Fluorine-containing synthons /

Annotation

Bibliographic Details
Corporate Authors: American Chemical Society. Division of Fluorine Chemistry, American Chemical Society. Division of Medicinal Chemistry, American Chemical Society. Division of Organic Chemistry
Other Authors: Soloshonok, V. A.
Format: eBook
Language:English
Language Notes:English.
Published: Washington, DC : American Chemical Society : Distributed by Oxford University Press, ©2005.
Series:ACS symposium series ; 911.
Subjects:
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Recent advances in perfluoroalkylation methodology
  • New nucleophilic fluoroalkylation chemistry
  • Fluoroform, fluoral, trifluoroacetic, and trifluoromethanesulfinic acids derivatives as new reagents for the introduction of polyfluorinated moieties SF₅-synthons : pathways to organic derivatives of SF₆
  • Stereoselective synthesis of monofluoroalkenes using cross-coupling reactions
  • A new in situ room temperature approach to fluorinated vinylzinc reagents and fluorinated styrenes
  • Vinyl fluorides in cycloadditions
  • Asymmetric synthesis of monofluorinated compounds having the fluorine atom vicinal to pi-systems
  • A new aspect of fluoroalkylated acetylenes : synthesis and applications
  • hydrometallation and carbometallation
  • Functionalized fluorinated allenes
  • Regioexhaustive functionalizations : to miss an isomer means to miss a chance
  • Perfluoroketene dithioacetals : versatile building blocks toward trifluoromethyl heterocycles
  • Highly functionalized heterocycles and macrocycles from pentafluoropyridine
  • Synthetic methods for the preparation of ring-fluorinated heterocycles via intramolecular vinylic substitution of gem-difluoroalkenes
  • Selective anodic fluorination of heterocyclic compounds
  • Polyfluorinated binaphthol ligands in asymmetric catalysis
  • Selective fluorination of biologically important imidazoles and indoles
  • Functional group transformations at alpha-carbon to trifluoromethyl group
  • Use of trifluoroacetaldehyde ethyl hemiacetal in a simple and practical synthesis of beta-hydroxy-beta-trifluoromethylated ketones
  • Fluorinated synthon : asymmetric catalytic reactions
  • Industrial synthetic application of fluoral and 3,3-dichloro-1,1,1-trifluoroacetone as fluorinated synthons
  • Synthesis and utility of fluorinated acylsilanes
  • The role of fluorine-containing methyl groups toward diastereofacial selection
  • Reactions of unsaturated organometallic reagents on trifluoroacetaldimines
  • Optically active gem-difluorocyclopropanes : synthesis and application for novel molecular materials
  • General methods for the synthesis of difluoromethylphosphonates
  • Mg-promoted selective C-F bond cleavage : a general and efficient access to difluoroenol silyl ethers and their derivatives
  • Reactions of ethyl bromodifluoroacetate in the presence of copper powder
  • Fluorine-based crystal engineering
  • Haloperfluorocarbons : versatile tectons in halogen bonding based crystal engineering
  • Fluoro-beta-lactams as useful building blocks for the synthesis of fluorinated amino acids, dipeptides, and toxoids
  • Synthesis of fluorinated prolines and pyroglutamic acids
  • Synthesis and properties of new fluorinated peptidomimetics
  • Fluorinated beta-enamino esters as versatile synthetic intermediates : synthesis of fluorinated beta-amino acids and uracils
  • Using the potential of fluorine for peptide and protein modification.