Green imprinted materials : from design to environmental and food applications /

Green Imprinted Materials provides a comprehensive overview of green aspects to MIPs.With a strong focus on food and environment, this book provides insights into the state-of-the-art and practice of green chemistry and its approaches to imprinting.Methodologies for the preparation of these material...

Full description

Bibliographic Details
Corporate Author:	ScienceDirect (Online service)
Other Authors:	Hussain, Chaudhery Mustansar (Editor), Kec̦ili, Rustem (Editor)
Format:	eBook
Language:	English
Published:	Amsterdam, Netherlands : Elsevier, [2024]
Subjects:	Imprinted polymers. Green chemistry. Polymères à empreintes moléculaires. Chimie verte. Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Front Cover
Green Imprinted Materials
Green Imprinted Materials: From Design to Environmental and Food Applications
Copyright
Contents
List of contributors
Preface
1
Introduction
1
Green and sustainable chemistry
1. Introduction
2. Green chemistry
2.1 Prevention
2.2 Atom economy
2.3 Less hazardous chemical synthesis
2.4 Designing safer chemicals
2.5 Safer solvents and auxiliaries
2.6 Design for energy efficiency
2.7 Use of renewable feedstocks
2.8 Reduce derivatives
2.9 Catalysis
2.10 Design for degradation
2.11 Real-time analysis
2.12 Safer chemistry for accident prevention
3. Sustainable chemistry
3.1 Benefits of sustainable chemistry
3.2 Sustainable chemistry R&amp
D
3.2.1 Green solvents
3.2.2 Biodegradable polymers
3.2.3 Renewable energy sources
3.2.4 Carbon capture and utilization
3.2.5 Water treatment technologies
3.2.6 Green nanotechnology
4. Conclusions and future perspective
References
Further reading
2
Basics of affinity and its importance in designing molecularly imprinted polymers
1. What is affinity?
2. Parameters in affinity interactions
3. Inspiration from life
4. Intersection of affinity and MIPs
4.1 How are MIPs designed?
4.2 Where are MIPs needed?
5. Recent approaches in MIPs
6. Concluding remarks
References
3
Green approaches for the preparation of molecularly imprinted polymers
1. Introduction
2. Green approaches for the preparation of molecularly imprinted polymers
2.1 Microwave-assisted synthesis
2.2 Supercritical fluid technology
2.3 Ultrasound-assisted synthesis
2.4 Green precipitation polymerization technique
2.5 Green emulsion polymerization technique
2.6 Green electrochemical polymerization technique
2.7 Green precursors for MIPs.
2.7.1 Bio-based functional monomers
2.7.2 Ionic liquids
2.7.3 Deep eutectic solvents
2.8 Green template removal
3. Conclusions
References
2
Green MIPs in sample pretreatment
4
Green molecularly imprinted polymers for the adsorption and enrichment of pesticides
1. Introduction
2. Types of commonly analyzed pesticides
3. Green MIPs approaches for pesticide recognition
3.1 Dummy template
3.2 Multitemplate imprinting
3.3 Computational approach
3.4 Green solvents
3.5 Green polymerization techniques
3.6 Simultaneous determination
3.7 Ionic liquids
3.8 Magnetic MIPs
4. Conclusions and future trends
Acknowledgment
References
5
Green ion-imprinted polymers
1. Introduction
2. The overview of ion-imprinted polymers
3. Basic green components for the synthesis of IIPs
3.1 Template
3.2 Functional monomers
3.3 Porogens
4. Green strategy for the ion-imprinting polymerization
4.1 Bulk polymerization
4.2 Suspension polymerization
4.3 Precipitation polymerization
5. Computational approach
6. Conclusions and future perspective
References
6
Development of green molecularly imprinted polymers for the treatment of wastewater samples
1. Introduction
1.1 Historical development of molecular imprinting toward functional polymers
1.2 Molecularly imprinted polymers
1.3 Different approaches and features for MIPs
1.4 Approach and methods in MIPs production
2. Green molecularly imprinted polymers
2.1 Green chemistry
2.2 Green monomer
2.3 Green solvents/porogens
2.4 Green template
2.5 Green crosslinker
3. Conclusions
References
7
Green MIPs as powerful sorbents for the detection and determination of pharmaceuticals
1. Sorbents and their importance
1.1 An introduction to sorbents.
1.2 Characteristics of an ideal sorbent
1.3 Importance of pharmaceutical analysis
2. Green chemistry
2.1 Introduction
2.2 Twelve principles of green chemistry
2.3 Application of green chemistry
3. Molecularly imprinted polymers
3.1 MIP sorbents and their advantages
3.2 Green MIPs
3.3 Greenification of MIPs
