Chiral phosphorous based ligands in earth-abundant transition metal catalysis /

Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis summarizes the most significant progress in the field of chiral phosphine ligand chemistry and a broad range of earth-abundant transition metal/chiral phosphine ligand-catalyzed enantioselective transformations. The book p...

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Bibliographic Details
Corporate Author:	ScienceDirect (Online service)
Other Authors:	Zhang, Junliang, Li, Wenbo
Format:	eBook
Language:	English
Published:	Amsterdam, Netherlands ; Oxford, United Kingdom ; Cambridge MA : Elsevier, [2023]
Subjects:	Transition metal catalysts. Ligands. Chirality. Pharmaceutical chemistry. Chemistry, Organic. Phosphine. Stereoisomers. Chemistry, Pharmaceutical Chemistry, Organic Phosphines Ligands Stereoisomerism Catalyseurs à base de métaux de transition. Chiralité. Chimie pharmaceutique. Chimie organique. Stéréo-isomères. organic chemistry. Chirality Transition metal catalysts Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

Introduction
1
Design and synthesis of typical chiral bisphosphorus ligands
1. Introduction
2. Bisphosphorus ligands with carbon chiral center
3. Axially chiral bisphosphorus ligands
4. Ferrocenyl bisphosphorus ligands
5. Spiro backbone-based bisphosphorus ligands
6. P-chiral bisphosphorus ligands
7. Conclusions
References
2
The progress of chiral phosphine ligands in asymmetric iron catalysis
1. Introduction
2. Kumada cross-coupling reactions
3. Suzuki-Miyaura coupling reaction
4. Diels-Alder reaction
5. 1,3-dipolar cycloadditions
6. Olefin carbometalation
7. Hydrosilylation of ketones
8. Asymmetric strecker reaction of azomethine imines
9. Asymmetric transfer hydrogenation of ketones and imines
10. Asymmetric hydrogenation of ketones and imines
11. Conclusion
References
3
Asymmetric transformations under cobalt catalysis
1. Introduction
2. Allylic substitutions
3. Cycloaddition and cyclization
4. Hydrogenation
5. Hydrosilylation
6. Hydroboration
7. Hydroarylation
8. Hydrovinylation
9. Hydroalkynylation
10. Hydroalkylation
11. Hydroacylation
12. Reductive coupling
13. Conclusions
References
4
Asymmetric transformations under nickel catalysis
1. Introduction
2. Allylic substitution reactions
3. Cross-coupling reactions
4. Addition reactions
5. Cyclization reactions
6. Cycloaddition reactions
7. Hydrogenation
8. Conclusions
References
5
Copper/chiral phosphine ligand-catalyzed enantioselective 1,3-dipole cycloaddition reactions
1. Introduction.