http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Annual Reports on NMR Spectroscopy, Volume 92 provides a thorough and in-depth accounting of progress in nuclear magnetic resonance (NMR) spectroscopy and its many applications. Topics presented include new chapters on The DEPT Experiment and Some of Its Useful Variants, NMR Studies of Organic Aerosols, Recent NMR Studies of Thermoelectric Materials, Nonlinear Effects in NMR, Applications of Solid-State 43 Ca Nuclear Magnetic Resonance: Superconductors, Glasses, Biomaterials, and NMR Crystallography, and Solid-State NMR Spectroscopy: The Magic Wand to View Bone at Nanoscopic Resolution.This book has established itself as a premier means for both specialists and non-specialists who are looking to become familiar with new techniques and applications pertaining to NMR spectroscopy.- Serves as the premier resource for learning the new techniques and applications of NMR spectroscopy- Provides a key reference for chemists and physicists using NMR spectroscopy to study the structure and dynamics of molecules- Covers all aspects of molecular science, including MRI (Magnetic Resonance Imaging).
Front Cover -- Annual Reports on NMR Spectroscopy -- Copyright -- Contents -- Contributors -- Preface -- Chapter One: The DEPT Experiment and Some of Its Useful Variants -- 1. Introduction -- 2. Product Operator Formalism -- 3. Spin Echo (SE)-Based Experiments -- 3.1. The SEFT/APT Sequence -- 3.2. The CAPT Sequences -- 3.3. The SEMUT Sequences -- 4. INEPT-Based Experiments -- 4.1. A Few General Remarks -- 4.2. The INEPT Sequences -- 4.3. The PENDANT Sequence -- 5. Basic Theory Analysis of the Standard DEPT Experiment -- 5.1. The Standard DEPT Pulse Sequence -- 5.2. PO Treatment of the DEPT Experiment -- 5.3. The Influence of the Last Proton Pulse and Spectral Editing -- 5.4. The Influence of the Interpulse Delay Delta -- 5.5. The Influence of Phase Cycling -- 5.6. The Influence of the 13C 180 Degree Pulse -- 5.7. Strengths and Weaknesses of the DEPT Sequence -- 6. The POMMIE Experiment -- 7. Application of DEPT to Other Heteronuclei -- 7.1. 29Si/1H DEPT Experiments -- 7.2. The Special Case of 13C/19F DEPT Experiments -- 8. The DEPT+ and DEPT++ Sequences -- 8.1. Analyses of the Sequences -- 9. J-Compensated DEPT Sequences -- 10. The IDEPT Experiment -- 11. Inclusion of Quaternary Carbons: The DEPTQ Sequence -- 11.1. A Few General Remarks -- 11.2. Analyses of the Basic DEPTQ Pulse Sequence -- 11.3. Improvements for the DEPTQ Pulse Sequence -- 11.4. Illustrative Examples -- 12. Equalizing the Intensities: The ACCORDEPT Experiment -- 12.1. Analyses of the ACCORDEPT Pulse Sequence -- 12.2. Decrementation Technique -- 13. Obtaining Quantitative 13C Spectra: The Q-DEPT and Q-DEPT+ Experiments -- 14. Comparison of APT, DEPT, DEPTQ, RefINEPT, and PENDANT Experiments: Conclusion and Practical Recommendations -- Appendix -- References -- Chapter Two: NMR Studies of Organic Aerosols -- 1. Introduction.
