Salinity gradient heat engines /
Salinity Gradient Heat Engines classifies all the existing SGHEs and presents an in-depth analysis of their fundamentals, applications and perspectives.The main SGHEs analyzed in this publication are Osmotic, the Reverse Electrodialysis, and the Accumulator Mixing Heat Engines.
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| Format: | eBook |
| Language: | English |
| Published: |
Duxford :
Woodhead Publishing,
[2022]
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| Series: | Woodhead Publishing in energy.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Intro
- Salinity Gradient Heat Engines
- Copyright
- Contents
- Contributors
- Preface
- Chapter 1: Salinity gradient heat engines: An innovative concept for waste heat valorization
- 1.1. Background and motivation
- 1.2. What is salinity gradient energy?
- 1.3. Salinity gradient heat engines: Introduction, fundamentals, and classification
- 1.3.1. Introduction
- 1.3.2. Fundamentals and key performance parameters
- 1.3.3. Classification
- 1.3.3.1. Power units
- Osmotic heat engine (OHE)
- Reverse electrodialysis heat engine (REDHE)
- Other SGP engines or special engines
- 1.3.3.2. Regeneration strategies
- Solvent extraction strategy (full details are provided in Chapter 5)
- Salt extraction strategy (full details are provided in Chapter 6)
- 1.4. Chapters outline
- References
- Chapter 2: The state of art of conventional and nonconventional heat engines
- 2.1. General information
- 2.2. Power plants
- 2.2.1. Steam prime mover plants
- 2.2.1.1. Methods for increasing efficiency
- Increase of the inlet turbine temperature
- Reduction of condensation pressure
- Increase of the maximum pressure of the cycle
- Resuperheating
- Regeneration
- 2.2.2. Gas power plants
- 2.2.2.1. Open cycle
- 2.2.2.2. Closed cycle
- 2.2.2.3. Regeneration
- 2.2.2.4. Interrefrigeration and postcombustion
- 2.2.3. Combined cycle
- 2.2.3.1. Introduction
- 2.2.3.2. Layout
- 2.2.4. Organic Rankine cycle
- 2.2.5. Kalina cycle
- 2.2.6. Stirling cycle
- 2.2.7. Direct conversion of heat into electricity by means of thermoelectric generators
- 2.2.8. Direct conversion of heat into electricity by means of magnetohydrodynamic power generators
- 2.2.9. Heat recovery and novel technologies to produce power
- 2.2.10. Low- and high-temperature fuel cells
- 2.3. Conclusions
- References
- Chapter 3: Osmotic heat engine (OHE).
- 3.1. Fundamentals of pressure-retarded osmosis and osmotic heat engine
- 3.1.1. Introduction
- 3.1.2. Analysis of single-stage PRO ignoring concentration polarization
- 3.1.3. Analysis of single-stage PRO accounting for concentration polarization
- 3.1.4. Analysis of multistage PRO design
- 3.2. Salt selection
- 3.3. Process couplings in OHE
- 3.3.1. Solvent extraction method
- 3.3.1.1. PRO-MD
- 3.3.1.2. PRO-RO
- 3.3.1.3. PRO-LIS
- 3.3.2. Salt extraction method
- 3.3.2.1. PRO-thermolytic
- 3.3.2.2. PRO precipitation
- 3.4. Perspectives
- References
- Chapter 4: Reverse electrodialysis heat engine (REDHE)
- 4.1. Fundamentals of reverse electrodialysis
- 4.1.1. Description of the RED process
- 4.1.2. Ion-exchange membranes for RED
- 4.1.2.1. Electrical resistance
- 4.1.2.2. Membrane permselectivity
- 4.1.2.3. Swelling degree
- 4.1.2.4. Ion-exchange capacity and fixed charge density
- 4.1.3. Fluxes of water and ions through the IEMs
- 4.1.4. Main outputs of the RED process
- 4.2. Fundamentals of RED heat engines
- 4.2.1. Solvent extraction schemes
- 4.2.2. Salt extraction schemes
- 4.2.3. Main outputs of the RED heat engines
- 4.3. Salt selection
- 4.3.1. Salt-solutions for solvent extraction schemes
- 4.3.1.1. Thermodynamic properties of salt solutions
- 4.3.1.2. Theoretical RED results with different salts
- 4.3.1.3. State of the art: RED with alternative salts
- 4.3.2. Salt-solutions for salt extraction schemes
- 4.3.2.1. State of the art: RED with thermolytic salts
- 4.4. RED heat engines
- 4.4.1. State of the art: Solvent extraction schemes
- 4.4.2. State of the art: Salt extraction schemes
- 4.4.3. First prototype of a RED-HE
- 4.4.4. General comparison
- References
- Chapter 5: Solvent extraction regeneration technologies
- 5.1. Introduction
- 5.2. Multieffect distillation for regeneration in an SGP-HE.
