http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
1 online resource (xii, 740 pages) : illustrations
Chemistry and chemical technology have been at the heart of the revolutionary developments of the 20th century. The chemical industry has a long history of combining theory (science) and practice (engineering) to create new and useful products. Worldwide, the process industry (which includes chemicals, petrochemicals, petroleum refining, and pharmaceuticals) is a huge, complex, and interconnected global business with an annual production value exceeding 4 trillion dollars. Although in industry special focus is in heterogeneous catalysis, homogeneous, enzymatic, photochemical and electrochemica.
Front Cover; Catalytic Kinetics: Chemistry and Engineering; Copyright; Contents; About the Authors; Preface; Chapter 1: Setting the Scene; Chapter 2: Catalysis; Chapter 3: Elementary Reactions; Chapter 4: Complex Reactions; Chapter 5: Homogeneous Catalytic Kinetics; Chapter 6: Enzymatic Kinetics; Chapter 7: Heterogeneous Catalytic Kinetics; Chapter 8: Kinetics of Catalytic Reactions With Multiple/Multifunctional Catalysts; Chapter 9: Dynamic Catalysis; Chapter 10: Mass Transfer and Catalytic Reactions; Chapter 11: Kinetic Modeling; Index; Back Cover; Dmitry Yu. Murzin; Tapio Salmi.
1.1. History1.2. Catalysis; 1.3. Formal Kinetics; 1.4. Acquisition of Kinetic Data; 1.5. Kinetics and Thermodynamics; 1.6. Examples and Exercises; Reference; 2.1. Homogeneous Catalysis; 2.2. Heterogeneous Catalysis; 2.3. Organocatalysis; 2.4. Examples and Exercises; Reference; 3.1. Reaction Rate Theory; 3.2. Elementary Reactions in Solutions; 3.3. Reaction Mechanism; 3.4. Quasi-equilibrium Approximation; 3.5. Relationship Between Thermodynamics and Kinetics; 3.6. Transition State Theory of Surface Reactions; 3.7. Rates of Reactions on Nonideal Surfaces.
3.8. Deterministic and Stochastic Models3.9. Microkinetic Modeling; 3.10. Compensation Effect; 3.11. Isotope Effects; 3.12. Examples and Exercises; References; 4.1. Steady State Kinetics of Complex Reactions; 4.2. Basic Routes of Complex Reactions; 4.3. Single-Route Steady-State Reaction; 4.4. Topological Analysis of Complex Reactions; 4.5. Electrical Analogy of Reaction Networks; 4.6. Thermodynamic Consistency of Rate Constants for Complex Networks; 4.7. Kinetic Aspects of Selectivity; 4.8. Parallel Reactions: Kinetic Coupling; 4.9. Reduction of Complexity; 4.10. Polynomial Kinetics.
4.11. Examples and ExercisesReferences; 5.1. Homogeneous Acid-Base Catalysis; 5.2. Nucleophilic Catalysis; 5.3. Catalysis by Metal Ions; 5.4. Catalysis by Organometallic Complexes; 5.5. Organocatalysis; 5.6. Polymerization Catalysis; 5.7. Examples and Exercises; References; 6.1. Enzymatic Catalysis; 6.2. Cooperative Kinetics; 6.3. Inhibition; 6.4. Effects of pH; 6.5. Single Molecule Enzymology; 6.6. Enantioselectivity in Enzyme Catalyzed Reactions; 6.7. Generalized Rate Laws for Enzymatic Reactions; 6.8. Heterogeneous Systems/Immobilized Enzymes; 6.9. Examples and Exercises; References.
7.1. Reactions on Ideal Surfaces7.2. Reactions on Nonideal Surfaces; 7.3. Selectivity; 7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode; 7.5. Solvent Effects; 7.6. Ionic Species; 7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions; 7.8. Electrocatalytic Kinetics; 7.9. Photocatalytic Kinetics; 7.10. Nanokinetics; 7.11. Examples and Exercises; References; 8.1. General; 8.2. Combined Catalytic and Noncatalytic Reactions; 8.3. Multiple Catalysts of the Same Type; 8.4. Multiple Catalysts of Different Types; 8.5. Examples and Exercises; References.
Includes bibliographical references and index.
Catalytic Kinetics : Chemistry and Engineering