Energy aspects of acoustic cavitation and sonochemistry : fundamentals and engineering /
"Covers topics ranging from fundamental modeling to up-scaled experiments. The book relates acoustic cavitation and its intrinsic energy balance to macroscopic physical and chemical events that are analyzed from an energetic perspective. Outcomes are directly projected into practical applicatio...
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| Format: | eBook |
| Language: | English |
| Published: |
Amsterdam, Netherlands :
Elsevier,
[2022]
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Intro
- Half title
- Title
- Copyright
- Contents
- Contributors
- Part I The single acoustic cavitation bubble as an energetic system: qualitative and quantitative assessments
- Chapter 1 Single acoustic cavitation bubble and energy concentration concept
- 1.1 Introduction
- 1.2 Single acoustic cavitation bubble: Thermodynamic aspects of inception and growth, and dynamics of bubble oscillation
- 1.2.1 Bubble inception, growth and dynamics of oscillation
- 1.2.2 Thresholds
- 1.2.3 Dynamics of bubble oscillation
- 1.3 The hot spot theory
- 1.4 Thermodynamics of acoustic cavitation bubble and energy balance
- 1.4.1 Polytropic model
- 1.4.2 Energetics of sonochemistry
- 1.4.3 Mass diffusion
- 1.4.4 Nonequilibrium of evaporation and condensation
- 1.4.5 Conduction
- 1.4.6 Convection
- 1.5 Energy concentration concept
- 1.5.1 Acoustic energy
- 1.5.2 Acoustic radiation as a source of cavitation
- 1.5.3 Acoustic radiation from collapsing bubble
- 1.5.4 Energy concentration
- 1.6 Engineering outcomes
- References
- Chapter 2 The energy forms and energy conversion
- 2.1 Introduction
- 2.2 Theoretical background
- 2.3 Energetic evolution of an oscillating bubble
- 2.4 Influence of acoustical conditions
- 2.5 Energy analysis as function of initial bubble size
- 2.6 Conclusion
- Acknowledgments
- References
- Chapter 3 Physical effects and associated energy release
- 3.1 Introduction
- 3.2 The theoretical approach of the propagation of an acoustic wave in a liquid medium, and acoustic streaming
- 3.2.1 Propagation of an ultrasonic wave in a liquid medium
- 3.2.2 Acoustic streaming
- 3.3 The theoretical approach of the oscillation of acoustic cavitation bubbles and its associated physical effects
- 3.3.1 The energetic mechanism of bubble inception, oscillation, and collapse.
- 3.3.2 The physical effects associated with acoustic cavitation bubbles
- 3.4 Energetic outcomes: Macroscopic dissipation of acoustic energy
- 3.5 Conclusion
- References
- Chapter 4 Sonochemical reactions, when, where and how: Modelling approach
- 4.1 Introduction
- 4.2 The governing equations
- 4.2.1 State-of-the-art reaction mechanism of an oxygen bubble
- 4.2.2 The complete bubble model
- 4.3 Numerical technique and the investigated parameter space
- 4.4 Chemical yield of a single bubble
- 4.5 Energy efficiency considerations
- 4.6 Discussion and summary
- References
- Chapter 5 Sonochemical reactions, when, where and how: Experimental approach
- 5.1 When do the sonochemical reactions take place?
- 5.2 Where and how do sonochemical reactions take place?
- 5.2.1 In the gas phase of collapsing bubbles
- 5.2.2 At the interfacial region surrounding collapsing bubbles
- 5.2.3 In the bulk solution
- 5.3 Techniques for ultrasonic cavitation observation and measurement
- 5.3.1 Sonoluminescence (SL)
- 5.3.2 Tube arrest method
- 5.3.3 Color Doppler ultrasound imaging
- 5.3.4 Quantify acoustic bulk cavitation in multiple bubble system
- 5.3.5 Micro-PIV method
- 5.4 Application of sonochemical reactions
- 5.4.1 US/persulfate system
- 5.4.2 US/permanganate system
- 5.4.3 US/Fenton system
- 5.4.4 US/O3 system
- 5.4.5 US/electrochemistry system
- 5.4.6 US/UV system
- 5.5 Conclusions and perspective
- References
- Part II The bubble population: an analytic view into mutual forces and allied energy exchange
- Chapter 6 The Bjerknes forces and acoustic radiation energy
- 6.1 Acoustic radiation force in a plane traveling wave field
- 6.2 Bjerknes forces
- 6.2.1 Primary Bjerknes force
- 6.2.2 Secondary Bjerknes force
- 6.3 Experimental aspects of determining acoustic radiation energy.
