http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Molecularly Imprinted Catalysts: Principle, Synthesis, and Applications is the first book of its kind to provide an in-depth overview of molecularly imprinted catalysts and selective catalysis, including technical details, principles of selective catalysis, preparation processes, the catalytically active polymers themselves, and important progress made in this field. It serves as an important reference for scientists, students, and researchers who are working in the areas of molecular imprinting, catalysis, molecular recognition, materials science, biotechnology, and nanotechnology.Comprising a diverse group of experts from prestigious universities and industries across the world, the contributors to this book provide access to the latest knowledge and eye-catching achievements in the field, and an understanding of what progress has been made and to what extent it is being advanced in industry.The first book in the field on molecularly imprinted catalysts (MIPs)Provides a systematic background to selective catalysis, especially the basic concepts and key principles of the different MIP-based catalystsFeatures state-of-the art presentation of preparation methods and applications of MIPsWritten by scientists from prestigious universities and industries across the world, and edited by veteran researchers in molecular imprinting and selective catalysis
Front Cover; Molecularly Imprinted Catalysts; Copyright; Contents; Contributors; Editors' Biographies; Foreword; Preface; 1 -- Molecularly Imprinted Polymers for Enzyme-like Catalysis: Principle, Design, and Applications; 1. Introduction; 2. Generic Profile of Molecular Imprinting; 3. Rationally Optimized Interactions within Imprinted Polymers; 4. Some Basic Issues in Imprinted Polymer Catalysts for Selective Catalysis; 5. Molecular Imprinting with Transition State Analogues as the Template; 6. Molecular Imprinting with Substrate as the Template
7. Molecular Imprinting with Product as the Template8. Future Outlook of Molecular Imprinting in Catalysis; 9. Concluding Remarks; Acknowledgments; References; 2 -- Catalytically Active MIP Architectures; 1. Introduction; 2. Transition State Analogues as Templates in Abzyme Mimics; 3. Metal Complexes and Prosthetic Groups in Enzyme Mimics; 4. MIP-Enzyme Architectures; 5. Protein-Based MIPs; 6. Summary and Outlook; References; 3 -- Molecularly Imprinted Catalysts: Synthesis and Applications; 1. Introduction; 2. Design of MIPs for Catalytic Action
3. Different Designs of MIPs for the Biomimetic Catalyst3.1 MIPs as Mimics of Hydrolytic Enzyme; 3.1.1 Ester Hydrolysis; 3.1.2 Stereoselective Hydrolysis; 3.1.3 Charged Hydrogen Bonding and Ester Hydrolysis; 3.1.4 Carbonate and Carbamate Hydrolysis; 3.1.5 Cellulose Hydrolysis; 3.2 MIP with Cholesterol Esterase Activity; 3.3 MIP Catalyst-Enhanced Elimination Reaction; 3.4 Diels-Alder Catalysis; 3.5 Metalloenzyme-Based MIP Catalysts; 3.6 MIP Catalyst for Isomerization Reactions; 4. Recent Progress Made in MIPs to Enhance Their Biomimetic Catalyst Property
4.1 Intrinsic Factors for Enhancement of Biomimetic Catalyst Property4.1.1 High Enzyme Substrate Binding Affinities; 4.1.2 High Synergy between Recognition and Catalysis; 4.1.3 High Catalytic Turnover; 4.1.4 Substantial Rate Accelerations; 4.2 Extrinsic Factors for Enhancement of Biomimetic Catalyst Property; 4.2.1 Development of Computational Methodology Affiliated with MIPs as Biomimetic Catalyst; 5. Conclusion; References; 4 -- Advances and Challenges in the Design and Synthesis of Molecularly Imprinted Microspheres; 1. Introduction
2. Progress in Design and Synthesis of Molecularly Imprinted Microspheres2.1 Methods of Initiation; 2.1.1 Controlled Radical Polymerization; 2.1.2 Iniferters; 2.1.3 Nitroxide-Mediated Polymerization; 2.1.4 Reversible Addition Fragmentation Polymerization; 2.1.5 Atom Transfer Radical Polymerization; 2.1.6 Porogens; 2.2 Cross-linkers and Functional Monomers; 2.3 Other Strategies; 3. Challenges in the Design and Synthesis of Molecularly Imprinted Microspheres; 4. Future Outlook: Processable Star MIPs; 5. Conclusion; References
5 -- Molecularly Imprinted Polymers: Principle, Design, and Enzyme-Like Catalysis
edited by Sonjun Li, Shunsheng Cao, Sergey A. Piletsky, Anthony P.F. Turner.
Includes bibliographical references and index.
Molecularly Imprinted Catalysts : Principles, Syntheses, and Applications