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Surface and interface chemistry of clay minerals
Front Cover; Surface and Interface Chemistry of Clay Minerals; Copyright; Dedication; Contents; Contributors; Preface; Acknowledgements; Chapter 1: Clay minerals and their surfaces; 1.1. TO or 1:1 and TOT or 2:1 clay minerals; 1.2. Structural considerations; 1.3. Isomorphous substitution; 1.4. Consequences of isomorphous substitution; 1.4.1. Cation exchange; 1.4.2. Cation exchange capacity; 1.4.3. Intercalation and swelling; 1.5. Surfaces, surface areas, and surface sites; 1.6. Surface atoms; 1.7. Molecule-molecule and molecule-surface interactions; 1.7.1. Molecule-molecule interactions.
1.7.1.1. Ion-ion interactions1.7.1.2. Dipole-dipole interactions; 1.7.1.3. Charge-nonpolar interaction; 1.7.1.4. Dipolar-nonpolar interaction; 1.7.1.5. Nonpolar-nonpolar interactions; 1.7.1.6. H-bonding: X-H -- Y; 1.7.2. Molecule-surface and surface-surface interactions; References; Further reading; Chapter 2: Determination of surface areas and textural properties of clay minerals; 2.1. Introduction; 2.2. Nonswelling and nonmicroporous clay minerals; 2.3. Microporous clay minerals; 2.4. Swelling clay minerals; 2.4.1. The dry state.
2.4.1.1. Gas adsorption techniques using `classical adsorbates2.4.1.2. Adsorption techniques using polar adsorbates; 2.4.2. Swelling clay minerals dispersions; 2.5. Concluding remarks; References; Chapter 3: Quantum-chemical modelling of clay mineral surfaces and clay mineral-surface-adsorbate interactions; 3.1. Quantum mechanical description of interatomic interactions; 3.1.1. Hartree-Fock method; 3.1.2. Density functional theory; 3.1.3. Dispersion correction; 3.1.4. Basis set; 3.1.5. Effective core potentials; 3.1.6. System size and boundary conditions.
3.1.7. Structural optimisation and molecular dynamics simulations3.1.8. Ab initio spectroscopy; 3.2. Simulations of clay minerals structure; 3.2.1. Structure of TO/TOT layer and isomorphous substitutions; 3.2.2. Structure of hydroxyl layer in 1:1 clay minerals; 3.2.3. Structure of the interlayer and basal plane in 2:1 clay minerals; 3.3. Elastic properties of clay minerals; 3.4. Redox processes; 3.5. Interaction of clay minerals with organic compounds; 3.5.1. Natural organic matter and environmental engineering; 3.5.2. Organic contaminants; 3.5.3. Pillared organo-clay nanocomposites.
3.5.4. Interaction with petroleum molecules3.5.5. Adsorption of biomolecules; 3.6. Acid-base properties of edge surfaces and cation complexation; 3.6.1. Edge surface structures and surface pKa; 3.6.2. Metal complexation at edge sites; 3.7. Outlook; References; Chapter 4: Clay mineral-water interactions; 4.1. Introduction; 4.2. Water interactions with `neutral clay mineral surfaces; 4.2.1. Talc and pyrophyllite; 4.2.2. Kaolin group mineral; 4.2.2.1.1. Kaolinite; 4.2.2.1.2. Halloysite; 4.3. Water interactions with `charged clay mineral surfaces (ion-dipole); 4.3.1. Smectites.
edited by R. Schoonheydt, C.T. Johnston, F. Bergaya.
[Place of publication not identified] : Elsevier Ltd. : Elsevier, 2018