4. Solvents and their roles
4.1 Greenification of solvents as porogens
4.1.1 Water and alcohols
4.1.2 Ionic liquids
4.1.3 Deep eutectic solvents
4.1.4 Supercritical fluid carbon dioxide (scCO2)
4.2 Greenification of solvent as the extraction tool
4.2.1 Microextraction technique
5. Greenification of MIP compositions
5.1 Functional monomers
5.1.1 Silica
5.1.2 Ionic liquids
5.1.3 Biomass-derived materials
5.1.4 Bio-based materials
5.1.5 Biocompatible small molecules
5.1.6 Self-polymerizable monomers
5.1.7 Deep eutectic solvent
5.2 Templates
5.2.1 Multitemplate MIPs
5.2.2 Dummy-template MIPs
5.3 Crosslinking agent
6. Greenification based on computational analysis
6.1 Introduction
6.2 Technical methods used for molecular calculations
6.2.1 Molecular mechanics
6.2.2 2- Molecular dynamics
6.2.3 Quantum mechanics
6.3 Computational calculation software
7. Online analysis
8. Future looks and conclusion
References
3
Green MIPs in separation/identification stage of analysis
8
Green MIPs in food analysis
1. Introduction
1.1 Conventional MIP synthesis techniques
1.2 Importance of MIPs in various research area
2. Green MIPs
2.1 Green strategies in MIP synthesis
2.1.1 Supercritical fluid technology
2.1.2 Usage of 3D-imprinted porous samples
2.1.3 Usage of ionic liquids
2.1.4 Ultrasound- and microwave-assisted MIP synthesis
3. Green MIPs in food analysis
3.1 Contaminant analysis in foods.
3.1.1 Mycotoxin detection
3.1.2 Pesticide detection
3.1.3 Antibiotic residue detection
3.2 Food additive analysis in foods
4. Conclusion
Abbreviations
References
9
Green magnetic core-shell MIPs for environmental applications
1. Introduction
2. Preparation of green magnetic core-shell MIPs
3. Removal/detection of environmental pollutants with green magnetic core-shell MIPs
3.1 Removal/detection of heavy metals with green magnetic core-shell MIPs
3.2 Removal/detection of dyes with green magnetic core-shell MIPs
3.3 Removal/detection of pesticides with green magnetic core-shell MIPs
3.4 Removal/detection of pharmaceuticals and other organic compounds with green magnetic core-shell MIPs
3.5 Decompositions of harmful substances using MMIPs
4. Conclusions
References
10
Design, preparation, and applications of green molecularly imprinted membranes
1. Introduction
2. Techniques for the preparation of molecularly imprinted membranes
2.1 In-situ polymerization technique
2.2 Phase inversion polymerization technique
2.3 Sol-gel polymerization technique
2.4 Emulsion polymerization technique
2.5 Electrochemical polymerization technique
2.6 Surface grafting technique
2.7 Electrospinning technique
3. Environmental and food applications of green MIMs
3.1 Environmental applications
3.2 Food applications
4. Conclusions
References
4
Green MIPs in detection stage of analysis/miniaturization of devices
11
Green MIPs for the detection of food allergens
1. Introduction
2. Food allergen
2.1 Milk allergy
2.2 Egg allergens
2.3 Seafood allergens
2.4 Peanut allergens
3. Molecularly imprinted polymer
3.1 Molecular imprinting process
4. Sensors
5. Applications of MIP-based sensors for food allergens
6. Conclusion
References.
12
Electrochemical sensors based on green molecularly imprinted polymers
1. Introduction
1.1 Introduction to EC sensors
1.2 Desirable EC sensor's characteristics in green chemistry
1.3 Introduction to EC sensor's modifiers
1.4 Summary of EC applications
2. MIPs and their incorporation into EC sensors
3. Green MIPs
3.1 Introduction to green chemistry
3.2 Moving from conventional to green MIPs
4. Recent greenification advances in MIP-based EC sensors
4.1 Synthesis steps
4.1.1 Green reagents in MIP-based EC development
4.1.2 Green MIP-based EC polymerization techniques
4.2 Miniaturization
4.3 Computational strategies
5. Conclusions
List of acronyms
References
13
Optical sensors based on green molecularly imprinted polymers
1. Introduction
2. Green MIP-based fluorescent sensors
3. Food and environmental applications of green MIP-based fluorescent sensors
4. Conclusions and future perspective
References
14
Molecularly imprinted polymer (MIP)-coated green carbon dots-based sensing platforms
1. Introduction
2. Green carbon dots
3. Green synthesis approaches of CDs
3.1 Hydrothermal technique
3.2 Microwave irradiation technique
3.3 Ultrasonic technique
3.4 Chemical oxidation technique
4. Applications of MIP-coated green CD-based sensors
4.1 Food applications
4.2 Environmental applications
5. Conclusions
References
Index
Back Cover.