Molecular magnetic materials : concepts and applications /
| Other Authors: | , |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Weinheim, Germany :
Wiley-VCH,
[2017]
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| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Cover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Magnetism; 1.1 Origin of Magnetism; 1.2 Macroscopic Approach; 1.3 Units in Magnetism; 1.4 Ground State of an Ion and Hund's Rules; 1.5 An Atom in a Magnetic Field; 1.6 Mechanisms of Magnetic Interactions; 1.6.1 Dipolar Interactions; 1.6.2 Direct Exchange; 1.6.3 Indirect Exchange
- Superexchange; 1.6.4 Indirect Exchange
- Double Exchange; 1.6.5 Indirect Exchange
- Antisymmetric Exchange; 1.6.6 Itinerant Exchange
- RKKY Interaction; 1.6.7 Magnetism of Itinerant Electrons; 1.7 Collective Magnetic State
- 1.7.1 Models of Interaction and Dimension of the Lattice1.7.2 Ferromagnets; 1.7.3 Antiferromagnets; 1.7.4 Ferrimagnets; 1.7.5 Spin Glasses; 1.7.6 Superparamagnets; 1.8 Applications and Research; References; Chapter 2 Molecular Magnetism; 2.1 Introduction; 2.2 Birth of the Topic: Exchange-Coupled Clusters; 2.3 Evolution of the Topic: Molecule-Based Magnets; 2.4 Burgeoning Topics: Single-Molecule Magnets; 2.5 Single-Chain Magnets; 2.6 Spin Crossover Complexes; 2.7 Charge Transfer-Induced Spin Transitions; 2.8 Multifunctional Materials; 2.9 Future Perspectives; References
- Chapter 3 High-Spin Molecules3.1 Introduction; 3.2 Strategies for High-Spin Molecules; 3.2.1 Magnetic Exchange Strategy for High-Spin Molecules; 3.2.1.1 Strict Orthogonality of the Magnetic Orbitals for Ferromagnetic Interaction; 3.2.1.2 Accidental Orthogonality of the Magnetic Orbitals for Ferromagnetic Interaction; 3.2.1.3 Spin Polarization Mechanism for Ferromagnetic Interaction; 3.2.2 Synthetic Strategy for High-Spin Molecules; 3.2.2.1 Bridging Ligands for High-Spin Molecules; 3.2.2.2 The Effect of the Blocking Ligands; 3.3 High-Spin Molecules based on d-Metal Ions
- 3.3.1 Homo-Metallic High-Spin Molecules based on d-Metal Ions3.3.2 Hetero-Metallic High-Spin Molecules Based on d-Metal Ions; 3.4 High-Spin Molecules Based on f-Metal Ions; 3.5 High-Spin Molecules Based on d-f Metal Ions; 3.6 Conclusions and Perspectives; References; Chapter 4 Single Molecule Magnets; 4.1 Introduction; 4.1.1 Molecular Magnets; 4.1.2 Rough Outline of the Single-Molecule Magnets (SMMs); 4.2 Measurement Techniques; 4.2.1 Direct Current (dc) Measurements; 4.2.2 Remnant Magnetization; 4.2.3 Alternating Current (ac) Measurements; 4.2.4 Electron Spin Resonance (ESR)
- 4.2.5 Nuclear Magnetic Resonance (NMR)4.2.6 Other Methods; 4.3 Rational Design of SMMs; 4.4 Family of SMMs; 4.4.1 Polynuclear d Metal Complexes; 4.4.2 Mononuclear d Metal complexes (Single-Ion Magnets (SIMs)); 4.4.3 Mononuclear f Metal Complexes (SIMs); 4.4.4 Polynuclear f Metal Complexes; 4.4.5 Mixed Metal nd-4f Complexes; 4.5 Conclusions and Perspectives; References; Chapter 5 Magnetic Molecules as Spin Qubits; 5.1 Introduction; 5.1.1 QIP Paradigms with Magnetic Molecules; 5.2 Molecular Qubits; 5.3 Schemes for Two-Qubit Gates; 5.3.1 Permanently Coupled Qubits