Bio-inspired polymers /
Many key aspects of life are based on naturally occurring polymers, such as polysaccharides, proteins and DNA. Unsurprisingly, their molecular functionalities, macromolecular structures and material properties are providing inspiration for designing new polymeric materials with specific functions, f...
| Other Authors: | , |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
[Cambridge, England] :
Royal Society of Chemistry,
2016.
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| Series: | RSC polymer chemistry series ;
22. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Cover; Contents; Preface; Chapter 1 Synthetic Aspects of Peptide- and Protein-Polymer Conjugates in the Post-click Era; 1.1 Introduction; 1.2 General Concepts for Bioconjugation; 1.3 Chemical Synthesis of Peptide- and Protein-Polymer Conjugates; 1.3.1 Coupling with Amines; 1.3.2 Coupling with Thiols; 1.3.3 Chemical Ligation by Oxime/Hydrazone Formation; 1.3.4 Staudinger Ligation; 1.3.5 Azide-Alkyne Cycloaddition; 1.3.6 Diels-Alder (DA) Cycloaddition Reactions; 1.3.7 Chemistry with 1,2,4-Triazoline-3,5-diones (TAD); 1.4 Chemoenzymatic Approaches
- 1.4.1 Transglutaminase (TGase) Catalyzed Ligation1.4.2 Sortase (Srt)-mediated Ligation; 1.4.3 Enzyme-induced Functional Group Modifications; 1.5 Biotransformations; 1.6 Conclusions and Future Perspectives; References; Chapter 2 Glycopolymers; 2.1 Introduction; 2.2 Synthesis of Glycopolymers; 2.2.1 Synthesis of Glycopolymers via Glycomonomers; 2.2.2 Synthesis of Glycopolymers via Post-polymerization Strategies; 2.2.3 Synthesis of Glyco- and Block Copolymers; 2.3 Analyzing Glycopolymers; 2.3.1 Multivalent Binding of Glycopolymers; 2.3.2 Binding Studies of Glycopolymers Targeting Lectins
- 2.4 Biomedical and Biotechnological Applications of Glycopolymers2.5 Conclusions; Acknowledgments; References; Chapter 3 Synthesis of Non-natural Polymers with Controlled Primary Structures; 3.1 Introduction; 3.2 Sequence-controlled Polymers Prepared by Chain-growth Polymerization; 3.2.1 Anionic Polymerization; 3.2.2 Cationic Polymerization; 3.2.3 Controlled Radical Polymerization; 3.2.4 Ring-opening Polymerization; 3.2.5 Ring-opening Metathesis Polymerization; 3.3 Sequence-controlled Polymers Prepared by Step-growth Polymerization; 3.3.1 Acyclic Diene Metathesis Polymerization
- 3.3.2 Click Step-growth Polymerization3.3.3 Other Step-growth Approaches; 3.3.4 Multicomponent Reactions; 3.4 Sequence-controlled Polymers Prepared by Multi-step-growth Polymerization; 3.4.1 Conventional Iterative Synthesis; 3.4.2 Protecting-group-free Iterative Synthesis; 3.4.3 Successive Radical Insertion; 3.4.4 Convergent and Divergent Strategies; 3.5 Use of Templates and Catalytic Molecular Machines; 3.5.1 Template-assisted Sequence-controlled Polymerization; 3.5.2 Rotaxane-based Catalytic Machines; 3.6 Outlook; References; Chapter 4 Single-chain Nanoparticles; 4.1 Introduction
- 4.2 Synthesis of SCNPs4.2.1 Covalent Cross-linking Reactions; 4.2.2 Dynamic Covalent Chemistry; 4.2.3 Non-covalent Chemistry; 4.2.4 Multiple Intra-chain Interactions; 4.2.5 Outlook; 4.3 Characterization of SCNPs; 4.3.1 Size Exclusion Chromatography; 4.3.2 Light Scattering; 4.3.3 Viscometry; 4.3.4 NMR Spectroscopy; 4.3.5 Characterizing the Morphology of SCNPs; 4.4 Potential Applications; 4.4.1 Catalysis; 4.4.2 Nano-medicine; 4.4.3 Chemical Sensors; 4.4.4 Self-assembly; 4.5 Summary and Outlook; Acknowledgments; References; Chapter 5 Polymeric Tubular Structures
- 5.1 Introduction
- Bio-inspiration