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1 online resource (vii, 388 pages) : illustrations
Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.
Front Cover; Advances in Inorganic Chemistry, Volume 44; Copyright Page; Contents; Chapter 1. Organometallic Complexes of Fullerenes; I. Introduction; II. Synthesis; III. Characterization; IV. Structure; V. Effects on Bonding of Metal Complexation; VI. Physical Properties and Chemical Reactivity; VII. Conclusion; List of Abbreviations; References; Chapter 2. Group 6 Metal Chalcogenide Cluster Complexes and Their Relationships to Solid-state Cluster Compounds; I. Introduction; II. Octahedral Clusters; III. Tetrahedral Clusters; IV. Rhomboidal Clusters; V. Triangular Clusters; References
Chapter 3. Macrocyclic Chemistry of NickelI. Introduction; II. Nickel(II) Complexes; III. Nickel(III) Complexes; IV. Nickel(I) Complexes; References; Chapter 4. Arsenic and Marine Organisms; I. Introduction; II. Arsenic Concentrations in Marine Samples; III. Key Arsenic Compounds: Chemical and Analytical Considerations; IV. Occurrence and Distribution of Arsenic Compounds in Marine Samples; V. Toxicological Considerations; VI. Biotransformation of Marine Arsenic Compounds; VII. Origin of Arsenobetaine; References
Chapter 5. The Biochemical Action of Arsonic Acids Especially as Phosphate AnaloguesI. Scope of Review.; II. The Biochemistry of Arsenate; III. The Biochemistry of Arsenite; IV. Arsonates as Analogues of Natural Phosphates or Phosphonates; V. Arsonates as Analogues of Nonphosphate Metabolites; VI. Other Biological Actions of Arsonates; VII. Aspects of the Chemistry of Arsonates; VIII. Summary; References; Chapter 6. Intrinsic Properties of Zinc(Il) Ion Pertinent to Zinc Enzymes; I. Introduction; II. Why Zinc(II) and Serine in Alkaline Phosphatase?; III. Reactivity of Zinc(II)-Bound Thiolate
IV. Dinuclear Metal Systems for Group Transferases and Their ModelsV. Concluding Remarks; References; Chapter 7. Activation of Dioxygen by Cobalt Group Metal Complexes; I. Introduction; II. Nitrogen Donor Ligands; III. Phosphorus Donor Ligands; IV. Oxygen and Sulfur Donor Ligands; V. Carbon Donor Ligands; VI. Special Applications; VII. Concluding Remarks; References; Chapter 8. Recent Developments in Chromium Chemistry; I. Introduction and Scope; II. Oxo and Peroxo Ligands; III. Organochromium Compounds; IV. Polynuclear Chromium(III) Complexes; V. Polyaminocarboxylic Ligands
VI. Conjugate-Base Mechanism in Reactions of Chromium(III)Amine ComplexesReferences; Index; Contents of Previous Volumes
Includes bibliographical references and index.
Advances in inorganic chemistry. Volume 44