Organometallics in synthesis : fourth manual /
"This manual is essential reading for all synthetic organic chemists, providing the most useful reference on organometallics for practicing researchers. The featured elements in this manual are copper, rhodium, nickel, and gold. Background information about the organometallic class, the various...
| Other Authors: | |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Hoboken, New Jersey :
John Wiley & Sons,
[2013]
|
| Edition: | Fourth edition. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Half Title page; Title page; Copyright page; Contributors; Preface; Foreword; Chapter One: Organocopper Chemistry; 1. Introduction; 2. Click Chemistry: Just Add Copper; 3. Cu-Catalyzed Aminations and Amidations; 4. Cu-Catalyzed O- and S-Arylation Reactions; 5. Asymmetric Cu-Catalyzed Borylations; 6. Oxidations of Organocopper Complexes; 7. 1,2-Additions to Imines; 8. Cu-Catalyzed Asymmetric C-C Bond Formation; 9. Copper Hydride Chemistry; 10. Miscellaneous Reactions Catalyzed by Cu(I); 11. Conclusions and Outlook; 12. Acknowledgments; 13. References; Chapter Two: Organorhodium Chemistry.
- List of Abbreviations1. Introduction; 2. Rhodium Complexes; 3. Hydroformylation; 4. Silylformylation; 5. Cyclopropanation; 6. Cyclohydrocarbonlyation; 7. Asymmetric Hydrogenation; 8. Hydroacylation of Alkenes and Alkynes; 9. C-H Activation by Metal-Carbenoid and Nitrenoid Induced C-H Insertion; 10. Rh-Catalyzed C-H Activation; 11. Rh-Catalyzed 1,4-Conjugate Addition of Boronic Acids; 12. Rh-Catalyzed Hydroboration; 13. Rh-Catalyzed Reductive Coupling; 14. Miscellaneous Reactions Catalyzed by Rh-Complexes; 15. Rhodium-Catalyzed Cycloadditions and Cyclizations.
- 16. Rh(I)-Catalyzed Cycloisomerization and Alder-Ene Reactions17. Concluding Remarks; 18. Acknowledgments; 19. References; Chapter Three: Organonickel Chemistry; 1. Introduction; 2. Cross-Couplings and Homocouplings; 3. Cycloaddition Processes; 4. Reductive Coupling Processes; 5. Carbonyl Additions and Conjugate Additions; 6. 1,2- and 1,4-Additions to Alkenes, Alkynes, and Dienes; 7. Conclusions and Outlook; 8. Acknowledgments; 9. References; Chapter Four: Organogold Chemistry; 1. Introduction; 2. C-H Bond Formation; 3. C-C Bond Formation; 4. C-N Bond Formation; 5. C-O Bond Formation.
- 6. C-S and C-Halogen Bond Formation7. Conclusions and Outlook; 8. Acknowledgments; 9. References; Index.