- 6.3.1 Acoustic dosimetry based on radiation force measurement
- 6.3.2 Acoustic radiation force in the near field
- 6.3.3 Measurement of acoustic radiation energy from a liquid of multibubbles
- 6.3.4 Interpretation of acoustic energy spectra from multibubble cavitation
- 6.4 Conclusion
- References
- Chapter 7 Nonlinear oscillations and resonances of the acoustic bubble and the mechanisms of energy dissipation
- 7.1 Introduction
- 7.2 The bubble model
- 7.2.1 Thermal effects
- 7.3 Scattered pressure by bubbles
- 7.4 Various regimes of complex bubble oscillations
- 7.5 Damping constants for the linear regime of oscillations
- 7.6 Nonlinear resonances of the bubble oscillator
- 7.7 Nonlinear bubble behavior analysis
- 7.7.1 Poincaré section
- 7.7.2 Method of maxima
- 7.7.3 Final construction
- 7.8 Nonlinear dissipation terms
- 7.8.1 Nonlinear dissipation terms of the uncoated free bubble
- 7.9 Bifurcation structure and the nonlinear dissipations of the bubble
- 7.10 Summarizing points and discussion
- 7.11 Concluding remarks
- References
- Chapter 8 Damping mechanisms of oscillating gas/vapor bubbles in liquids
- 8.1 Introduction
- 8.2 Bubble wall motion equation
- 8.2.1 Prosperetti-Lezzi equation
- 8.2.2 Gilmore equation
- 8.2.3 Keller-Miksis equation
- 8.2.4 Herring equation
- 8.2.5 Rayleigh-Plesset equation
- 8.3 Linear oscillations of gas bubbles
- 8.3.1 Bubble wall motion equation with thermal effects
- 8.3.2 Linearization process
- 8.3.3 Damping constants
- 8.4 Thermal effects and thermal damping
- 8.4.1 Basic equations
- 8.4.2 Solutions for the nonuniform pressure inside bubble
- 8.4.3 Solutions for the uniform pressure inside bubble
- 8.5 Effects of liquid compressibility and acoustic damping
- 8.6 Total damping constants and comparisons of damping mechanisms
- 8.7 Damping mechanisms of vapor bubbles.
- 8.7.1 Basic equations
- 8.7.2 Linear oscillations
- 8.7.3 Effects of mass transfer
- 8.8 Wave propagation in the liquids containing bubbles
- 8.8.1 Basic equations
- 8.8.2 Wave speed and attenuation
- 8.9 Nonlinear oscillations of bubbles
- 8.9.1 Comparisons of the viscous and acoustic damping mechanisms
- 8.9.2 Comparisons of predictions by different bubble wall motion equations
- 8.10 Conclusions
- Acknowledgement
- References
- Chapter 9 Energy controlling mechanisms: Relationship with operational conditions
- 9.1 Introduction
- 9.2 Model description
- 9.3 Chemical activity in single bubble and multibubble systems
- 9.4 Energy variation of a multibubble system
- 9.5 Conclusion
- Acknowledgments
- References
- Part III Ultrasound assisted processes, sonochemical reactors and energy efficiency
- Chapter 10 Efficiency assessment and mapping of cavitational activities in sonochemical reactors
- 10.1 Introduction
- 10.2 Types, classification and working principle of the sonochemical reactors
- 10.3 Overview of cavitational activities in the sonochemical reactors
- 10.3.1 Spatial and temporal distribution (mapping activities and bubble dynamics studies)
- 10.3.2 Active and passive cavitational zones
- 10.3.3 Effect of operating parameters on distribution of cavitational activities
- 10.3.4 Challenges in efficient design and operation of sonochemical reactors
- 10.4 Efficiency assessment and mapping of cavitational activities in sonochemical reactors
- 10.4.1 Efficiency assessment
- 10.4.2 Overview of techniques for quantifying cavitational activity distribution
- 10.4.3 Experimental techniques
- 10.4.4 Numerical investigations
- 10.5 Case study
- 10.5.1 Experimental setup
- 10.5.2 Measurements of Iodine liberated in reactor
- 10.5.3 Quantification of local pressure field by wave equation.
- 10.5.4 Bubble dynamics studies
- 10.5.5 Observations
- 10.6 Outlook and path forward
- References
- Chapter 11 Sources of dissipation: An outlook into the effects of operational conditions
- 11.1 Introduction
- 11.2 Theoretical approaches
- 11.3 Formation of extreme conditions in reactions
- 11.3.1 Sonochemical reaction sites
- 11.3.2 Definition of "cavitation treshold"
- 11.4 Transducers
- 11.5 Signals
- 11.6 Effects of operational parameters
- 11.6.1 The primary parameters
- 11.6.2 Secondary parameters
- 11.7 Conclusion
- References
- Chapter 12 Mechanistic issues of energy efficiency of an ultrasonic process: Role of free and dissolved gas
- 12.1 Introduction
- 12.2 Experimental summary
- 12.3 The mathematical model
- 12.3.1 Determining the acoustic impedance
- 12.3.2 Acoustic wave propagation in bubbly liquids
- 12.3.3 Cavitation nucleation and bubble dynamics
- 12.3.4 Rectified diffusion
- 12.4 Results and resasoning
- 12.4.1 Interpretation of the spectral characteristics
- 12.4.2 Radial motion of the bubbles
- 12.4.3 Analysis of the spectral characteristics of acoustic emission
- 12.5 Overview
- 12.6 Case studies of ultrasonic processes based on energy transformation analysis
- 12.7 Intensification of wet textile treatment
- 12.8 Case study 2: Weissler reaction
- References
- CHAPTER 13 Simulation of sonoreators accounting for dissipated power
- 13.1 Introduction
- 13.2 Linear acoustics
- 13.2.1 Energetics of nondissipative linear acoustics
- 13.2.2 Energetics of dissipative linear acoustics
- 13.3 Sound propagation accounting for cavitation
- 13.3.1 The Caflisch model
- 13.3.2 Linear case
- 13.3.3 Energy formulation
- 13.3.4 Energy dissipation functions
- 13.3.5 A reduced model (Louisnard, 2012)
- 13.3.6 Summary of the cavitating liquid model
- 13.4 Acoustics of solid parts and piezo-electrics.