The organometallic chemistry of N-heterocyclic carbenes /
The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and...
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| Format: | eBook |
| Language: | English |
| Published: |
Hoboken, NJ :
John Wiley & Sons, Inc.,
2017.
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| Edition: | First edition. |
| Series: | Inorganic chemistry : a textbook series
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Foreword; Preface; List of Abbreviations and Definitions; 1 General Introduction; 1.1 Definition of Carbenes; 1.2 Historical Overview of Carbenes, N?Heterocyclic Carbenes, and Their Complexes; References; 2 General Properties of Classical NHCs and Their Complexes; 2.1 Stabilization in NHCs (Push?Pull Effect); 2.2 Backbone Differences and Their Implications; 2.3 Dimerization of Carbenes; 2.4 Nomenclature of N?Heterocyclic Carbenes; 2.5 Electronic Properties of NHCs and Different Electronic Parameters; 2.6 Steric Properties of NHCs.
- 2.7 Structural Diversity of NHC Ligands and Their ComplexesReferences; 3 Synthetic Aspects; 3.1 General Routes to Azolium Salts as NHC Precursors; 3.2 General Routes to Free NHCs; 3.3 General Synthetic Routes to NHC Complexes; References; 4 Group 10 Metal(0)?NHC Complexes; 4.1 Nickel(0)?NHC Complexes; 4.2 Palladium(0)?NHC Complexes; 4.3 Platinum(0)?NHC Complexes; References; 5 Group 10 Metal(II)?NHC Complexes; 5.1 Nickel(II)?NHC Complexes; 5.2 Palladium(II)?NHC Complexes; 5.3 Platinum(II)?NHC Complexes; References; 6 Group 11 Metal?NHC Complexes; 6.1 Copper(I)?NHC Complexes.
- 6.2 Silver(I)?NHC Complexes6.3 Gold(I)?NHC Complexes; 6.4 Gold(III)?NHC Complexes; References; 7 Ruthenium, Rhodium, and Iridium Metal?NHC Complexes; 7.1 Ruthenium(II)?NHC Complexes; 7.2 Rhodium(I)? and Rhodium(III)?NHC Complexes; 7.3 Iridium(I)? and Iridium(III) NHC Complexes; References; 8 Beyond Classical N?heterocyclic Carbenes I; 8.1 N, S?Heterocyclic Carbenes (NSHCs); 8.2 N, O?Heterocyclic Carbenes (NOHCs); 8.3 Expanded Six?Membered NHCs; 8.4 Expanded Seven? and Eight?Membered NHCs; 8.5 Expanded Diamidocarbenes (DAC); References; 9 Beyond Classical N?heterocyclic Carbenes II.
- 9.1 Abnormal Imidazolin?4/5?ylidenes (aNHC)9.2 Mesoionic 1,2,3?Triazolin?5?ylidenes (MIC); 9.3 Pyrazolin?3/5?ylidenes (Pyry) and Indazolin?3?ylidenes (Indy); 9.4 Cyclic (Alkyl)(Amino)Carbenes (CAACs) Or Pyrrolidin?2?ylidenes; 9.5 Remote N?Heterocyclic Carbenes (rNHC); References; Index.