Manganese catalysis in organic synthesis /

Bibliographic Details
Other Authors:	Sortais, Jean-Baptiste (Editor)
Format:	eBook
Language:	English
Published:	Weinheim, Germany : Wiley, [2022]
Subjects:	Manganese catalysts. Organic compounds > Synthesis. Electronic books.
Online Access:	Connect to the full text of this electronic book

Table of Contents:

3.2.2 Synthesis of Esters and Functionalizations of Nitriles and Alkanes
3.2.3 Synthesis and Derivatization of Heterocycles
3.3 Hydrogen-Borrowing Reactions
3.3.1 Alkylation of Amines
3.3.2 Alkylation of Alcohols and Ketones
3.3.3 Alkylation of Amides and Esters
3.3.4 Alkylation of Nitriles and Sulfonamide
3.3.5 Upgrading of Ethanol into 1-Butanol
3.3.6 Alkylation of Hydrazine
3.3.7 Combining Acceptorless Dehydrogenative Coupling with Hydrogen-Borrowing
3.4 Conclusions and Perspectives
References
Chapter 4 Manganese-Catalyzed Hydrosilylation and Hydroboration Reactions
4.1 Introduction
4.2 Hydrosilylation
4.2.1 Hydrosilylation of Carbonyls and Carboxylates
4.2.2 Hydrosilylation of Amides
4.2.3 Hydrosilylation of Carbon Dioxide
4.2.4 Hydrosilylation of C C and C C Bonds
4.2.4.1 Olefin Hydrosilylation
4.2.4.2 Alkyne Hydrosilylation
4.3 Hydroboration
4.3.1 Hydroboration of C O Bonds
4.3.2 Hydroboration of Alkenes
4.3.3 Hydroboration of Alkynes
4.3.4 Hydroboration of Nitriles
4.4 Summary and Conclusions
References
Chapter 5 Manganese Complexes for Electro- and Photocatalytic Transformations
5.1 Introduction
5.2 Mn-Catalyzed Organic Oxidations
5.3 Mn-Catalyzed Reductions and Other Organic Transformations
5.4 Mn-Catalyzed CO2 Reduction
5.4.1 Electrocatalytic CO2 Reduction with Manganese-Based Catalysts
5.4.1.1 Pyridine-Based Complexes
5.4.1.2 Diimine-Based Complexes
5.4.1.3 N-Heterocyclic Carbene-Based Complexes
5.4.2 Photochemical CO2 Reduction
5.4.3 Heterogenization of Molecular Mn Catalysts for the CO2 Reduction Reaction
5.5 Conclusions
References
Chapter 6 Manganese-Catalyzed C H Oxygenation Reactions
6.1 Introduction
6.2 Selective Manganese-Catalyzed C-H Oxidation Reactions: Early Studies.
6.3 Manganese-Catalyzed Chemo- and Regioselective C-H Oxidations with Hydrogen Peroxide
6.4 Manganese-Catalyzed Enantioselective C-H Oxidations
6.5 Manganese-Catalyzed Oxidative Desymmetrizations
6.6 Mn-Catalyzed Oxidative Kinetic Resolution of sec-Alcohols
6.7 Mn-Catalyzed Oxidation of Aromatic Compounds
6.8 Summary and Conclusions
Acknowledgment
References
Chapter 7 Manganese-Catalyzed Organometallic C H Activation
7.1 Introduction
7.2 Stoichiometric Cyclometalation with Manganese Complexes
7.3 Manganese-Catalyzed C C Bond Formation via Directed C H Activation
7.3.1 Insertion of C C Bonds into Manganacycles
7.3.2 Insertion of C C Bonds into Manganacycles
7.3.3 Insertion of Allene into Manganacycles
7.3.4 Insertion of C X (X &amp
equals
O, N) Bond into Manganacycles
7.3.5 Miscellaneous Reactions Involving C-H Activation
7.4 Summary and Outlook
References
Chapter 8 Manganese-Catalyzed Cross-Coupling Processes
8.1 Introduction
8.2 C C Bond Formation via Mn-Catalyzed Cross-Coupling Reactions
8.2.1 Mn-Catalyzed Kumada Cross-Coupling Reactions
8.2.1.1 Aryl Halides with Grignard Reagents
8.2.1.2 Heteroaryl Halides with Grignard Reagents
8.2.1.3 Vinyl(Pseudo)Halides with Grignard Reagents
8.2.1.4 Conclusion on Mn-Catalyzed Kumada Cross-Coupling Reactions
8.2.2 Mn-Catalyzed Stille Cross-Coupling Reactions
8.2.3 Mn-Catalyzed Coupling Reactions of Organometallic Reagents Under Oxidative Conditions
8.2.3.1 Homocoupling Reactions
8.2.3.2 Heterocoupling Reactions
8.2.4 Mechanistic Insights
8.2.5 Conclusion on Mn-Catalyzed Coupling Reactions of Organometallic Reagents Under Oxidative Conditions
8.3 Mn-Catalyzed Carbon-Heteroatom Bond Formation
8.3.1 C N Bond Formation
8.3.2 C O Bond Formation
8.3.3 C S Bond Formation
8.3.4 C B Bond Formation.
Organometallic Manganese Compounds in Organic Synthesis / Alina A Grineva, Noël Lugan, Dmitry A Valyaev
Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions / Jean-Baptiste Sortais, Ruqaya Buhaibeh, Yves Canac
Manganese-Catalyzed Hydrogen-Borrowing and Dehydrogenative Coupling Reactions / Stefan Weber, Karl Kirchner
Manganese-Catalyzed Hydrosilylation and Hydroboration Reactions / Thao T Nguyen, Ryan J Trovitch
Manganese Complexes for Electro- and Photocatalytic Transformations / Sergio Fernandez, Geyla C Dubed Bandomo, Julio Lloret-Fillol
Manganese-Catalyzed C#xF8FF;H Oxygenation Reactions / Konstantin P Bryliakov
Manganese-Catalyzed Organometallic C #xF8FF; H Activation / Yunhui Yang, Congyang Wang
Manganese-Catalyzed Cross-Coupling Processes / Xiaoping Liu, Florian Jaroschik, Marc Taillefer
Manganese( III) Acetate-Mediated Cyclizations / Barry B Snider
Manganese-Catalyzed Dihydroxylation and Epoxidation of Olefins / Niek NHM Eisink,, Wesley R Browne.