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Electron paramagnetic resonance of d transition metal compounds
1 online resource (xix, 1326 pages) : illustrations
Electron paramagnetic resonance (epr) spectroscopy is a sensitive and versatile method of studying paramagnets, which is finding increasing use in chemistry, biochemistry, earth and materials sciences. The technique is treated both qualitatively and quantitatively, with a progressive increase in sophistication in each succeeding chapter. Following a general introductory chapter, the first half of the book deals with single unpaired electron systems and considers both metal and ligand Zeeman, hyperfine and quadrupole interactions. The simulation of these spectra is discussed, followed by the r.
Front Cover; Electron Paramagnetic Resonance of d Transition Metal Compounds; Copyright Page; Table of Contents; Preface; Chapter 1.; 1.1 THE ELECTRON PARAMAGNETIC RESONANCE EXPERIMENT; 1.2 THE BASIC COMPONENTS OF AN E.P.R. SPECTROMETER AND THEIR FUNCTIONS; 1.3 THE EFFECTS OF INSTRUMENTAL SETTINGS ON E.P.R. SPECTRA; 1.4 SOME EFFECTS OF SAMPLE CHARACTERISTICS ON E.P.R. SPECTRA; 1.5 SOME EFFECTS OF MICROWAVE FREQUENCY; References; Chapter 2. SPIN DOUBLETS IN AN APPLIED MAGNETIC FIELD; A QUALITATIVE TREATMENT; 2.1 ENERGY LEVELS AND SPECTRA FOR A FREE ELECTRON
2.2 SPECTRA OF ISOLATED SINGLE PARAMAGNETS2.3 SPECTRA OF RANDOM COLLECTIONS OF PARAMAGNETS: POWDERS AND GLASSES; Chapter 3. THE QUANTITATIVE DESCRIPTION OF THE SPECTRA FROM SPIN DOUBLETS INTERACTING WITH AN APPLIED MAGNETIC FIELD ONLY; 3.1 THE INTERACTION OF THE ELECTRON WITH A MAGNETIC FIELD; 3.2 THE ESSENTIALS OF PERTURBATION THEORY; 3.3 THE APPLICATION OF PERTURBATION THEORY TO SPIN DOUBLETS; 3.4 THE DETERMINATION OF THE PRINCIPAL g TENSOR ELEMENTS FROM SINGLE CRYSTAL SPECTRA; References; Chapter 4. THE SPECTRA FROM SPIN DOUBLETS INTERACTING WITH A NUCLEAR SPIN: A QUALITATIVE TREATMENT
4.1 INTRODUCTION4.2 ISOTROPIC PARAMAGNETS; 4.3 ANISOTROPY IN METAL HYPERFINE INTERACTIONS; 4.4 ANISOTROPY IN LIGAND HYPERFINE INTERACTION; References; Chapter 5. SPECTRA OF SPIN DOUBLETS INTERACTING WITH A NUCLEAR SPIN: A QUANTITATIVE TREATMENT; 5.1 INTERACTION WITH A METAL NUCLEAR SPIN; 5.2 THE DETERMINATION OF THE g AND A TENSORS FROM SINGLE CRYSTAL STUDIES; 5.3 SPIN DOUBLETS INTERACTING WITH A LIGAND NUCLEAR SPIN ONLY; 5.4 INTERACTION WITH BOTH A METAL NUCLEAR SPIN AND LIGAND NUCLEAR SPINS; References; Chapter 6. NUCLEAR QUADRUPOLE AND NUCLEAR ZEEMAN EFFECTS IN SPIN DOUBLETS
6.1 QUALITATIVE ASPECTS OF METAL NUCLEAR ZEEMAN AND NUCLEAR QUADRUPOLE INTERACTIONS6.2 QUALITATIVE ASPECTS OF LIGAND NUCLEAR QUADRUPOLE AND NUCLEAR ZEEMAN INTERACTIONS; 6.3 QUANTITATIVE ASPECTS OF THE METAL NUCLEAR ZEEMAN INTERACTION; 6.4 QUANTITATIVE ASPECTS OF THE METAL NUCLEAR QUADRUPOLE INTERACTION; 6.5 OTHER METHODS FOR MEASURING QUADRUPOLE INTERACTIONS; References; Chapter 7. SPECTRUM SIMULATION FOR SPIN DOUBLETS; 7.1 PURPOSE OF SIMULATING E.P.R. SPECTRA; 7.2 THE ESSENTIAL STEPS IN SPECTRUM SIMULATION; 7.3 LINESHAPES AND LINEWIDTHS; 7.4 THE CONSTRUCTION AND PRESENTATION OF A SPECTRUM
7.5 THE EFFECTS OF g STRAIN AND A STRAIN7.6 ADDITIONAL SIMULATION DEVICES; 7.7 DETAILED TREATMENTS OF SOME SIMULATION SOFTWARE; 7.8 SIMULATION SOFTWARE; References; Chapter 8. METAL IONS IN CUBIC AND AXIAL LIGAND FIELDS; 8.1 INTRODUCTION; 8.2 TERM ENERGIES AND WA VEFUNCTIONS IN CUBIC CRYSTAL FIELDS; 8.3 TERM SPLITTINGS AND WA VEFUNCTIONS IN AXIAL DISTORTIONS FROM CUBIC SYMMETRIES; References; Chapter 9. THE RELATIONSHIP BETWEEN THE SPIN-HAMILTONIAN PARAMETERS AND THE ELECTRONIC STRUCTURES OF SPIN DOUBLET PARAMAGNETS; 9.1 SPIN-ORBIT COUPLING
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Includes bibliographical references and indexes.
Electron paramagnetic resonance spectroscopy
Spectroscopie de résonance paramagnétique électronique