Recent advances in organometallic chemistry : synthetic, mechanistic and medicinal perspective /

Recent Advances in Organometallic Chemistry: Synthetic, Mechanistic and Medicinal Perspective highlights recent advancements in the field of organometallic chemistry.Containing essential information for researchers and advanced-level students, especially those working in chemical synthesis, the book...

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Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Ansari, Azaj, Kumar, Vinod
Format: eBook
Language:English
Published: Amsterdam : Elsevier, 2024.
Subjects:
Online Access:Connect to the full text of this electronic book

MARC

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505 8 |a 5.3.2 Iron-catalyzed C-H activation -- 5.3.3 Rhodium-catalyzed C-H activation -- 5.4 Future prospective and scope -- 5.5 Summary -- References -- 6 Organotransition metal chemistry in asymmetric catalysis mediated by different transition metal N-heterocyclic carbene co... -- 6.1 Introduction -- 6.2 Fundamental principles -- 6.3 Common methods of preparation -- 6.4 Mechanism involved -- 6.5 Recent developments with examples -- 6.6 Applications in emerging fields -- 6.7 Future prospective and scope -- 6.8 Summary -- 6.9 Problems with solutions -- 6.10 Objective type questions -- References -- 7 Organophosphorus compounds: recent developments and future perspective -- 7.1 Introduction -- 7.2 Fundamental principles -- 7.2.1 Phosphorus-based ligands -- 7.2.2 Classification of phosphorus-based ligands -- 7.3 Common methods of preparation -- 7.3.1 Pincer ligands -- 7.3.2 Synthesis of pincer complexes -- 7.3.2.1 C-H bond activation -- 7.3.3 Oxidative addition to aryl halide bond -- 7.3.4 Trans-metallation -- 7.3.5 Trans-cyclometallation -- 7.4 Classification of pincer complexes -- 7.4.1 Transition metal chemistry of pincer ligands -- 7.4.1.1 PCP pincer complexes -- 7.4.1.2 PNP pincer complexes -- 7.4.2 Application of tridentate chelating pincer complexes in catalysis -- 7.4.2.1 Heck cross-coupling reactions -- 7.4.2.2 Asymmetric allylation of sulfonimines -- 7.4.2.3 Hydrophosphination reaction -- 7.4.3 Chiral tridentate chelating pincer complexes -- 7.4.4 Aminophosphines -- 7.4.4.1 Cyclodiphosphazanes -- 7.4.4.2 Cis/trans isomerization -- 7.4.4.3 Synthesis of cyclodiphosphazanes -- 7.4.4.4 Reactivity of cyclodiphosphazanes -- 7.4.4.5 Macrocyclic cyclodiphosphazane derivatives -- 7.4.5 Phosphacyclophanes -- 7.5 Summary -- 7.6 Problems with solutions -- 7.7 Objective-type questions -- References. 
505 8 |a 8 Synthesis of silicon and germanium organometallic compounds and their applications in catalysis -- 8.1 Introduction -- 8.2 Synthesizing of silicon and germanium organometallic compounds -- 8.2.1 Direct synthesis -- 8.2.2 Hydrosilylation -- 8.2.3 Silenes -- 8.2.4 Silicones, silyl ethers, silanols, siloxanes, and siloxides -- 8.2.5 Bonding through carbon -- 8.3 Catalysis -- 8.4 Future prospective and scope -- 8.5 Summary -- 8.6 Problems with solutions -- 8.7 Objective type questions -- References -- 9 Sensing application of organometallic compounds -- 9.1 Introduction -- 9.2 Fundamental principles -- 9.3 Common methods of preparation -- 9.4 Mechanism involved -- 9.4.1 Ligand substitution -- 9.4.2 Oxidative addition -- 9.4.3 Concerted track based -- 9.5 Recent developments with examples -- 9.6 Applications in emerging fields -- 9.6.1 Chemical sensor -- 9.6.2 Gas sensor -- 9.6.3 Optical sensor -- 9.6.4 Biochemical sensor -- 9.7 Future prospective and scope -- 9.8 Summary -- 9.9 Problems with solutions -- 9.10 Objective type questions -- References -- 10 Bioorganometallic chemistry: a new horizon on organometallic landscape -- 10.1 Introduction -- 10.2 Shift from platinum metal based therapeutics to other bio-compatible less toxic nonplatinum complexes -- 10.2.1 Anticancerous properties of iron complexes -- 10.2.2 Anticancer properties of copper complexes -- 10.2.3 Anticancer properties of ruthenium complexes -- 10.2.3.1 Substitution modulated anticancer activity of Half-sandwich ruthenium (II) complexes with heterocyclic ancillary l... -- 10.2.4 Anticancer properties of gold complexes -- 10.2.5 Anticancer properties of rhodium and iridium complexes -- 10.3 Organoselenium compounds as potent chemotherapeutic agents -- 10.3.1 Inorganic selenium compounds -- 10.3.2 Organic selenium compounds -- 10.3.3 Selenocysteine -- 10.3.4 Selol. 
505 8 |a 10.3.5 Seleninic acids -- 10.3.6 Selenophene-based derivatives -- 10.3.7 1,2-Benzisoselenazole-3[2H]-one derivatives -- 10.3.8 Analysis of anticancer property of selenium-bearing 4-anilinoquinazoline compounds -- 10.3.8.1 Anticancer agent -- 10.3.9 Evaluation of indole chalcone and diarylketone derivatives containing selenium as tubulin polymerization inhibitory ... -- 10.3.9.1 Effect of diarylketone selenium derivative(compound-36) on the advancement of cell apoptosis -- 10.3.10 Chemopreventive applications of isoselenocyanate compounds -- 10.4 Other biological activities of organoselenium compounds -- 10.4.1 GPx activity -- 10.4.1.1 Catalytic GPx-like activity of 2,7-dialkoxy-substituted naphthalene-1,8-peri diselenides -- 10.4.1.2 pH-sensitive organoselenium compounds as pH-responsive glutathione peroxidase mimics -- 10.4.1.2.1 Mechanistic study -- 10.4.1.3 Enhanced activity as glutathione peroxidase mimics when benzo[d]isoselenazol-3-ones are combined with sterically h... -- 10.4.2 Anti-Alzheimer activity -- 10.4.2.1 Selenyl-dihydrofurans as anti-Alzheimer agents -- 10.4.2.2 Selenodihydropyrimidinones as potential multi-targeted treatments for Alzheimer's disease -- 10.4.2.3 AChE inhibitory activity -- 10.4.3 Cytoprotection -- 10.4.3.1 Organoselenium antioxidant compounds with cytoprotective effects -- 10.4.3.2 Bromo substituted diselenide compounds potential to scavenge ROS -- 10.4.4 Insecticidal activity -- 10.4.4.1 Selenoethers and their insecticidal activities -- 10.4.4.2 2,2-Difluoro-1,3-benzoxathioles (selenoles)with insecticidal activities -- 10.4.4.3 Selenium-containing imidazolium ionic liquids with antibacterial activity -- 10.4.4.4 Cyclization of Z-selenoenynes by iron(III)-PhSeSePh results in selenophenes with antidepressant-like activity -- 10.5 Different plausible mechanisms of action for bioorganometallic complexes. 
520 |a Recent Advances in Organometallic Chemistry: Synthetic, Mechanistic and Medicinal Perspective highlights recent advancements in the field of organometallic chemistry.Containing essential information for researchers and advanced-level students, especially those working in chemical synthesis, the book describes the role of organometallic compounds. 
650 0 |a Organometallic chemistry. 
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700 1 |a Kumar, Vinod. 
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