2.1. Definitions of Nonlinearity and Related Terms -- 2.2. The High Temperature and High Field Limits -- 2.3. Effects at High Polarization -- 3. Nonadditive NMR Signals -- 4. Nonlinearity of Nuclear Spin Noise -- 5. NMR-Maser Emissions -- 6. Avoiding Nonlinear Response in Quantitative NMR -- 7. Conclusion and Outlook -- References -- Chapter Five: Applications of Solid-State 43Ca Nuclear Magnetic Resonance: Superconductors, Glasses, Biomaterials, and NM ... -- 1. Introduction and Background -- 1.1. Scope -- 1.2. Calcium: Why Should We Care? -- 1.3. Obtaining High-Quality 43Ca SSNMR Data Is Challenging -- 1.4. Ways to Improve 43Ca SSNMR Sensitivity and/or Resolution -- 1.4.1. Brute Force: Isotopic Enrichment -- 1.4.2. Increase the Applied Magnetic Field (B0) -- 1.4.3. Magic-Angle Spinning -- 1.4.4. Double-Rotation and Dynamic-Angle Spinning -- 1.4.5. Magic-Angle Coil Spinning -- 1.4.6. Cross-Polarization -- 1.4.7. Manipulate Satellite Transitions to Enhance the CT -- 1.4.8. Multiple-Quantum MAS -- 1.4.9. Decouple Abundant Nuclei -- 1.4.10. Decrease the System Temperature -- 1.5. What Can Be Measured Using 43Ca SSNMR Experiments? -- 1.5.1. Chemical Shifts (and 43Ca NMR Reference Materials) -- 1.5.2. Knight Shifts and Spin Susceptibility -- 1.5.3. Quadrupolar Interaction (and Euler Angles) -- 1.5.4. Sternheimer Antishielding -- 1.5.5. Spin-Lattice Relaxation (T1) -- 1.5.6. Extracting Tensor Information From 43Ca SSNMR Spectra -- 1.5.7. Direct Insight Into Ca Local Environments via Heteronuclear Correlations -- 1.6. Relationships Between Measured Parameters and Structure -- 1.6.1. Calcium First Coordination Shell Average Distance vs Chemical Shift -- 1.6.2. Calcium Coordination Number vs Chemical Shift -- 1.6.3. EFG Tensor Magnitude and Calcium Local Environment -- 2. Calcium-43 Solid-State NMR Literature Accounts.
2.1. Early Double-Resonance/Magnetization Transfer Experiments -- 2.2. Calcium-Containing Inorganics -- 2.2.1. Calcium-Containing High-Temperature Superconductors -- 2.2.2. CaCO3 Polymorphs and Calcium-Containing Carbonates -- 2.2.3. Calcium Hydroxide -- 2.2.4. Silicates, Glasses, Cements, Concretes, and Clays -- 2.2.5. Phosphites, Phosphates, Bones, and Teeth -- 2.2.6. Other Binary and Ternary Inorganics (and Hydrates Thereof) -- 2.2.7. Other Inorganic Applications and Exotica -- 2.3. Biomaterials -- 2.4. Calcium-Containing Organics and Bioorganics -- 2.5. Quantum Chemical Calculations (Usually DFT) -- 2.6. Calcium-43 NMR Crystallography -- 3. Calcium-43 SSNMR Prospective -- Acknowledgments -- References -- Chapter Six: Solid-State NMR Spectroscopy: The Magic Wand to View Bone at Nanoscopic Resolution -- 1. Introduction -- 2. Solid-State NMR Studies of Bone Mineral -- 2.1. MAS NMR of Metal Cations in the Bone Mineral -- 2.2. Phosphorous-31 MAS NMR of Bone -- 3. Solid-State NMR Studies of Bone Organic Matrix -- 3.1. Carbon-13 MAS NMR of Bone -- 3.2. Carbon-13 MAS NMR to Monitor Dehydration-Induced Structural Changes in Bone -- 3.3. Water-Associated Dynamical Changes in Bone Architecture -- 3.4. Measurement of Water-Dependent Backbone Dynamics of Native Collagen in Bone by Natural-Abundance 15N Spectroscopy -- 3.5. Carbon-13 MAS NMR of Articular Cartilage -- 4. Solid-State MAS NMR of the Organic-Mineral Interface in Bone -- 4.1. Collagen-Mineral Interface in Bone: A Sensitive Parameter to Assess Bone Quality -- 5. Enhancing Sensitivity of SSNMR Spectroscopy of Bone and Cartilage -- 5.1. Proton-Detected Ultrafast MAS NMR of Bone -- 5.2. Sensitivity Enhancement by Dynamic Nuclear Polarization (DNP) -- 5.3. Sensitivity Enhancement in Cartilage -- 6. Conclusions -- Acknowledgments -- References -- Index -- Back Cover.
Includes bibliographical references and index.
Spectroscopie de la résonance magnétique nucléaire