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Rare earth coordination chemistry : fundamentals and applications /

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Bibliographic Details
Other Authors: Huang, Chun-Hui, 1933-
Format: eBook
Language:English
Published: Singapore ; Hoboken, NJ : John Wiley & Sons, ©2010.
Subjects:
Rare earths.
Rare earth metal compounds.
Coordination compounds.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • Note continued: 3.2. Rare Earth Complexes with Carboxylic Acids
  • 3.2.1. Preparation of Rare Earth Complexes with Carboxylic Acids
  • 3.2.2. Structural Chemistry of Rare Earth Complexes with Carboxylic Acids
  • 3.2.3. Solution Chemistry of Rare Earth Complexes with Carboxylic Acids
  • 3.3. Rare Earth Complexes with Polyaminopolycarboxylic Acids
  • 3.3.1. Preparation of Rare Earth Complexes with Polyaminopolycarboxylic Acids
  • 3.3.2. Structural Chemistry of Rare Earth Complexes with Polyaminopolycarboxylic Acids
  • 3.3.3. Solution Chemistry of Rare Earth Complexes with Polyaminopolycarboxylic Acids
  • 3.4. Rare Earth Complexes with Amino Acids
  • 3.4.1. Preparation of Rare Earth Complexes with Amino Acids
  • 3.4.2. Structural Chemistry of Rare Earth Complexes with Amino Acids
  • 3.4.3. Solution Chemistry of Rare Earth Complexes with Amino Acids
  • 3.5. Summary and Outlook
  • References
  • 4. N-Based Rare Earth Complexes / Jianzhuang Jiang
  • 4.1. Introduction
  • 4.2. Rare Earth Complexes with Amide Type Ligands
  • 4.2.1. Rare Earth Complexes with Aliphatic Amide Type Ligands
  • 4.2.2. Rare Earth Complexes with Silyl Amide Type Ligands
  • 4.3. Rare Earth Complexes with N-Heterocyclic Type Ligands
  • 4.3.1. Rare Earth Complexes with Pyridine Type Ligands
  • 4.3.2. Rare Earth Complexes with Imidazole Type Ligands
  • 4.3.3. Rare Earth Complexes with Porphyrin Type Ligands
  • 4.3.4. Rare Earth Complexes with Phthalocyanine Type Ligands
  • 4.4. Rare Earth Complexes with Schiff Base Type Ligands
  • 4.4.1. Rare Earth Complexes with Imine Type Ligands
  • 4.4.2. Rare Earth Complexes with H2Salen (30) Type Ligands
  • 4.5. Outlook
  • List of Abbreviations
  • Acknowledgments
  • References
  • 5. Rare Earth Polyoxometalate Complexes / Enbo Wang
  • 5.1. Synthesis
  • 5.2. Types and Structure Features
  • 5.2.1. RE-POM Clusters
  • Note continued: 5.2.2. Extending Structural RE-POMs Complexes
  • 5.2.3. RE-Organo Cation POM Supermolecule Complexes
  • 5.3. Applications
  • 5.3.1. Luminescence
  • 5.3.2. Magnetism
  • 5.3.3. Catalysis
  • 5.3.4. Medicine
  • 5.4. Outlook
  • References
  • 6. Coordination Chemistry of Rare Earth Alkoxides, Aryloxides, and Hydroxides / Ruiyao Wang
  • 6.1. Introduction
  • 6.2. Lanthanide Alkoxides, Aryloxides, and Macrocyclic Polyaryloxides
  • 6.2.1. Preparative Methods
  • 6.2.2. Structural Chemistry of Lanthanide Alkoxide Complexes
  • 6.2.3. Applications of Lanthanide Alkoxides
  • 6.3. Lanthanide Hydroxide Complexes
  • 6.3.1. Rational Synthetic Methodologies for Lanthanide Hydroxide Complexes
  • 6.3.2. Coordination Modes of Hydroxo Ligands and Key Lanthanide-Hydroxo Motifs
  • 6.3.3. Properties and Possible Applications
  • 6.4. Summary and Outlook
  • Acknowledgments
  • ^ References
  • 7. Rare Earth Metals Trapped Inside Fullerenes
  • Endohedral Metallofullerenes (EMFs) / Shigeru Nagase
  • 7.1. Introduction
  • 7.1.1. History of Discovery
  • 7.1.2. What Can Be Encapsulated Inside Fullerenes?
