Polypropylene handbook : morphology, blends and composites /

This book extensively reviews Polypropylene (PP), the second most widely produced thermoplastic material, having been produced for over 60 years. Its synthesis, processing and application are still accompanied by vigorous R and D developments because the properties of PP are at the borderline betwee...

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Bibliographic Details
Corporate Author: Knovel (Firm)
Other Authors: Karger-Kocsis, J. (József) (Editor), Bárány, Tamás (Editor)
Format: eBook
Language:English
Published: Cham, Switzerland : Springer, [2019]
Subjects:
Online Access:Connect to the full text of this electronic book

MARC

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245 0 0 |a Polypropylene handbook :  |b morphology, blends and composites /  |c József Karger-Kocsis, Tamás Bárány, editors. 
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505 0 |a Intro; Preface; In Memoriam József Karger-Kocsis; Contents; Contributors; 1 Tacticity, Regio and Stereoregularity; Abstract; 1.1 Introduction; 1.2 Definition and Nomenclature; 1.3 13C NMR of Polypropylenes; 1.4 Steric Defects in PP and Models for Stereocontrol; 1.5 Regio Defects in PP and Models for Regiocontrol; 1.6 Heterogeneous Versus Homogeneous ZN Catalysts; 1.7 Further Techniques for Polypropylene Tacticity Analysis; 1.8 Polypropylene Microstructures Obtained by Non-metallocene Ligands and by Late Transition Metal; 1.9 Concluding Remarks; Acknowledgements; References 
505 8 |a 2.4.6 The "New Mesomorphic" Form in Copolymers of Isotactic Polypropylene with Branched Comonomers2.5 Crystal Polymorphism of Syndiotactic Polypropylene; 2.5.1 Crystal Structure of Form I; 2.5.2 Structural Disorder in Form I; 2.5.3 Crystal Structure of Form II; 2.5.4 Structural Disorder in Form II; 2.5.5 Crystal Structure of Form III; 2.5.6 Crystal Structure of Form IV; 2.5.7 The Trans-planar Mesomorphic Form of sPP; 2.5.8 Helical Mesophase in Syndiotactic Copolymers of Propylene; 2.6 Conclusions; References; 3 Polypropylene Nucleation; Abstract; 3.1 Introduction; 3.2 Crystallization Process 
505 8 |a 3.4.1 Prediction of Tensile Modulus from Crystalline Parameters3.4.2 Obtaining Balanced Properties by Efficient Nucleation; 3.4.3 Improvement of Optical Properties by Efficient Nucleation; 3.5 Summary; Acknowledgements; References; 4 Crystallization of Polypropylene; Abstract; 4.1 Introduction (Overview); 4.2 Methods of Crystallization Studies; 4.3 Polymorphism; 4.4 Nucleation and Crystal Growth in General; 4.5 Structure of Single Crystal; 4.6 Structure of Spherulite; 4.7 Shish-Kebabs; 4.8 Nucleation Theories; 4.9 Formation of Spherulitic Structure 
500 |a 4.10 Crystallization of PP in Specific Conditions 
588 0 |a Online resource; title from digital title page (viewed on April 11, 2019). 
520 |a This book extensively reviews Polypropylene (PP), the second most widely produced thermoplastic material, having been produced for over 60 years. Its synthesis, processing and application are still accompanied by vigorous R and D developments because the properties of PP are at the borderline between those of commodity and engineering thermoplastics. Readers are introduced to various tacticities and polymorphs of PP, and their effects on structural properties. Further, the book addresses the control of optical properties using nucleants, provides strategies for overcoming the limited cold/impact resistance of PP, examines in detail the effects of recycling, and presents guidelines for the property modification of PPs through foaming, filling and reinforcing with respect to target applications. Special attention is paid to descriptions and models of properties as a function of morphological variables. Last but not least, the book suggests potential practical applications of PP-based systems, especially in the packaging, appliances, building/construction, textile and automotive sectors. Each chapter, written by internationally respected scientists, reflects the current state-of-art in the respective field and offers a vital source of information for students, researchers and engineers interested in the morphology, properties, testing and modeling of PP and PP-based systems. The content is indispensable to the appropriate application of PPs and related composites. 
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880 8 |6 505-00/(S  |a 2 Solid State Polymorphism of Isotactic and Syndiotactic PolypropyleneAbstract; 2.1 Introduction; 2.2 Chain Conformation of Isotactic and Syndiotactic Polypropylene in the Crystalline State; 2.2.1 Isotactic Polypropylene; 2.2.2 Syndiotactic Polypropylene; 2.3 Crystal Polymorphism of Isotactic Polypropylene; 2.4 The Crystal Structure of α Form; 2.4.1 The Crystal Structure of γ Form; 2.4.2 Structural Disorder of γ Form of iPP; 2.4.3 Crystal Structure of β Form; 2.4.4 Mesomorphic Form of iPP; 2.4.5 Crystal Structure of the Trigonal Form of iPP 
880 8 |6 505-00/(S  |a 3.3 Nucleation, the Targeted Manipulation of Crystalline Structure3.3.1 Basic Characterization of Nucleating Agents; 3.3.2 "Conventional" Heterogeneous Nucleating Agents; 3.3.3 Soluble Nucleating Agents, Organogelators and Clarifiers for α-iPP; 3.3.4 Crystallization of iPP in the Presence of Soluble Organogelators; 3.3.5 Estimation of Solubility Limit of Organogelators; 3.3.6 Supermolecular Structure Formed in the Presence of Organogelators; 3.3.7 Nucleating Agent Based on Trisamides of Trimesic Acid; 3.3.8 Soluble Nucleating Agents for β-iPP; 3.4 Structure-Property Case Studies 
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