rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Nitroxides
    sub title: synthesis, properties and applications
  name:
    name part: Ouari, Olivier
    role:
      role term: editor.
  name:
    name part: Gigmes, Didier
    role:
      role term: editor.
  name:
    name part: Knovel (Firm)
  type of resource: text
  genre: Electronic books.
  origin info:
    place:
      place term: enk
    date issued: 2021
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: remote
    extent: 1 online resource
  abstract: Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.
  table of contents: Intro -- Title -- Copyright -- Contents -- Chapter 1 A Brief History and Outlook of Nitroxides -- 1.1 Brief History -- 1.2 Nitroxide Reactivity -- 1.3 Conclusion -- References -- Chapter 2 General Approaches to Synthesis of Nitroxides -- 2.1 What are Nitroxides. Limits of Nitroxide Stability -- 2.2 Nitroxide Group Formation -- 2.2.1 From Amines -- 2.2.2 From Hydroxylamines -- 2.2.3 From Alkoxyamines -- 2.2.4 From Nitrones -- 2.3 Some Contemporary Trends in Nitroxide Chemistry
  table of contents: 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems -- 2.3.2 Electron Spin Relaxation -- 2.4 The Most Important Nitroxide Classes -- 2.4.1 Piperidine Nitroxides -- 2.4.2 Pyrroline Nitroxides -- 2.4.3 Pyrrolidine Nitroxides -- 2.4.4 Isoindoline Nitroxides -- 2.4.5 3-Imidazoline and Imidazolidine Nitroxides -- 2.5 Cyclic Conjugated Nitroxides -- 2.5.1 4,5-Dihydroimidazole-1-oxyls -- 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs) -- 2.5.3 Heterocyclic Vinyl Nitroxides -- 2.6 Conclusion -- Acknowledgements
  table of contents: 3.6 Nitroxide-mediated C-C Bond Formation Reactions -- 3.7 Miscellaneous Reactions Mediated by Nitroxides -- 3.8 Conclusion -- References -- Chapter 4 Spin Probes and Imaging Using Nitroxides -- 4.1 Introduction -- 4.2 NR Oxymetric Probes and EPR Oximetry -- 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen -- 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes -- 4.3 NR pH Probes -- 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH -- 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes -- 4.4 NRs as Thiol-sensitive Probes
  table of contents: 4.4.1 Basics of GSH Detection Using Nitroxide Probes -- 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione -- 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions -- 4.6 Conclusion -- Acknowledgements -- References -- Chapter 5 Nitroxides in Battery-related Applications -- 5.1 Context -- 5.2 Organic Batteries Based on Nitroxide Radicals -- 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties -- 5.4 Nanostructures in Nitroxide Polymer Electrodes -- 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes
  note: edited by Olivier Ouari, Didier Gigmes.
  subject:
    topic: Nitroxides
  subject:
    topic: Radicaux aminoxyles
  subject:
    topic: Nitroxides
  classification: QD305.N8
  classification: 547.041
  related item:
    title info:
      title: Nitroxides
    origin info:
      publisher: Cambridge : Royal Society of Chemistry, 2021
    identifier: (OCoLC)1242738095
  identifier: 9781788019651
  identifier: 1788019652
  identifier: 9781788019668
  identifier: 1788019660
  identifier: 9781788017527
  identifier: 1788017528
  identifier: 3-178-9781788019668 Ingram Content Group
  identifier: http://proxy.library.tamu.edu/login
  record info:
    record content source: UKRSC
    record creation date: 210603
    record change date: 20230110224553.5
    record identifier: in00004640451
    language of cataloging:
      language term: eng