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| LEADER |
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| 001 |
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| 005 |
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| 006 |
m o d |
| 007 |
cr cnu---unuuu |
| 008 |
090605t19871987enka ob 001 0 eng d |
| 040 |
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|a N$T
|b eng
|e rda
|e pn
|c N$T
|d OCLCQ
|d EBLCP
|d IDEBK
|d OCLCQ
|d OCLCF
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|d DEBSZ
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| 019 |
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|a 505140565
|a 646756989
|a 808998506
|a 1340056919
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| 020 |
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|a 9780080581620
|q (electronic bk.)
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| 020 |
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|a 0080581625
|q (electronic bk.)
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| 020 |
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|z 0120335239
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|z 9780120335237
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| 024 |
8 |
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|a (WaSeSS)ssj0000334382
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| 035 |
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|a (OCoLC)371539059
|z (OCoLC)505140565
|z (OCoLC)646756989
|z (OCoLC)808998506
|z (OCoLC)1340056919
|
| 050 |
|
4 |
|a QD476
|b .A38eb vol. 23
|
| 060 |
|
4 |
|a QD 476 A244 v.23 1987
|
| 072 |
|
7 |
|a SCI
|x 013040
|2 bisacsh
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| 082 |
0 |
4 |
|a 547/.13
|2 22
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| 049 |
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|a TXAM
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| 245 |
0 |
0 |
|a Advances in physical organic chemistry.
|n Volume 23 /
|c edited by D. Bethell.
|
| 264 |
|
1 |
|a London ;
|a Orlando :
|b Academic Press,
|c 1987.
|
| 300 |
|
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|a 1 online resource (vii, 348 pages) :
|b illustrations
|
| 336 |
|
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|a text
|b txt
|2 rdacontent
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| 337 |
|
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|a computer
|b c
|2 rdamedia
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| 338 |
|
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|a online resource
|b cr
|2 rdacarrier
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| 347 |
|
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|a text file
|2 rdaft
|0 http://rdaregistry.info/termList/fileType/1002.
|
| 490 |
0 |
|
|a Advances in physical organic chemistry ;
|v v. 23.
|
| 504 |
|
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|a Includes bibliographical references and indexes.
|
| 588 |
0 |
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|a Print version record.
|
| 505 |
0 |
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|a Front Cover; Advances in Physical Organic Chemistry, Volume 23; Copyright Page; Contents; Contributors to Volume 23; Chapter 1. The Nucleophilicity of Metal Complexes Towards Organic Molecules; 1. The scope of the review; 2. Introduction to metal complexes as nucleophiles; 3. Types of metal-based nucleophiles; 4. The scale of nucleophilicity; 5. The influence of the solvent on the nucleophilicity; 6. Stereochemical changes at a saturated carbon centre; 7. Stereochemical changes at an unsaturated carbon centre; 8. Stereochemical changes at the metal; 9. The iodide catalysis effect.
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| 505 |
8 |
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|a 10. The reactions of binuclear complexes11. The reactivity of the carbon centre; 12. The reactions of a,?-dihalogenoalkanes; 13. Activation parameters; 14. Thermodynamics of reactions involving metal nucleophiles; 15. Activation of carbon-hydrogen bonds; 16. Applications; 17. Ad finem; Chapter 2. Isotope Effects on nmr Spectra of Equilibrating Systems; 1. Introduction; 2. Applications; Chapter 3. The Mechanisms of Reactions of ß-Lacta m Antibiotics; 1. Introduction; 2. Mode of action of ß-lactam antibiotics; 3. Is the antibiotic ß-lactam unusual?
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| 505 |
8 |
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|a 4. Alkaline hydrolysis and structure: chemical reactivity and relationships5. Acid hydrolysis; 6. Spontaneous hydrolysis; 7. Buffer catalysed hydrolysis; 8. Metal-ion catalysed hydrolysis; 9. Micelle catalysed hydrolysis of penicillins; 10. Cycloheptaamylose catalysed hydrolysis; 11. The aminolysis of ß-lactam antibiotics; 12. The stepwise mechanism for expulsion of C(3')-leaving groups in cephalosporins; 13. Reaction with alcohols and other oxygen nucleophiles; 14. Epimerisation of penicillin derivatives.
|
| 505 |
8 |
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|a Chapter 4. Free Radical Chain Processes in Aliphatic Systems involving an Electron Transfer Process1. Introduction; 2. Free radical chain processes involving nucleophiles; 3. Free radical chain processes involving electron transfer between neutral substances; 4. Free radical chain reactions involving radical cations; 5. Concluding remarks; Author Index; Cumulative Index of Authors; Cumulative Index of Titles.
|
| 650 |
|
0 |
|a Physical organic chemistry.
|
| 650 |
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0 |
|a Chemistry, Organic.
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| 650 |
|
0 |
|a Chemistry, Physical and theoretical.
|
| 650 |
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2 |
|a Chemistry, Organic
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| 650 |
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2 |
|a Chemistry, Physical
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| 650 |
|
6 |
|a Chimie organique physique.
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| 650 |
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6 |
|a Chimie organique.
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| 650 |
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6 |
|a Chimie physique et théorique.
|
| 650 |
|
7 |
|a organic chemistry.
|2 aat
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| 650 |
|
7 |
|a physical chemistry.
|2 aat
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| 650 |
|
7 |
|a SCIENCE
|x Chemistry
|x Organic.
|2 bisacsh
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| 650 |
|
7 |
|a Physical organic chemistry
|2 fast
|
| 655 |
|
7 |
|a Electronic books.
|2 local
|
| 700 |
1 |
|
|a Bethell, D.
|q (Donald)
|1 https://id.oclc.org/worldcat/entity/E39PCjxc6R37MCThBTrHTxv9rC
|
| 710 |
2 |
|
|a ScienceDirect (Online service)
|
| 758 |
|
|
|i has work:
|a Advances in physical organic chemistry Volume 23 (Text)
|1 https://id.oclc.org/worldcat/entity/E39PCGqMv8WJTmBJHy7b4hgMyd
|4 https://id.oclc.org/worldcat/ontology/hasWork
|
| 776 |
0 |
8 |
|i Print version:
|t Advances in physical organic chemistry. Volume 23.
|d London ; Orlando : Academic Press, 1987
|z 9780120335237
|w (OCoLC)39517221
|
| 856 |
4 |
0 |
|u http://proxy.library.tamu.edu/login?url=https://www.sciencedirect.com/science/bookseries/00653160/23
|z Connect to the full text of this electronic book
|t 0
|
| 955 |
|
|
|a Elsevier ScienceDirect 2026-2027
|
| 994 |
|
|
|a 92
|b TXA
|
| 999 |
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f |
|i 19271cd3-6d6b-4a91-ad78-fd9bca559510
|s 31d013bc-e692-4344-89cf-82b1bd0b40a2
|t 0
|
| 952 |
f |
f |
|a Texas A&M University
|b College Station
|c Electronic Resources
|s www_evans
|d Available Online
|t 0
|e QD476 .A38eb vol. 23
|h Library of Congress classification
|
| 998 |
f |
f |
|a QD476 .A38eb vol. 23
|t 0
|l Available Online
|