http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Stone, F. Gordon A. (Francis Gordon Albert)
1 online resource (ix, 372 pages) : illustrations.
This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species that are so reactive that they only have a transient existence at ambient temperatures to those thatare thermally very stable. They are used extensively in the synthesis of useful compounds on both small and large scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advances in organometallic chemistry. Key Features * In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves * Each volume of Advances in Organometallic Chemistry contains an index, and each chapter includes references.
Front Cover; Advances in Oraganometallic Chemistry, Volume 36; Copyright Page; Contents; Contributors; Chapter 1. Early Carboranes and Their Structural Legacy; I. Background and Introduction; II. Carboranes, Carbocations, and Polyboranes; III. Skeletal Electron Pair Bonds Identified by styx and Chop-Stx; IV. Classification Based on Geometry, Empirical Formula, and Electron Pair Bond Relationships; V. Polyborane Lewis Base Adducts; VI. Electron Counting; VII. Carborane Nomenclature; VIII. nido-Carboranes and Related Compounds; IX. arachno-Carboranes and Related Compounds
X. hypho-Carboranes and Related CompoundsXI. Conclusion; References; Chapter 2. Organometallic Derivatives of Fullerenes; I. Introduction; II. Endohedral Complexes; III. Fullerenes with Metal-Containing External Substituents; IV. Interstitial Substitution and Salt Formation; V. Substitution for Framework Carbon; VI. Conclusions; References; Chapter 3. Quantification of Steric Effects in Organometallic Chemistry; I. Introduction; II. Quantification of Steric Size Using Physical Measurements; III. Quantification of Steric Size Using Molecular Mechanics Methods
IV. Quantification of Steric Size Using Chemical MethodsV. Quantification of the Variation in Steric Effect with Distance; VI. Steric Profiles and Thresholds; VII. Quantification of Steric Size Using Molecular Volumes; VIII. Some Applications of Steric Size Measurements; IX. Conclusion; References; Chapter 4. Organotransition Metallic Chemistry of Sulfur Dioxide Analogs; I. Introduction and Scope; II. General Coordination Chemistry; III. Triatomic Interchalcogens; IV. Sulfines (Alkylideneoxo-?4-sulfuranes, Thione-S-oxides); V. N-Sulfinylamines (Iminooxo-?4-sulfuranes)
VI. Sulfur Diimides (Diimino-?4-sulfuranes)VII. Thiazate and Related Ligands; VIII. Concluding Remarks; References; Chapter 5. Silaorganometallic Chemistry on the Basis of Multiple Bonding; I. Introduction; II. Silylene Complexes; III. Silane-Induced CO-Activation Reaction; IV. Cyclic Silylene Complexes; V. Donor-Stabilized Silylyne Complexes; VI. Silaethene Complexes; VII. Silaimine Complexes; VIII. Disilaethene Complexes; IX. Silatrimethylenemethane Complexes; X. Metallasilaallenes; XI. Prospects; References; Chapter 6. Organometallic Chemistry of the Lanthanides; I. Introduction
II. Homoleptic Alkyl ComplexesIII. Alkoxides; IV. Thiolates; V. Selenides and Tellurolates; VI. Nitrogen Donor Ligands; VII. p Adducts; VIII. p-Arene Complexes; IX. Cyclooctatetraene Complexes; X. Carboranes; XI. Heterocyclopentadienyls; XII. Monocyclopentadienyl Complexes; XIII. Bis(cyclopentadienyl) Complexes; XIV. Bis(cyclopentadienyl) Ligand Variations; XV. Reactivity of (C5Me5)2Ln with Aluminum/Gallium Reagents; XVI. Isocarbonyls and Lanthanide Transition Metal Bonds; XVII. ?-C-H-Ln versus ß-Si-Me-Ln Interactions; XVIII. Thermodynamics; XIX. Low Oxidation State Chemistry
Includes bibliographical references and index.
Advances in organometallic chemistry. Volume 36
Advances in organometallic chemistry ; v. 36