Porous coordination polymers : from fundamentals to advanced applications /

Porous Coordination Polymers: From Fundamentals to Advanced Applications brings together the latest advances in Porous Coordination Polymers (PCPs) for cutting-edge applications. The book begins by introducing PCPs, highlighting their structure, chemistry, basic properties and design approaches. Thi...

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Bibliographic Details
Corporate Author:	ScienceDirect (Online service)
Other Authors:	Goel, Nidhi (Editor), Kim, Ki-Hyun (Editor)
Format:	eBook
Language:	English
Published:	Amsterdam : Elsevier, 2024.
Subjects:	Coordination polymers. Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Front Cover
Porous Coordination Polymers
Copyright Page
Contents
List of contributors
About the editors
1 Porous coordination polymers: a brief introduction
1.1 Introduction
1.2 Classification of PCPs
1.2.1 Structural properties
1.2.2 Phases of synthesis
1.2.3 Crystal structure arrangement
1.2.4 Based on stimuli
1.3 Structural aspects
1.3.1 Primary building units
1.3.2 Secondary building units
1.4 Properties
1.5 Conclusions
References
2 Approaches toward the synthesis and mechanical properties of porous coordination polymers
2.1 Introduction
2.2 Design and analysis
2.2.1 Design of porous coordination polymers
2.2.1.1 Framework
2.2.1.2 Molecular metal-organic hybrid
2.2.1.3 Porosity
2.2.2 Lewis acidic frameworks
2.2.3 Soft porous crystals
2.3 Synthetic methods
2.3.1 Conventional solvothermal/hydrothermal and nonsolvothermal methods
2.3.2 Unconventional methods
2.3.3 Alternative synthesis methods
2.3.3.1 Microwave-assisted synthesis
2.3.3.2 Electrochemical synthesis
2.3.3.3 Sonochemical synthesis
2.3.3.4 Layer-by-layer synthesis
2.3.3.5 Ionothermal method
2.3.3.6 Postsynthetic modification
2.3.3.7 Ball milling
2.3.4 Spray dryer
2.3.5 Sol-gel
2.3.6 Supercritical
2.3.7 Flow chemistry
2.4 Factors affecting the synthesis of PCPs
2.4.1 Solvents
2.4.2 Efficacy of pH and temperature in the synthesis of PCPs
2.4.3 Component ratio (effect of metal-ligand ratio)
2.4.4 Additional acids, bases, and salts
2.4.5 Effect of auxiliary additives
2.4.6 Effect of pressure and time
2.5 Mechanical properties of porous coordination polymers
2.5.1 The effect of metal coordination node
2.5.2 The effect of organic linker structure
2.5.3 The effect of PCP structure modification.
2.5.4 Mechanical features of PCP-based composites
2.6 Conclusion
References
3 Progressive approach of porous coordination polymers toward catalysis and photocatalysis
3.1 Introduction
3.2 PCPs as catalysts and their modification strategies
3.2.1 PCPs as catalysts
3.2.2 Modification strategies for PCPs
3.2.2.1 Postsynthetic modification
3.2.2.2 PCP-based single-atom catalysts
3.2.2.3 Metal nanoparticle (MNP) encapsulation
3.2.3 Modified PCPs and synergistic catalysis
3.3 Approaches for the modification of PCPs as photocatalysts
3.3.1 Modification of organic linker
3.3.2 Photosensitization
3.3.3 Metal nanoparticle doping
3.3.4 Coupling with semiconductors and carbon-based materials
3.4 Concluding remarks
References
4 Role of porous coordination polymers as chemical and bio-sensors in the remediation of environmental contaminants
4.1 Introduction
4.2 Contaminants and their chemo-sensed remediation by coordination polymers
4.2.1 Common contaminants
4.2.2 Remediation of contaminants and signal transduction
4.2.3 Adsorptive remediation and spectroscopic signal transduction
4.2.3.1 Infrared spectra as a tool
4.2.3.2 31P NMR as a tool
4.2.3.3 X-ray photoelectron spectroscopy and Fluorescence spectroscopy as tools
4.2.4 Topology, pores, surface area, and their impacts
4.3 Principles on the selection of a coordination polymer for sensing and remediation of contaminants
4.3.1 Building up a designed coordination polymer
4.3.2 Utility of the defect sites of a PCP in remediation
4.3.3 Pretreatment for enhanced adsorption
4.3.4 Stimuli-guided control of pores and sensing
4.3.5 Effects of dehydration and hydration
4.4 Ion-exchange and selectivity for remediation of toxic ions
4.4.1 Ionic interactions in adsorption
4.4.2 Size and shape selectivity.
4.4.3 Use of robust linkers
4.5 Adsorptions through supramolecular assembling of contaminants with CPs and recovery
4.5.1 Role of weak interactions
4.5.2 Chemo-sensed remediation from mixture of dyes
4.6 Photochemical chemo-sensed remediation
4.6.1 Principle
4.6.2 Utilization of semiconducting PCP in chemo-sensed remediation
4.6.3 Design of voids by linkers for chemo-sensed photo-chemical remediation by PCPs
4.6.4 Aromatic templates in photo-remediation by a PCP
4.7 Electrochemical remediation
4.7.1 Principles
4.7.2 Electrodes of PCPs in chemo-sensed remediation
