http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Cycloaddition reactions in organic synthesis
Cycloaddition reactions are among the most important tools for synthesis in organic chemistry, since these reactions are vital to the modern synthesis of natural products and biologically active substances. Metal catalysis plays an increasingly important role in these reactions, often allowing several stereocenters to be selectively created and integrated in the target molecules. Kobayashi and Jorgensen's handbook provides numerous examples of metal-catalyzed reactions, including [2+1], [3+2] and [4+2] cycloadditions. Important reactions such as carbo- and hetero-Diels-Alder, carbocyclic, cyclopropanation and 1,3-dipolar cycloaddition reactions are discussed. A large number of experimental procedures gives a concrete idea of the use of metal-catalyzed cycloaddition reactions in modern synthesis. The book is aimed at chemists in industry or academia, who want to effectively use cycloadditions in their work.
Catalytic Asymmetric Diels-Alder Reactions / Yujiro Hayashi -- The Chiral Lewis Acid-catalyzed Diels-Alder Reaction -- The Asymmetric Diels-Alder Reaction of [alpha, beta]-Unsaturated Aldehydes as Dienophiles -- Aluminum -- Boron -- Titanium -- Iron -- Ruthenium -- Chromium -- Copper -- The Asymmetric Diels-Alder Reaction of [alpha, beta]-Unsaturated Esters as Dienophiles -- The Asymmetric Diels-Alder Reaction of 3-Alkenoyl-1,3-oxazolidin-2-ones as Dienophiles -- Aluminum -- Magnesium -- Copper -- Iron -- Nickel -- Titanium -- Zirconium -- Lanthanides -- The Asymmetric Diels-Alder Reaction of Other Dienophiles -- The Asymmetric Catalytic Diels-Alder Reaction Catalyzed by Base -- Recent Advances in Palladium-catalyzed Cycloadditions Involving Trimethylenemethane and its Analogs / Dominic M.T. Chan -- Mechanism for [3+2] Carbocyclic Cycloaddition -- Dynamic Behavior of TMM-Pd Complexes -- Application in Organic Synthesis -- [3+2] Cycloaddition: The Parent TMM -- Recent Applications in Natural and Unnatural Product Synthesis -- Novel Substrates for TMM Cycloaddition -- [3+2] Cycloaddition: Substituted TMM -- Cyclopropyl-substituted TMM -- Phenylthio-TMM -- [3+2] Cycloaddition: Intramolecular Versions -- Introduction and Substrate Synthesis -- Synthesis of Bicyclo[3.3.0]octyl Systems -- Synthesis of Bicyclo[4.3.0]nonyl Systems -- Synthesis of Bicyclo[5.3.0]decyl Systems -- Carboxylative Cycloadditions -- Carbonyl Cycloadditions -- Addition to Aldehydes -- Addition to Ketones -- Imine Cycloadditions -- [4+3] Cycloadditions.
edited by Shū Kobayashi and Karl Anker Jørgensen.
Includes bibliographical references and index.