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Gaseous hydrogen embrittlement of materials in energy technologies
Mechanisms, modelling and future developments
1 online resource (xx, 500 pages) : illustrations.
Many modern energy systems are reliant on the production, transportation, storage, and use of gaseous hydrogen. The safety, durability, performance and economic operation of these systems is challenged by operating-cycle dependent degradation by hydrogen of otherwise high performance materials. This important two-volume work provides a comprehensive and authoritative overview of the latest research into managing hydrogen embrittlement in energy technologies. Volume 2 is divided into three parts, part one looks at the mechanisms of hydrogen interactions with metals including chapters on.
Cover; Gaseous hydrogen embrittlement of materials in energy technologies: Volume 2: Mechanisms, modelling and future developments; Copyright; Contents; Contributor contact details; Introduction; Part I Mechanisms of hydrogen interactions with metals; 1Hydrogen adsorption on the surface of metals; 1.1 Introduction; 1.2 Adsorption effect; 1.3 Elementary processes in adsorption; 1.4 The structure of the H-Me adsorption complex; 1.5 Kinetic equations and equilibrium; 1.6 Conclusions; 1.7 References; 2 Analysing hydrogen in metals: bulk thermal desorption spectroscopy (TDS) methods.
2.1 Introduction2.2 Principle of thermal desorption spectroscopy (TDS) measurements; 2.3 Experimental aspects of thermal desorption spectroscopy (TDS); 2.4 Complementary techniques; 2.5 Conclusion; 2.6 References; 3Analyzing hydrogen in metals: surface techniques; 3.1 Introduction; 3.2 Available techniques for analyzing hydrogen; 3.3 Methods for analyzing hydrogen in metals: basic principles; 3.4 Applications of hydrogen analysis methods; 3.5 Ion beam-based methods; 3.6 Conclusion; 3.7 References; 4Hydrogen diffusion and trapping in metals; 4.1 Introduction: hydrogen uptake.
4.2 Solubility of hydrogen in metals4.3 Principles of hydrogen diffusion and trapping; 4.4 Modelling of hydrogen diffusion and trapping; 4.5 Measurement of hydrogen diffusion; 4.6 Hydrogen diffusion data; 4.7 Conclusions; 4.8 Acknowledgements; 4.9 References; 5Control of hydrogen embrittlement of metals by chemical inhibitors and coatings; 5.1 Introduction; 5.2 Chemical barriers to hydrogen environment embrittlement (HEE): gaseous inhibitors; 5.3 Physical barriers to hydrogen environment embrittlement (HEE); 5.4 Conclusions and future trends; 5.5 Sources of further information and advice.
5.6 References6The role of grain boundaries in hydrogen induced cracking (HIC) of steels; 6.1 Introduction: modes of cracking; 6.2 Impurity effects; 6.3 Temper embrittlement and hydrogen; 6.4 Tempered-martensite embrittlement and hydrogen; 6.5 Future trends; 6.6 Conclusions; 6.7 References; 7Influence of hydrogen on the behavior of dislocations; 7.1 Introduction; 7.2 Dislocation motion; 7.3 Evidence for hydrogen dislocation interactions; 7.4 Discussion; 7.5 Conclusions; 7.6 Acknowledgements; 7.7 References; Part II Modelling hydrogen embrittlement.
8Modeling hydrogen induced damage mechanisms in metals8.1 Introduction; 8.2 Pros and cons of proposed mechanisms; 8.3 Evolution of decohesion models; 8.4 Evolution of shear localization models; 8.5 Summary; 8.6 Conclusions; 8.7 Acknowledgements; 8.8 References; 9Hydrogen effects on the plasticity of face centred cubic (fcc) crystals; 9.1 Introduction and scope; 9.2 Study of dynamic interactions and elastic binding by static strain ageing (SSA); 9.3 Modelling in the framework of the elastic theory of discrete dislocations.
edited by Richard P. Gangloff, Brian P. Somerday.
Richard P. Gangloff is the Ferman W. Perry Professor of Materials Science and Engineering at the University of Virginia, Charlottesville, VA, USA. Brian P. Somerday is a member of the technical staff at Sandia National Laboratories, Livermore, California, USA. Both editors are world authorities in the field of hydrogen embrittlement.
Gaseous Hydrogen Embrittlement of Materials in Energy Technologies : Mechanisms, Modelling And Future Developments