4.8 Membranes of CPs for contaminant remediation
4.9 CPs of environmentally benign degradable biomaterials
4.10 Conclusions
References
5 Magnetic nanocomposite of sugarcane bagasse/HKUST-1 for pesticide removal
5.1 Introduction
5.2 PCPs in composites
5.2.1 PCP-based composites for pesticide removal in water
5.2.2 Pesticide removal, parameters, and adsorption mechanism
5.3 Natural lignocellulosic materials and nanoparticles for pesticide removal
5.4 Synthesis and characterization of new magnetic sugarcane bagasse and PCP composites
5.4.1 Magnetic nanoparticle synthesis and functionalization
5.4.2 Synthesis of [MNP/HKUST-1]
5.4.3 Synthesis of [MNP/HKUST-1@SCB]
5.4.4 Synthesis of [HKUST-1@MNP/SCB]
5.4.5 Characterization
5.5 Adsorption of pesticides by the composites
5.5.1 Equilibrium time determination
5.5.2 Adsorption isotherms
5.5.3 Possible adsorption mechanism
5.6 Conclusions and outlook
References
6 Investigation of porous coordination polymers for gas storage and separation
6.1 Hydrogen storage
6.2 Methane storage
6.3 Carbon dioxide capture
6.4 Toxic and harmful gas capture and enrichment
6.4.1 Ammonia adsorption
6.4.2 NO adsorption
6.4.3 NO2 adsorption.
6.4.4 SO2 adsorption
6.4.5 H2S adsorption
6.5 Low-carbon hydrocarbon adsorption and separation
6.5.1 Separation of olefins/alkanes
6.5.2 Separation of alkenes/alkynes
6.6 Volatile organic compounds' adsorption and separation
6.7 Water vapor adsorption and stability
6.8 Selective adsorption and separation of other gases
6.8.1 D2/H2 separation
6.8.2 Xe/Kr separation
6.9 Summary and outlook
Abbreviations
References
7 A new advanced approach of ultrafast synthesis of ultrahigh Brunauer-Emmett-Teller surface area crystalline/noncrystallin...
7.1 Introduction
7.2 Synthetic approaches toward the preparation of PCPs
7.2.1 First: high-energetic laser-assisted synthesis of PCPs
7.2.1.1 Specification of applied laser source
7.2.1.2 He-Ag laser-assisted hydrothermal synthesis of Cu++-PCPs
7.2.1.3 He-Ag laser-assisted hydrothermal synthesis of 2D-Zn++-PCP flakes
7.2.2 Second: microwave-assisted synthesis of PCPs
7.2.2.1 Microwave-assisted hydrothermal synthesis of Ni++-PCPs
7.2.2.1.1 Geometrical impact of trione ligand
7.2.2.2 Microwave-assisted hydrothermal synthesis of Mg++-PCPs
7.2.2.2.1 Geometrical structure studies and proposed model of Mg-complex
2D zigzagged structure arrays of novel synthesized Mg-complex
7.3 Structural measurements: structure identification and characterization of Cu++, Ni++, Zn++, and Mg-PCPs
7.3.1 Structure identification and characterization of Cu++-PCPs
7.3.2 Structure identification and characterization of Ni++-PCPs
7.3.2.1 UV/Vis spectra and microstructural features of Ni++-PCPs
7.3.2.2 Surface area (Brunauer-Emmett-Teller) measurements for Ni-PCPs
7.3.3 Structure identification and characterization of Zn++-PCPs
7.3.3.1 Amorphous phase identification
7.3.3.2 Characterization of Zn-chloro-corenene amorphous polymeric Zn-aPCPs.
7.3.3.3 Nano-/microstructural features of amorphous Zn-aPCPs
7.3.3.4 Brunauer-Emmett-Teller surface area of Zn-aPCPs
7.4 Gas capture efficiency for PCPs
7.4.1 Laser-assisted (Cu++ and Zn++) PCPs
7.4.1.1 CO2 capture efficiency for Cu++-PCPs
7.4.1.2 CH4/CO2 capture efficiency for Zn++-PCPs
7.4.2 Microwave-assisted (Ni++and Mg++) PCPs
7.4.2.1 CO2 adsorption experiment isotherm of Ni++-PCPs
7.4.2.2 Hydrogen storage efficiency for Mg++-PCPs
7.5 Conclusions and perspectives
References
8 Porous coordination polymers in energy storage and conversion
8.1 Introduction
8.2 Synthesis and modification of the porous coordination polymers
8.2.1 Pristine PCPs
8.2.2 Bimetal/multimetal nodes
8.2.3 Structural transformation (partial)
8.2.4 Architectural modifications
8.2.5 Dimensional modifications
8.2.6 Pore structure engineering
8.3 PCP applications in energy storage and conversion
8.3.1 Mechanism of charge storage in the PCPs
8.3.2 PCP-based electrode materials for rechargeable batteries
8.3.3 PCP-based electrode materials for supercapacitor
8.3.4 PCP-based material for energy conversion
8.4 Conclusion and future perspectives
References
9 Ions and electron conductive porous coordination polymers for energy applications
9.1 Introduction
9.2 Ionic conductive porous coordination polymers
9.2.1 Design strategies and conducting media for proton conductive PCPs
9.2.2 Proton conduction under hydrated conditions
9.2.3 Proton conduction under anhydrous conditions
9.2.4 Other ionic species for conductive PCPs
9.2.4.1 Hydroxide and media for conductive PCPs ionic liquid
9.2.4.2 Metal ions conductive PCPs
9.3 Electronic conductive porous coordination polymers
9.3.1 Electron conduction through space
9.3.2 Electron conduction through bond.