- 5.2.1. Description and fundamentals
- 5.2.2. Assessment of the potential of MED for regeneration in an SGP-HE
- 5.2.2.1. Model of a MED unit for salt solutions regeneration in an SGP-HE
- 5.2.3. Case study
- 5.3. Membrane distillation for regeneration in an SGP-HE
- 5.3.1. Description of the process
- 5.3.2. Assessment of the potential of MD for regeneration in an SGP-HE
- 5.3.3. Case study
- 5.4. Forward osmosis for regeneration in an SGP-HE
- 5.4.1. Description and fundamentals
- 5.4.2. Assessment of FO potential for regeneration in an SGP-HE
- 5.5. Conclusions
- Acknowledgments
- References
- Chapter 6: Salt extraction regeneration technologies
- 6.1. Introduction
- 6.2. Switchable solubility salts
- 6.2.1. Thermal-sensible solubility
- 6.2.2. Phase separation processes
- 6.3. Thermolytic salts
- 6.3.1. Regeneration unit for thermolytic salt solution
- 6.3.1.1. Distillation
- 6.3.1.2. Air stripping process
- 6.3.1.3. Membrane distillation
- 6.3.2. First prototypes
- 6.3.3. Modeling and simulation
- 6.3.4. Regeneration unit performance
- 6.4. Final remarks
- References
- Chapter 7: Coupling salinity gradient heat engines with power generation systems and industrial processes
- 7.1. Introduction
- 7.2. Identification of potential applications of salinity gradients power-heat engines in power plants and industries
- 7.3. Description and modeling of the case studies proposed
- 7.3.1. Case study no. 1: Integration of SGP-HEs in thermoelectric power plant
- 7.3.2. Case study no. 2: Coupling a RED-HE with medium-temperature waste heat to power technologies
- 7.3.3. Case study no. 3: Salinity gradient powers-heat engine in combined heat and power plants
- 7.3.4. Case study no. 4: SGP-HEs for heat upgrade in industrial processes.
- 7.3.5. Case study no. 5: SGP-HEs for waste-heat exploitation in industrial processes with large water demand
- 7.4. Notes on energy, economic, and environmental indicators used
- 7.4.1. Notes on the legislative framework for combined heat and power plants in European Union
- 7.5. Results
- 7.5.1. Case study no. 1: Reverse electrodialysis-heat engine in thermoelectric power plant
- 7.5.2. Results for case study no. 2: Coupling reverse electrodialysis-heat engine with an organic Rankine cycle plant
- 7.5.3. Results for case study no. 3: Integration of a reverse electrodialysis-heat engine in CHP plants
- 7.5.4. Results for case study no. 4: Coupling a reverse electrodialysis-heat engine with a heat pump for heat upgrade
- 7.5.5. Results for case study no. 5 RED-HEs in industrial processes with large water demand
- 7.6. Perspective analysis with high-efficient reverse electrodialysis-heat engine
- 7.7. Conclusions
- References
- Chapter 8: Special engines
- Nomenclature
- Greek symbols
- Subscripts
- Acronyms
- Part 1: Accumulator mixing heat engine
- 8.1. Accumulator mixing heat engine
- 8.1.1. Introduction and thermodynamic considerations
- 8.1.2. Accumulator mixing technology fundamentals
- 8.1.3. The zinc-silver AccMix cell
- 8.1.3.1. Description
- 8.1.3.2. Experimental realization
- 8.1.3.3. Cell voltage and voltage rise
- 8.1.4. Power generation step: Efficiency of the AccMix cycles
- 8.1.5. Regeneration step: Efficiency of the distillation stage
- 8.1.6. Discussion of the overall efficiency of distillation and SGP heat engine
- 8.1.7. Potentials and limitations
- References
- Part 2: Thermally regenerative ammonia battery (TRAB): Fundamentals and perspectives
- 8.2. Thermally regenerative ammonia battery (TRAB): Fundamentals and perspectives
- 8.2.1. Introduction and description of TRAB concept.
- 8.2.1.1. Performances evaluation
- 8.2.2. Power production as a function of different operating parameters
- 8.2.2.1. Effect of the concentration of ammonia
- 8.2.2.2. Effect of the concentration of Cu(II) and supporting electrolyte
- 8.2.2.3. Effect of the mixing rate and cell design
- 8.2.2.4. Effect of temperature
- 8.2.2.5. Effect of nature of the membrane
- 8.2.2.6. Effect of electrode shapes
- 8.2.3. Cathodic and Anodic Coulombic efficiencies
- 8.2.4. Regeneration of the solutions and performances in successive cycles
- 8.2.5. Perspectives
- References
- Part 3: Swelling/shrinking hydrogels engines:Fundamentals and perspectives
- 8.3. Swelling/shrinking hydrogels engines: Fundamentals and perspectives
- 8.3.1. What are hydrogels?
- 8.3.2. Salinity gradient energy recovery based on hydrogels
- 8.3.3. Energy recovery from acid-base neutralization based on hydrogels
- 8.3.4. Possible energy recovery from waste heat based on hydrogels
- 8.3.5. Outlook for energy harvest based on hydrogels
- References
- Chapter 9: Resource, environmental, and economic aspects of SGHE
- 9.1. Resource assessment-Heat availability
- 9.1.1. Introduction
- 9.1.2. Waste heat
- 9.1.2.1. Industrial waste heat
- 9.1.2.2. Decentralized power plants
- 9.1.2.3. Marine
- 9.1.2.4. Gas compression stations
- 9.1.3. Geothermal
- 9.1.4. Solar
- 9.1.5. Conclusions
- 9.2. Environmental impacts of SGHE
- 9.2.1. Introduction
- 9.2.2. Background
- 9.2.3. Life cycle assessment methodology
- 9.2.4. Goal and scope
- 9.2.5. Life cycle inventory analysis
- 9.2.6. Life cycle impact assessment
- 9.2.7. Life cycle interpretation
- 9.2.8. LCA examples
- 9.3. Economics of SGHE
- 9.3.1. Introduction
- 9.3.2. Levelized cost of electricity as an indicator of cost-effectiveness
- 9.3.3. System sizing and performance analysis
- 9.3.4. Investment expenditures.