rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Visible light photocatalysis in organic chemistry
  name:
    name part: Stephenson, Corey R. J.
    role:
      role term: editor.
  name:
    name part: Yoon, Tehshik Peter
    name part: 1975-
    role:
      role term: editor.
  name:
    name part: MacMillan, David W. C.
    role:
      role term: editor.
  name:
    name part: Knovel (Firm)
  type of resource: text
  genre: bibliography
  genre: Electronic books.
  origin info:
    place:
      place term: gw
    date issued: 2018
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: remote
    extent: 1 online resource (x, 444 pages) : illustrations (some color)
  abstract: "Filling the need for a ready reference that reflects the vast developments in this field, this book presents everything from fundamentals, applications, various reaction types, and technical applications. Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photo-induced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts. A valuable resource to the synthetic organic community, polymer and medicinal chemists, as well as industry professionals."--Provided by publisher
  table of contents: Cover; Title Page; Copyright; Contents; Chapter 1 An Overview of the Physical and Photophysical Properties of [Ru(bpy)3]2+; 1.1 Introduction; 1.2 [Ru(bpy)3]2+: Optical and Electrochemical Properties; 1.2.1 Optical Properties; 1.2.2 Electrochemical Properties; 1.3 Excited State Kinetics; 1.3.1 Steady-State Emission; 1.3.2 Time-Resolved Emission; 1.4 Excited-State Reactivity of [Ru(bpy)3]2+; 1.5 Energy Transfer: FÃœrster and Dexter Mechanisms; 1.6 Electron Transfer; 1.7 Probing the Mechanism, Stage I: Sternâ#x80;#x93;Volmer Quenching Studies.
  table of contents: 1.8 Probing the Mechanism, Stage II: Electron Versus Energy Transfer1.9 Designing Photocatalysts: [Ru(bpy)3]2+ as a Starting Point; 1.10 Conclusion; References; Chapter 2 Visible-Light-Mediated Free Radical Synthesis; 2.1 Introduction; 2.2 Basics of the Photocatalytic Cycle; 2.3 Generation of Radicals; 2.3.1 Formation of C-Centered Radicals; 2.3.1.1 Dehalogenation (I, Br, Cl); 2.3.1.2 Other C-Heteroatom Cleavage; 2.3.1.3 C-C Bond Cleavage; 2.3.2 Formation of N-Centered Radicals; 2.4 C-X Bond Formation; 2.4.1 C-O Bond; 2.4.2 C-N Bond; 2.4.3 C-S and C-Se Bonds; 2.4.4 C-Br Bond; 2.4.5 C-F Bond.
  table of contents: 2.4.6 C-B Bond2.5 C-C Bond Formation; 2.5.1 Formation and Reactivity of Aryl Radicals; 2.5.2 Formation and Reactivity of Trifluoromethyl and Related Radicals; 2.5.2.1 Photocatalyzed Reduction of Perfluorohalogen Derivatives; 2.5.2.2 Photocatalyzed Reduction of Perfluoroalkyl-Substituted Onium Salts; 2.5.2.3 Photocatalyzed Formation of Perfluoroalkyl Radicals from Sulfonyl and Sulfinyl Derivatives; 2.5.3 Formation and Reactivity of Alkyl and Related Radicals; 2.5.3.1 C-C Bond Formation Through Photocatalyzed Reduction of Halogen Derivatives and Analogs.
  table of contents: 2.5.3.2 C-C Bond Formation Through Photocatalyzed Oxidation of Electron-Rich Functional Group2.5.3.3 C-C Bond Formation Through Photocatalyzed Oxidation of Amino Group; 2.6 Radical Cascade Applications; 2.6.1 Intramolecular Polycyclization Processes; 2.6.2 Sequential Inter- and Intramolecular Processes; 2.6.3 Sequential Radical and Polar Processes; References; Chapter 3 Atom Transfer Radical Addition using Photoredox Catalysis; 3.1 Introduction; 3.2 Transition Metal-Catalyzed ATRA; 3.2.1 Ruthenium- and Iridium-Based ATRA; 3.2.1.1 Mechanistic Investigations.
  table of contents: 3.2.1.2 Ruthenium- and Iridium-Based ATRA3.2.2 Copper-Mediated ATRA; 3.2.2.1 Trifluoromethylation; 3.3 Other Photocatalysts for ATRA Transformations; 3.3.1 p-Anisaldehyde; 3.4 Semiconductor; 3.5 Atom Transfer Radical Cyclization (ATRC); 3.6 Atom Transfer Radical Polymerization (ATRP); 3.7 Conclusion; References; Chapter 4 Visible Light Mediated -Amino C-H Functionalization Reactions; 4.1 Introduction; 4.2 Visible Light Mediated -Amino C-H Functionalization Via Iminium Ions; 4.2.1 Aza-Henry Reaction; 4.2.2 Mannich Reaction; 4.2.3 Strecker Reaction; 4.2.4 Friedelâ#x80;#x93;Crafts Reaction.
  note: edited by Corey R.J. Stephenson, Tehshik P. Yoon, and David W.C. MacMillan.
  note: Includes bibliographical references and index.
  subject:
    topic: Photocatalysis
  subject:
    topic: Chemistry, Organic
  subject:
    topic: Photocatalyse
  subject:
    topic: Chimie organique
  subject:
    topic: organic chemistry
  subject:
    topic: SCIENCE
    topic: Chemistry
    topic: Physical & Theoretical
  subject:
    topic: Chemistry, Organic
  subject:
    topic: Photocatalysis
  classification: QD716.P45
  classification: QD716.P45 V57 2018e
  classification: 541/.395
  related item:
    title info:
      title: Visible light photocatalysis in organic chemistry
    origin info:
      publisher: Weinheim, Germany : Wiley-VCH Verlag GmbH & Co., [2018]
    identifier: (OCoLC)1041521322
  related item:
    title info:
      title: Visible light photocatalysis in organic chemistry
    origin info:
      publisher: [Place of publication not identified], WILEY VCH, 2017
    identifier: (OCoLC)987899028
  identifier: 9783527674169
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  identifier: http://proxy.library.tamu.edu/login
  record info:
    record content source: N$T
    record creation date: 180214
    record change date: 20230110224246.2
    record identifier: in00004638892
    language of cataloging:
      language term: eng