Green sustainable process for chemical and environmental engineering and science : organic synthesis in water and supercritical water /
Green Sustainable Process for Chemical and Environmental Engineering and Science: Organic Synthesis in Water and Supercritical Water provides an in-depth review of purification and extraction methods for medicinal, analytical, engineering and bioactive compounds utilizing green chemistry protocols.
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| Other Authors: | , , |
| Format: | eBook |
| Language: | English |
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Amsterdam, Netherlands :
Elsevier,
2020.
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- 2.9. Aqueous intramolecular D-A reaction in the total synthesis
- 2.10. [3+2] Cycloaddition reactions in water
- 2.11. [4+3] Cycloaddition reaction
- 2.12. [2+2+2] Cycloadditions
- 2.13. [5+2] Cycloadditions
- 3. Cycloaddition reactions ``on-water´´
- 4. Concluding remarks
- Acknowledgments
- References
- Chapter 4: Hydrogenation reactions in water
- 1. Introduction
- 2. Types of hydrogenation
- 2.1. Catalytic hydrogenation
- 2.2. Transfer hydrogenation
- 2.3. Asymmetric hydrogenation
- 2.4. Asymmetric transfer hydrogenation
- 2.5. Electrocatalytic hydrogenation
- 2.6. Selective hydrogenation
- 2.6.1. Chemoselective hydrogenation
- 2.6.2. Diastereoselective hydrogenation
- 2.6.3. Regioselective hydrogenation
- 2.7. Other hydrogenation
- 3. Water as hydrogen donor
- 3.1. Synthesis of aliphatic compounds
- 3.2. Synthesis of aromatic compounds
- 3.3. Synthesis of carbonyl compounds
- 3.4. Synthesis of alcohols, ethers, sugars, nitro and nitril compounds
- 3.5. Synthesis of bio-oils, fossil fuel, and cellulose
- 4. Water as solvent
- 4.1. Synthesis of aliphatic compounds
- 4.2. Synthesis of aromatic compounds
- 4.3. Synthesis of carbonyl compounds
- 4.4. Synthesis of alcohols, ethers, sugars, nitro, and nitril compounds
- 5. Conclusion
- References
- Chapter 5: Magnetically separable nanocatalyzed synthesis of bioactive heterocycles in water
- 1. Introduction
- 2. Synthesis of nitrogen-containing heterocycles
- 2.1. Synthesis of N-substituted pyrroles
- 2.2. Synthesis of 1,4-dihydropyridines
- 2.3. Synthesis of hexahydroquinoline carboxylates
- 2.4. Synthesis of quinolines
- 2.5. Synthesis of acridine-1,8(2H,5H)-diones
- 2.6. Synthesis of benzo[d]imidazoles
- 2.7. Synthesis of imidazo[1,2-a]pyridines
- 2.8. Synthesis of quinoxalines
- 2.9. Synthesis of 1,2,3-triazoles.
- 5. Factors affecting CC coupling reactions in water
- 5.1. Catalyst
- 5.2. Bimetallic catalysts
- 5.3. Base and concentration effect
- 5.4. Light water/heavy water
- 5.5. Energy source
- 5.6. Additives and transfer agents
- 6. Specific CC coupling reactions
- 6.1. Mizoroki-Heck reaction
- 6.2. Hiyama reaction
- 6.3. Suzuki-Miyaura reaction
- 6.4. Sonogashira-Hagihara reaction
- 6.5. Stille reaction
- 6.6. Negishi reaction
- 7. Applications in synthesis
- 7.1. Derivatization of biomolecules
- 7.2. Bioactive molecules
- 8. Conclusions
- References
- Index.