http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
1 online resource (xxii, 349 pages) : illustrations (some color)
Do you need to know what's new in organosilicon chemistry? This book provides in-depth coverage of the latest developments in this interdisciplinary and fast-evolving field:- selectivity and reactivity of organosilicon compounds - new synthetic applications- structure and bonding- applications in materials and polymer scienceWritten by leading experts, this book is a well-referenced and critical overview of modern silicon chemistry.'I recommend this book to the student and the practitioner in this new, very different, and very exciting field'. Eugene G.
Organosilicon Chemistry From Molecules to Materials; Contents; Tetravalent Organosilicon Compounds: Chemistry and Structure; Introduction; Structures of Small Silicon Containing Compounds -- Why and How?; Sterically Overcrowded Organosilicon Compounds and their Properties; Synthesis of Functionally Substituted Oligosilanes Based on Silyltriflate Derivatives; Electroreductive Formation of Di- and Polysilanes; Linear Tetrasilanes with Internal Substituents: Oligosilanes with Optical Activity; A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes
29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H6-n and XnSi3H8-n (X = Br, I)Calculation of the 29 Si NMR Chemical Shifts in Molecules with SIN, SiCl, and SiSi Bonds; Reactivity of Very Electron-Rich Organosilyl Amines; Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes; Fluorofunctional Silylamines and -Hydrazines Precursors for (Si-N) Ring Systems; New Approaches to (Fluoromethyl)silanes; Homo- and heterocyclic Si-O-Systems . Rings and Cages
Silaheterocycles from Intramolecular Reactions of Silicon-functionalized Diazoacetic EstersSynthesis and Reaction Behavior of Organoalkoxysilylphenols; N-Silylation: New Possibilities for Long-known Amines; On the Acid-catalyzed Reaction of Siloxanes with Alcohols; On the Reactivity of Chlorosiloxanes; Chlorosilanols -- more stable than you think -- shown with 29Si NMR; Diorganosilyl-bis(O-alkylphosphonates); Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity; Introduction; Basic Principles of the Theory of Bonding in Silicon Compounds
Expectations from an Unusual Compound: The Chemistry of DecamethylsilicoceneCp*2Si(CO) and CP*2Si(N2): Complexes of Decamethylsilicocene; Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry; Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?; Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines; Reactions of Silaethenes in the Gas Phase and in Solution; The Reaction of Vinylsilanes with Lithium Metal; Small Silicon Ring Compounds: Formation and Reactions
Matrix Photolysis of Simple AzidosilanesLow-coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes; Unusual Coordination in Phosphorus-Silicon Compounds; Unsaturated Silicon Compounds: Matrix IR Investigations and Quantum Chemical Calculations; Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry; Introduction; Reactivity of Penta- and Hexacoordinated Silicon Species; Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon Centers
Electronic reproduction. [Place of publication not identified] : HathiTrust Digital Library, 2010. MiAaHDL
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL
digitized 2010 HathiTrust Digital Library committed to preserve pda MiAaHDL
Includes bibliographical references and indexes.