Cover Image

Palladium and norbornene cooperative catalysis : fundamentals and applications /

A comprehensive exploration of Pd/Norbornene (NBE) catalysis In Palladium and Norbornene Cooperative Catalysis: Fundamentals and Applications, renowned researcher Professor Guangbin Dong delivers a systematic and comprehensive discussion of Pd/NBE catalysis, including its mechanisms, scopes, applica...

Full description

Bibliographic Details
Other Authors: Dong, Guangbin (Editor)
Format: eBook
Language:English
Published: Weinheim, Germany : Wiley-VCH, 2025.
Subjects:
Palladium catalysts.
Norbornene.
Catalysis.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Preface
  • 1 The Palladium/Norbornene-Catalyzed Annulation Chemistry: Rapid Access to Diverse Ring Structures 1 Mark Lautens and Xavier Abel-Snape
  • 1.1 Introduction
  • 1.2 Intramolecular Cyclizations
  • 1.3 Intermolecular Cyclizations Following Intermolecular Ortho Functionalization
  • 1.4 Cyclizations with Three-Membered Heterocycles as Both the Electrophile and Terminating Reagent
  • 1.5 Norbornene/Norbornadiene-Integrated Cyclizations
  • 1.6 One-Pot Postcatalytic Intramolecular Cyclizations
  • 1.7 Summary
  • 2 Diverse Ipso Arene Functionalization by the Palladium/Norbornene Cooperative Catalysis 45 Bo-Sheng Zhang and Yong-Min Liang
  • 2.1 Introduction
  • 2.2 Ipso Functionalization Reaction in the Pd/NBE Catalytic Cycle
  • 2.3 Type of Ipso Functionalization Reactions
  • 2.4 Prospects and Challenges of Ipso Functionalization
  • 3 Diverse Ortho C--H Functionalization by the Palladium/Norbornene Cooperative Catalysis 89 Xin Liu and Guangbin Dong
  • 3.1 Introduction
  • 3.2 Carbon-Electrophile
  • 3.3 Nitrogen-Electrophile
  • 3.4 Sulfur-Electrophile
  • 3.5 Oxygen-Electrophile
  • 3.6 Conclusion and Outlook
  • 4 Asymmetric Palladium/Norbornene Cooperative Catalysis 129 Shuming Zhan and Zhenhua Gu
  • 4.1 Introduction
  • 4.2 Stereochemistry Controlled by the Substrate
  • 4.3 Catalytic Asymmetric Transformations Controlled by Chiral Ligands
  • 4.4 Catalytic Asymmetric Transformation Controlled by Chiral Norbornenes
  • 4.5 Summary and Outlook
  • 5 Pd(II)-Initiated Palladium/Norbornene Cooperative Catalysis 157 Hong-Gang Cheng, Kevin Wu, Qianghui Zhou, and Jin-Quan Yu
  • 5.1 Introduction
  • 5.2 Pd/NBE-catalyzed C-H Functionalization of NH-containing Heteroarenes
  • 5.3 Directing Group-Enabled meta-C-H Functionalization of Arenes
  • 5.4 Directing Group-Free Mono- and Difunctionalization of (Hetero)Arenes
  • 5.5 Template-Enabled Remote C-H Functionalization
  • 5.6 Enantioselective Remote C-H Functionalization
  • 5.7 Borono-Catellani Reactions
  • 5.8 Conclusion and Outlook
  • 6 Functionalization of Heteroarenes by the Palladium/Norbornene Cooperative Catalysis 199 Jung Min Joo
  • 6.1 Introduction
  • 6.2 Pd/NBE Reactions of Five-Membered Haloheteroarenes
  • 6.3 Pd/NBE Reactions of Six-Membered Haloheteroarenes
  • 6.4 Pd/NBE Reactions of Parent Heteroarenes
  • 6.5 Conclusion
  • 7 Addressing the Substrate Limitation in the Palladium/Norbornene Cooperative Catalysis 225 Zhao Wu
  • 7.1 Introduction
  • 7.2 Ortho Constraint
  • 7.3 Meta Constraint
  • 7.4 Aryl Iodide Constraint
  • 7.5 Beyond Aromatic Substrates
  • 7.6 Conclusions and Outlook
  • 8 Application of the Palladium/Norbornene Cooperative Catalysis to Synthesis of Natural Products and Materials 265 Jianchun Wang
  • 8.1 Applications in Synthesis of Natural Products and Drugs
  • 8.2 Applications in Synthesis of Organic Aromatic Materials
  • 8.3 Summary
  • References
  • Index.