Green imprinted materials : from design to environmental and food applications /

Green Imprinted Materials provides a comprehensive overview of green aspects to MIPs.With a strong focus on food and environment, this book provides insights into the state-of-the-art and practice of green chemistry and its approaches to imprinting.Methodologies for the preparation of these material...

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Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Hussain, Chaudhery Mustansar (Editor), Kec̦ili, Rustem (Editor)
Format: eBook
Language:English
Published: Amsterdam, Netherlands : Elsevier, [2024]
Subjects:
Online Access:Connect to the full text of this electronic book

MARC

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505 0 |a Front Cover -- Green Imprinted Materials -- Green Imprinted Materials: From Design to Environmental and Food Applications -- Copyright -- Contents -- List of contributors -- Preface -- 1 -- Introduction -- 1 -- Green and sustainable chemistry -- 1. Introduction -- 2. Green chemistry -- 2.1 Prevention -- 2.2 Atom economy -- 2.3 Less hazardous chemical synthesis -- 2.4 Designing safer chemicals -- 2.5 Safer solvents and auxiliaries -- 2.6 Design for energy efficiency -- 2.7 Use of renewable feedstocks -- 2.8 Reduce derivatives -- 2.9 Catalysis -- 2.10 Design for degradation -- 2.11 Real-time analysis -- 2.12 Safer chemistry for accident prevention -- 3. Sustainable chemistry -- 3.1 Benefits of sustainable chemistry -- 3.2 Sustainable chemistry R&amp -- D -- 3.2.1 Green solvents -- 3.2.2 Biodegradable polymers -- 3.2.3 Renewable energy sources -- 3.2.4 Carbon capture and utilization -- 3.2.5 Water treatment technologies -- 3.2.6 Green nanotechnology -- 4. Conclusions and future perspective -- References -- Further reading -- 2 -- Basics of affinity and its importance in designing molecularly imprinted polymers -- 1. What is affinity? -- 2. Parameters in affinity interactions -- 3. Inspiration from life -- 4. Intersection of affinity and MIPs -- 4.1 How are MIPs designed? -- 4.2 Where are MIPs needed? -- 5. Recent approaches in MIPs -- 6. Concluding remarks -- References -- 3 -- Green approaches for the preparation of molecularly imprinted polymers -- 1. Introduction -- 2. Green approaches for the preparation of molecularly imprinted polymers -- 2.1 Microwave-assisted synthesis -- 2.2 Supercritical fluid technology -- 2.3 Ultrasound-assisted synthesis -- 2.4 Green precipitation polymerization technique -- 2.5 Green emulsion polymerization technique -- 2.6 Green electrochemical polymerization technique -- 2.7 Green precursors for MIPs. 
505 8 |a 2.7.1 Bio-based functional monomers -- 2.7.2 Ionic liquids -- 2.7.3 Deep eutectic solvents -- 2.8 Green template removal -- 3. Conclusions -- References -- 2 -- Green MIPs in sample pretreatment -- 4 -- Green molecularly imprinted polymers for the adsorption and enrichment of pesticides -- 1. Introduction -- 2. Types of commonly analyzed pesticides -- 3. Green MIPs approaches for pesticide recognition -- 3.1 Dummy template -- 3.2 Multitemplate imprinting -- 3.3 Computational approach -- 3.4 Green solvents -- 3.5 Green polymerization techniques -- 3.6 Simultaneous determination -- 3.7 Ionic liquids -- 3.8 Magnetic MIPs -- 4. Conclusions and future trends -- Acknowledgment -- References -- 5 -- Green ion-imprinted polymers -- 1. Introduction -- 2. The overview of ion-imprinted polymers -- 3. Basic green components for the synthesis of IIPs -- 3.1 Template -- 3.2 Functional monomers -- 3.3 Porogens -- 4. Green strategy for the ion-imprinting polymerization -- 4.1 Bulk polymerization -- 4.2 Suspension polymerization -- 4.3 Precipitation polymerization -- 5. Computational approach -- 6. Conclusions and future perspective -- References -- 6 -- Development of green molecularly imprinted polymers for the treatment of wastewater samples -- 1. Introduction -- 1.1 Historical development of molecular imprinting toward functional polymers -- 1.2 Molecularly imprinted polymers -- 1.3 Different approaches and features for MIPs -- 1.4 Approach and methods in MIPs production -- 2. Green molecularly imprinted polymers -- 2.1 Green chemistry -- 2.2 Green monomer -- 2.3 Green solvents/porogens -- 2.4 Green template -- 2.5 Green crosslinker -- 3. Conclusions -- References -- 7 -- Green MIPs as powerful sorbents for the detection and determination of pharmaceuticals -- 1. Sorbents and their importance -- 1.1 An introduction to sorbents. 