  • 7.2. Preparation and Purification of EMFs
  • 7.2.1. Production Methods
  • 7.2.2. Extraction of EMFs from Raw Soot
  • 7.2.3. Separation and Purification of EMFs
  • 7.3. General Structures and Properties of EMFs Encapsulating Rare Earth Metals
  • 7.3.1. Geometrical Structures
  • 7.3.2. Electronic Structures of EMFs: Intramolecular Charge Transfer
  • 7.4. Chemistry of EMFs
  • 7.4.1. Chemical Reactions of EMFs: An Overview
  • 7.4.2. Positional Control of Encapsulated Metals by Exohedral Modifications
  • 7.4.3. Chemical Properties of Cage Carbons Dictated by the Encapsulated Metals
  • 7.4.4. Chemical Behaviors of EMFs Bearing Fused Pentagons
  • 7.5. Applications of EMFs and Their Derivatives
  • 7.5.1. Applications in Biology and Medicine
  • Note continued: 10. Gadolinium Complexes as MRI Contrast Agents for Diagnosis / Kannie Waiyan Chan
  • 10.1. Clinical Magnetic Resonance Imaging (MRI) Contrast Agents
  • 10.1.1. Development of Clinical Contrast Agents
  • 10.1.2. Clinical Contrast Agents
  • 10.2. Chemistry of Gadolinium Based Contrast Agents
  • 10.2.1. Relaxivity
  • 10.2.2. Biomolecular Interactions
  • 10.2.3. Toxicity and Safety Issues
  • 10.3. Contrast Enhanced MRI for Disease Diagnosis
  • 10.3.1. Magnetic Resonance Angiography (MRA)
  • 10.3.2. Liver Disease
  • 10.3.3. Oncology
  • 10.4. Outlook
  • References
  • 11. Electroluminescence Based on Lanthanide Complexes / Chunhui Huang
  • 11.1. Introduction
  • 11.1.1. Operating Principles in OLEDs
  • 11.1.2. History of OLEDs
  • 11.1.3. Potential Advantages of Lanthanide Complexes Used in OLEDs
  • 11.2. Lanthanide Complexes Used in OLEDs
  • 11.2.1. Europium Complexes
  • 11.2.2. Terbium Complexes
  • 11.2.3. Other Lanthanide Complexes
  • 11.3. Outlook
  • Acknowledgments
  • References
  • 12. Near-Infrared (NIR) Luminescence from Lanthanide(III) Complexes / Haibing Xu
  • 12.1. Introduction
  • 12.2. Organic Antenna Chromophores as Sensitizers
  • 12.2.1. Acyclic Ligands as Antenna Chromophores
  • 12.2.2. Macrocyclic Ligands as Antenna Chromophores
  • 12.3. Metal-Organic Chromophores as Sensitizers
  • 12.3.1. d-Block Chromophores
  • 12.3.2. f-Block Chromophores
  • 12.4. Outlook
  • List of Abbreviations
  • Acknowledgments
  • References
  • 13. Luminescent Rare Earth Complexes as Chemosensors and Bioimaging Probes / He Hu
  • 13.1. Introduction
  • 13.2. Rare Earth Complexes as Luminescent Chemosensors
  • 13.2.1. Basic Concept
  • 13.2.2. Rare Earth Complexes as Luminescent pH Chemosensors
  • 13.2.3. Rare Earth Complexes as Luminescent Chemosensors for Cations
  • Note continued: 13.2.4. Rare Earth Complexes as Luminescent Chemosensors for Anions
  • 13.2.5. Rare Earth Complexes as Luminescent Chemosensors for Small Molecules
  • 13.3. Bioimaging Based on Luminescent Rare Earth Complexes
  • 13.3.1. Time-Resolved Luminescence Imaging
  • 13.3.2. Types of Luminescent Rare Earth Complexes for Bioimaging
  • 13.3.3. Luminescent Rare Earth Complexes with Privileged Cyclen Core Structures as Bioimaging Probes
  • 13.3.4. Luminescent Rare Earth Complexes with Bis(benzimidazole) pyridine Tridentate Units as Bioimaging Probes
  • 13.3.5. Hybrid Rare Earth Complexes as Luminescent Probes in Bioimaging
  • 13.4. Rare Earth Luminescent Chemosensors as Bioimaging Probes
  • 13.4.1. Rare Earth Luminescent Chemosensors as Bioimaging Probes of Zn2+
  • 13.4.2. Rare Earth Luminescent Chemosensors as Bioimaging Probes of 1O2
  • 13.5. Rare Earth Complexes as Multiphoton Luminescence Probes for Bioimaging
  • 13.6. Rare Earth Materials with Upconversion Luminescence for Bioimaging
  • 13.6.1. General Concept of Upconversion Luminescence
  • 13.6.2. Rare Earth Complexes with Upconversion Luminescence
  • 13.6.3. Rare Earth Nanophosphors with Upconversion Luminescence
  • 13.6.4. Rare Earth Upconversion Luminescence Nanophosphors as Bioimaging Nanoprobes
  • 13.7. Outlook
  • References.