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Radical Brook Rearrangement

In-depth monograph presenting innovative radical methodologies in the Brook rearrangement and their utility in organic synthesis Radical Brook Rearrangement chronicles the evolution of radical Brook rearrangements, synthesizes recent advances in the field, and outlines future research directions.

Bibliographic Details
Main Author: Shen, Xiao
Other Authors: Zhang, Yunxiao, Zhou, Gang
Format: eBook
Language:English
Published: Newark : John Wiley & Sons, Incorporated, 2026.
Subjects:
Organic compounds > Synthesis.
Radicals (Chemistry)
Chemical reactions.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Cover
  • Title Page
  • Copyright
  • Contents
  • Preface
  • Acknowledgments
  • List of Abbreviations
  • 1. Introduction
  • References
  • 2. Generation of a -Siloxy Radicals with a -Silyl Alcohols Through Radical Brook Rearrangement
  • 2.1 Metal Free Reactions
  • 2.2 Metal-catalyzed Reactions
  • 2.3 Photocatalyzed Reactions
  • 2.4 Electrophotocatalyzed Reactions
  • 2.5 Other Reactions
  • References
  • 3. Generation of a -Siloxy Radicals with Acylsilanes Through Radical Brook Rearrangement
  • 3.1 Radical Initiation
  • 3.2 Metal-catalyzed Reactions
  • 3.3 Photocatalyzed Reactions
  • 3.4 Other Reactions
  • References
  • 4. Generation of a -Siloxy Silyl Radicals with (TMS)3SiOH Through Radical Brook Rearrangement
  • 4.1 Metallaphotoredox Reactions
  • 4.2 Photoredox Reactions
  • 4.3 Metallaphotoredox Reactions with (TMS)3SiNHAd
  • References
  • 5. Generation of Siloxycarbenes for Nucleophilic Addition Reaction
  • 5.1 Aldehydes or Ketones as Electrophiles
  • 5.2 Other Electrophilic Reagents
  • References
  • 6. Generation of Siloxycarbenes for Insertion Reaction
  • 6.1 Siloxycarbene Insertion Reactions into O-H Bond
  • 6.2 Siloxycarbene Insertion Reactions into N-H Bond
  • 6.3 Siloxycarbene Insertion Reactions into X-H Bond
  • 6.4 Siloxycarbene Insertion Reactions into B-C Bond
  • 6.5 Siloxycarbene Insertion Reactions into C-H Bond
  • References
  • 7. Generation of Siloxycarbenes for Cycloaddition Reaction
  • 7.1 [2 + 1] Cycloaddition with Alkynes
  • 7.2 [2 + 1] Cycloaddition with Alkenes
  • 7.3 [4 + 1] Cycloaddition Reaction with Dienes and a , ß -Unsaturated Ketones
  • 7.4 [2 + 2] Cycloaddition Reaction of a -Ketoacylsilanes with Imines
  • 7.5 Other Reaction of Siloxycarbene
  • References
  • 8. Metal Siloxycarbene and Aminooxycarbene Reaction
  • 8.1 Metal Siloxycarbene Reactions
  • 8.2 Aminooxycarbene Reactions
  • References
  • 9. Generation of Silenes Through Radical Brook Rearrangement
  • 9.1 Insertion Reactions
  • 9.2 [2 + 2] Cycloaddition Reaction
  • 9.3 [4 + 2] Cycloaddition Reaction
  • 9.4 Other Reaction
  • References
  • Index
  • EULA