation of MOF-TFs by LBL
8.3.1.4 Preparation of MOF-TFs by electrochemical deposition
8.3.1.5 Other chemical deposition methods
8.3.2 Physical methods to prepare MOFs-TFs
8.3.2.1 Spin coating
8.3.2.2 Bar coating
8.3.2.3 Dip coating
8.4 MOFs-TFs in TFME
8.5 Applications of MOF-TFs in TFME
Abbreviations
References
9 Hyphenating microextraction using metal-organic frameworks with separation and detection techniques
9.1 Introduction
9.2 Flow-through microextraction techniques
9.2.1 Online (micro)solid-phase extraction
9.2.2 In-tube solid-phase microextraction
9.3 Batch microextraction techniques
9.4 Conclusions and future perspectives
Acknowledgments
Abbreviations
References
III. Metal-organic frameworks as sensors for analysis
10 Metal-organic frameworks as luminescent sensors
10.1 Introduction
10.2 Luminescence in metal-organic frameworks
10.3 Designing of LMOFs
10.4 Detection of hazardous organic pollutants
10.4.1 Detection of antibiotics and pesticides
10.4.2 Detection of nitroaromatic explosives
10.4.3 Toxic small molecules
10.4.4 LMOF-based sensors for air pollutants
10.4.4.1 Hydrogen sulfide.
10.4.4.2 Nitric oxide (NO)
10.4.4.3 Sulfur dioxide (SO2)
10.4.4.4 Ammonia (NH3)
10.4.5 Other applications
10.5 Summary
10.6 Conclusion and outlook
Acknowledgments
References
11 Metal-organic frameworks as electrochemical sensors
11.1 Introduction
11.2 Metal-organic framework-based electrochemical sensors for analytes from liquid phase
11.2.1 Pristine metal-organic frameworks
11.2.1.1 Co-organic frameworks
11.2.1.2 Cu-organic frameworks
11.2.1.3 Ni-organic frameworks
11.2.1.4 Metal-organic frameworks based on other metal elements
11.2.1.5 Metal-organic framework-based on mixed-metal sites
11.2.2 Metal-organic framework composites
11.2.2.1 Metal-organic framework on metal-organic framework
11.2.2.2 Metal nanoparticles@metal-organic framework
11.2.2.3 Metal oxide nanoparticles@metal-organic framework
11.2.2.4 Metal-organic frameworks immobilized with other components
11.2.2.5 Metal-organic framework-carbon composites
11.2.3 Metal-organic framework-derived materials
11.2.3.1 Metal-organic framework-derived metal nanoparticles
11.2.3.2 Metal-organic framework-derived metal oxides
11.2.3.3 Metal-organic framework-derived carbon-based materials
11.3 Metal-organic framework-based electrochemical sensors for analytes from gas phase
11.3.1 Pristine metal-organic framework
11.3.1.1 Metal-organic framework with low electrical conductivity
11.3.1.2 Conductive metal-organic framework
11.3.2 Metal-organic framework composites
11.3.2.1 Metal nanoparticles@metal-organic framework
11.3.2.2 Metal oxide@metal-organic framework
11.3.3 Metal-organic framework-derived materials
11.3.3.1 Metal-organic framework-derived metal oxide
11.3.3.2 Metal-organic framework-derived carbon-based materials
11.4 Summary and outlook
References.
IV. Novel reticular materials in analytical sample preparation and sensing synthesis and applications of covalent-or...
12 Synthesis of covalent-organic frameworks and applications in analytical chemistry
12.1 Introduction
12.2 Design and synthesis of covalent-organic frameworks
12.2.1 Solvothermal synthesis
12.2.2 Ionothermal synthesis
12.2.3 Microwave-assisted synthesis
12.2.4 Ultrasound-assisted synthesis
12.2.5 Mechanochemical synthesis
12.2.6 Interfacial synthesis
12.2.7 Ambient conditions syntheses
12.3 Application of covalent-organic frameworks as sorbents in sample preparation
12.3.1 Solid-phase extraction
12.3.2 Dispersive solid-phase extraction
12.3.3 Solid-phase microextraction
12.3.4 Other sorbent-based microextraction techniques
12.4 Conclusions
Acknowledgments
References
13 Covalent-organic frameworks for luminescent sensors
13.1 Introduction
13.2 Explosives
13.3 Heavy metals
13.3.1 Mercury
13.3.2 Iron
13.3.3 Copper
13.3.4 Other metal cations
13.4 Biological molecules
13.5 pH
13.6 Volatile organic compounds (VOCs), amines and water
13.6.1 Anions
13.6.2 Enantiomers
13.7 Conclusion and future perspectives
13.8 Funding Sources
References
Index
Back Cover.