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Including Actinides /

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Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 61 presents the latest release in this continuous series that covers all aspects of rare earth science, including chemistry, life sciences, materials science and physics. Presents up-to-date overviews and new developme...

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Bibliographic Details
Corporate Author: ScienceDirect (Online service)
Other Authors: Bunzli, Jean-Claude G. (Editor), Pecharsky, Vitalij K. (Editor)
Format: eBook
Language:English
Published: San Diego : Elsevier, 2022.
Series:Handbook on the physics and chemistry of rare earths ; Volume 61.
Subjects:
Rare earths.
Actinide elements.
Terres rares.
Actinides.
Actinide elements
Rare earths
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Intro
  • Handbook on the Physics and Chemistry of Rare Earths: Including Actinides
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Chapter 323: Luminescence enrichment in perovskite-lanthanide composites: Complexity and complementarity
  • Chapter 324: Lanthanides for the new generation of optical sensing and Internet of Things
  • Chapter 325: Importance of ligand design in lanthanide azamacrocyclic complexes relevant to biomedical applications
  • Chapter 323: Luminescence enrichment in perovskite-lanthanide composites: Complexity and complementarity
  • 1. Introduction 2. Lanthanide-doped lead-based inorganic halide perovskites
  • 2.1. Lanthanide doping
  • 2.2. Optical features of lanthanide-doped lead inorganic halide perovskites
  • 2.3. Energy transfer and quantum cutting
  • 2.4. Photoluminescence saturation
  • 3. Optoelectronic applications
  • 3.1. Solar photovoltaics
  • 3.2. Luminescent solar concentrators (LSCs)
  • 3.3. Light-emitting diodes
  • 4. Outlook
  • Acknowledgments
  • References
  • Chapter 324: Lanthanides for the new generation of optical sensing and Internet of Things
  • 1. Introduction
  • 1.1. Motivation 1.2. Lanthanide-based sensors overview
  • 2. General considerations
  • 2.1. Luminescence thermometry
  • 2.2. Energy transfer
  • 2.2.1. Intramolecular energy transfer
  • 2.2.1.1. Example of theoretical modeling
  • 2.2.2. Ln3+-to-Ln3+ energy transfer
  • 2.2.3. Rate equations and emission quantum yield
  • 2.2.4. Computational tools
  • 2.3. Luminescence quantification
  • 2.3.1. Color models
  • 2.3.2. Emission color from Ln3+ ions in the RGB model
  • 2.3.3. Color multiplexing
  • 3. Experimental setups for mobile optical detection
  • 3.1. Steady-state detection
  • 3.2. Time-resolved detection 4. Optical mobile sensing without connection to IoT
  • 4.1. Single-center optical sensors
  • 4.1.1. Point of care
  • 4.2. Dual-center optical sensors
  • 4.2.1. Analyte sensing
  • 4.2.2. Temperature sensing
  • 5. Optical mobile sensing with connection to IoT: Authentication, trackability
  • 5.1. Bio and medical applications: eHealth and mHealth
  • 6. Conclusions and perspectives
  • Acknowledgments
  • References
  • Chapter 325: Importance of ligand design in lanthanide azamacrocyclic complexes relevant to biomedical applications
  • 1. Introduction
  • 2. Matching ligands and lanthanide ions 3. Synthesis of macrocyclic ligands
  • 3.1. Synthesis of fully functionalized macrocycles
  • 3.2. Synthesis of disymmetrically substituted CYCLEN derivatives
  • 3.2.1. Mono-N- or tri-N- regiospecific functionalization or protection
  • 3.2.2. Di-N-regiospecific functionalization
  • 3.3. Synthesis of PYCLEN derivatives
  • 3.4. Other macrocycles
  • 4. Thermodynamic stability of lanthanide complexes
  • 4.1. Stability constants and conditional stability of Gd(III) complexes
  • 4.2. Effects of ionic strength
  • 4.3. Effect of macrocyclic ring size and donors
  • 4.4. Influence of the pendant groups.