505 8 |a 1.2 Characteristics of an ideal sorbent -- 1.3 Importance of pharmaceutical analysis -- 2. Green chemistry -- 2.1 Introduction -- 2.2 Twelve principles of green chemistry -- 2.3 Application of green chemistry -- 3. Molecularly imprinted polymers -- 3.1 MIP sorbents and their advantages -- 3.2 Green MIPs -- 3.3 Greenification of MIPs -- 4. Solvents and their roles -- 4.1 Greenification of solvents as porogens -- 4.1.1 Water and alcohols -- 4.1.2 Ionic liquids -- 4.1.3 Deep eutectic solvents -- 4.1.4 Supercritical fluid carbon dioxide (scCO2) -- 4.2 Greenification of solvent as the extraction tool -- 4.2.1 Microextraction technique -- 5. Greenification of MIP compositions -- 5.1 Functional monomers -- 5.1.1 Silica -- 5.1.2 Ionic liquids -- 5.1.3 Biomass-derived materials -- 5.1.4 Bio-based materials -- 5.1.5 Biocompatible small molecules -- 5.1.6 Self-polymerizable monomers -- 5.1.7 Deep eutectic solvent -- 5.2 Templates -- 5.2.1 Multitemplate MIPs -- 5.2.2 Dummy-template MIPs -- 5.3 Crosslinking agent -- 6. Greenification based on computational analysis -- 6.1 Introduction -- 6.2 Technical methods used for molecular calculations -- 6.2.1 Molecular mechanics -- 6.2.2 2- Molecular dynamics -- 6.2.3 Quantum mechanics -- 6.3 Computational calculation software -- 7. Online analysis -- 8. Future looks and conclusion -- References -- 3 -- Green MIPs in separation/identification stage of analysis -- 8 -- Green MIPs in food analysis -- 1. Introduction -- 1.1 Conventional MIP synthesis techniques -- 1.2 Importance of MIPs in various research area -- 2. Green MIPs -- 2.1 Green strategies in MIP synthesis -- 2.1.1 Supercritical fluid technology -- 2.1.2 Usage of 3D-imprinted porous samples -- 2.1.3 Usage of ionic liquids -- 2.1.4 Ultrasound- and microwave-assisted MIP synthesis -- 3. Green MIPs in food analysis -- 3.1 Contaminant analysis in foods. 
505 8 |a 3.1.1 Mycotoxin detection -- 3.1.2 Pesticide detection -- 3.1.3 Antibiotic residue detection -- 3.2 Food additive analysis in foods -- 4. Conclusion -- Abbreviations -- References -- 9 -- Green magnetic core-shell MIPs for environmental applications -- 1. Introduction -- 2. Preparation of green magnetic core-shell MIPs -- 3. Removal/detection of environmental pollutants with green magnetic core-shell MIPs -- 3.1 Removal/detection of heavy metals with green magnetic core-shell MIPs -- 3.2 Removal/detection of dyes with green magnetic core-shell MIPs -- 3.3 Removal/detection of pesticides with green magnetic core-shell MIPs -- 3.4 Removal/detection of pharmaceuticals and other organic compounds with green magnetic core-shell MIPs -- 3.5 Decompositions of harmful substances using MMIPs -- 4. Conclusions -- References -- 10 -- Design, preparation, and applications of green molecularly imprinted membranes -- 1. Introduction -- 2. Techniques for the preparation of molecularly imprinted membranes -- 2.1 In-situ polymerization technique -- 2.2 Phase inversion polymerization technique -- 2.3 Sol-gel polymerization technique -- 2.4 Emulsion polymerization technique -- 2.5 Electrochemical polymerization technique -- 2.6 Surface grafting technique -- 2.7 Electrospinning technique -- 3. Environmental and food applications of green MIMs -- 3.1 Environmental applications -- 3.2 Food applications -- 4. Conclusions -- References -- 4 -- Green MIPs in detection stage of analysis/miniaturization of devices -- 11 -- Green MIPs for the detection of food allergens -- 1. Introduction -- 2. Food allergen -- 2.1 Milk allergy -- 2.2 Egg allergens -- 2.3 Seafood allergens -- 2.4 Peanut allergens -- 3. Molecularly imprinted polymer -- 3.1 Molecular imprinting process -- 4. Sensors -- 5. Applications of MIP-based sensors for food allergens -- 6. Conclusion -- References. 
505 8 |a 12 -- Electrochemical sensors based on green molecularly imprinted polymers -- 1. Introduction -- 1.1 Introduction to EC sensors -- 1.2 Desirable EC sensor's characteristics in green chemistry -- 1.3 Introduction to EC sensor's modifiers -- 1.4 Summary of EC applications -- 2. MIPs and their incorporation into EC sensors -- 3. Green MIPs -- 3.1 Introduction to green chemistry -- 3.2 Moving from conventional to green MIPs -- 4. Recent greenification advances in MIP-based EC sensors -- 4.1 Synthesis steps -- 4.1.1 Green reagents in MIP-based EC development -- 4.1.2 Green MIP-based EC polymerization techniques -- 4.2 Miniaturization -- 4.3 Computational strategies -- 5. Conclusions -- List of acronyms -- References -- 13 -- Optical sensors based on green molecularly imprinted polymers -- 1. Introduction -- 2. Green MIP-based fluorescent sensors -- 3. Food and environmental applications of green MIP-based fluorescent sensors -- 4. Conclusions and future perspective -- References -- 14 -- Molecularly imprinted polymer (MIP)-coated green carbon dots-based sensing platforms -- 1. Introduction -- 2. Green carbon dots -- 3. Green synthesis approaches of CDs -- 3.1 Hydrothermal technique -- 3.2 Microwave irradiation technique -- 3.3 Ultrasonic technique -- 3.4 Chemical oxidation technique -- 4. Applications of MIP-coated green CD-based sensors -- 4.1 Food applications -- 4.2 Environmental applications -- 5. Conclusions -- References -- Index -- Back Cover. 
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