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CO2-switchable Materials : Solvents, Surfactants, Solutes and Solids.

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Summarizing progress in the preparation and applications of CO2-responsive materials, this is an ideal resource for researchers working in green chemistry, chemical engineering, polymer chemistry and material science.

Bibliographic Details
Main Author: Jessop, Philip G.
Corporate Author: Knovel (Firm)
Other Authors: Cunningham, Michael F.
Format: eBook
Language:English
Published: Cambridge : Royal Society of Chemistry, 2020.
Series:ISSN.
Subjects:
Carbon dioxide > Properties.
Smart materials.
Materials science.
Polymer engineering.
Polymers.
Gaz carbonique > Propriétés.
Matériaux intelligents.
Science des matériaux.
Génie des polymères.
Polymères.
polymer science.
polymers.
Physical & Theoretical.
Sustainable Development.
Development.
BUSINESS & ECONOMICS.
Environmental.
TECHNOLOGY & ENGINEERING.
Chemistry.
SCIENCE.
Materials science
Polymer engineering
Polymers
Smart materials
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Cover
  • Preface
  • Acknowledgements
  • Contents
  • 1 Introduction to CO2-switchable Materials
  • References
  • 2 The Chemistry of CO2-triggered Switchable Materials
  • 2.1 Introduction to the Different Reactions
  • 2.2 Conversion of Neutral Bases to Bicarbonate Salts
  • 2.3 Bicarbonate Chemistry (Anionic Bases)
  • 2.4 Alkylcarbonate Chemistry
  • 2.5 Carbamic Acid/Carbamate Chemistry
  • 2.5.1 Two-component Systems
  • 2.5.2 One-component Systems
  • 2.6 Urea Chemistry
  • 2.7 Other Reactions of CO2
  • 2.8 Other Gases
  • 2.9 Environmental Considerations
  • 2.10 Conclusions
  • References
  • 3 CO2-switchable Aqueous Solutions
  • 3.1 Introduction to Switchable Water (SW)
  • 3.2 Switching the Ionic Strength
  • 3.3 Switching the Stability of Emulsions
  • 3.4 Switching the Stability of Suspensions
  • 3.5 Switching the Ability to Solubilize Organic Compounds
  • 3.6 Switching the Viscosity
  • 3.7 Switching the Osmotic Pressure and Osmolality
  • 3.8 Switching Other Properties
  • 3.9 Aqueous Biphasic Systems
  • 3.10 Environmental Considerations
  • 3.11 Conclusions
  • References
  • 4 CO2-switchable Solutes
  • 4.1 Introduction
  • 4.2 Controlling Solute Reactivity
  • 4.3 Controlling Solute Colour and Fluorescence
  • 4.3.1 Colour or Fluorescence Changes Due to CO2-induced pH Change
  • 4.3.2 Colour or Fluorescence Changes Due to Reactions with CO2
  • 4.4 Controlling Solute Solubility
  • 4.4.1 Solutes Having Switchable Solubility in Water
  • 4.4.2 Solutes Having Switchable Solubility in Organic Solvents
  • 4.5 Controlling Solute Partitioning
  • 4.5.1 Partitioning of Amine or Amidine Solutes
  • 4.5.2 Partitioning of Acidic Solutes
  • 4.6 Environmental Considerations
  • 4.7 Conclusions
  • References
  • 5 Switchable-polarity Solvents
  • 5.1 Introduction to Switchable and Tunable Organic Solvents
  • 5.1.1 Triggering Changes in Organic Solvents by Physical Means
  • 5.1.2 Triggering Changes in Organic Solvents by Chemical Reactions
  • 5.2 Types of Switchable-polarity Solvents (SPS)
  • 5.2.1 Alcohol/Base SPS
  • 5.2.2 Carbamate SPS
  • 5.2.3 Permanently Ionic SPS
  • 5.2.4 Other Types of SPS
  • 5.3 Property Changes in SPS upon Switching
  • 5.4 Applications of SPS
  • 5.4.1 Separations Using SPS
  • 5.4.2 Reactions in SPS
  • 5.4.3 Other Applications of SPS
  • 5.5 Environmental Considerations
  • References
  • 6 CO2-switchable Hydrophilicity Solvents
  • 6.1 Introduction to Switchable-hydrophilicity Solvents (SHS)
  • 6.2 Types of SHS
  • 6.2.1 Basic SHS
  • 6.2.2 Acidic SHS
  • 6.3 Physical Chemistry of Basic SHS
  • 6.3.1 The Phase Behaviour of SHS
  • 6.3.2 Restrictions on the Basicity and Structure of Basic SHS
  • 6.3.3 Properties of SHS/Water Mixtures
  • 6.4 Applications of SHS
  • 6.4.1 Preparative Separations Using SHS
  • 6.4.2 Analytical Separations using SHS
  • 6.4.3 Reactions in SHS
  • 6.4.4 Emulsion, Particle, and Gel Formation Using SHS
  • 6.5 Environmental Considerations