Optical multidimensional coherent spectroscopy /
Aimed at post-doctoral scientists, researchers, and graduate students in physics, this book provides an introduction to optical multidimensional coherent spectroscopy, a relatively new method of studying materials based on using ultrashort light pulses to perform spectroscopy.
| Main Authors: | , , , , |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Oxford ; New York, NY :
Oxford University Press,
[2023]
|
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Cover
- titlepage
- copyright
- dedication
- preface
- Acknowledgements
- Table of symbols
- Table of acronyms
- contents
- Basics of ultrafast spectroscopy
- Basics of spectroscopy: linear versus nonlinear
- Ultrashort pulses
- Ultrafast nonlinear/coherent spectroscopy
- The density matrix
- Bloch sphere representation of quantum states
- Introduction to multidimensional coherent spectroscopy
- Concepts of multidimensional coherent spectroscopy
- Coherent spectroscopy
- Multidimensional coherent spectroscopy
- Spectrum classification
- Density matrix formalism and double-sided Feynman diagrams
- Interpreting MDCS in the perturbative limit
- Double-sided Feynman diagrams
- Measured observables
- Putting it all together
- Case study: Two-level system
- Phase matching
- Two-dimensional infrared (2D IR) spectroscopy
- Interpretation of multidimensional coherent spectra
- Isolated two-level system
- Inhomogeneously broadened ensemble of two-level systems
- Gaussian inhomogeneity, constant homogeneous linewidth
- Large inhomogeneity
- Coherent coupling signatures
- Incoherent coupling signatures
- Doubly excited states and many-body interactions
- Double-quantum spectra
- Zero-quantum spectra
- Three-dimensional coherent spectroscopy
- Nonrephasing pathways and purely absorptive spectra
- Finite-pulse effects
- Mathematical formulations
- Example spectra
- Further applications
- Experimental implementations
- Experimental requirements and considerations
- Precision and stability of time delays
- Isolation of the signal
- Detection of the signal
- Overview of experimental approaches
- Actively stabilized box geometry
- Phase modulated collinear geometry
- Comparison of different approaches
- Data analysis
- Multidimensional coherent spectroscopy of atomic ensembles
- Single- and zero-quantum 2D spectra of atomic vapors
- MDCS in optically thick samples
- Probing many-body interactions with double-quantum 2D spectroscopy
- Probing many-body correlations with multi-quantum 2D spectroscopy
- Frequency comb-based multidimensional coherent spectroscopy
- Introduction to frequency combs and dual-comb spectroscopy
- Frequency comb-based four-wave-mixing spectroscopy
- Frequency comb-based single-quantum 2D spectroscopy
- Frequency comb-based double-quantum 2D spectroscopy
- Tri-comb spectroscopy
- Two-dimensional spectroscopy of semiconductor quantum wells
- Introduction to semiconductor optics
- Many-body signatures in one-quantum 2D spectra
- Many-body signatures in double- and multi-quantum 2D spectra
- Two-dimensional spectroscopy of coupled quantum wells
- Quantum well exciton-polaritons in microcavities
- Three-dimensional coherent spectroscopy
- Fifth-order 3D infrared spectroscopy
- Fifth-order 3D electronic spectroscopy
- Third-order 3D electronic spectroscopy