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Inorganic chemistry in aqueous solution /

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Bibliographic Details
Main Author: Barrett, Jack
Format: eBook
Language:English
Language Notes:English.
Published: Cambridge : Royal Society of Chemistry, 2003.
Series:Tutorial chemistry texts ; 21.
Subjects:
Chemistry, Inorganic.
Solution (Chemistry)
Chemistry.
Inorganic Chemistry.
Physical Sciences & Mathematics.
Science.
Electronic books.
Online Access:Connect to the full text of this electronic book
Table of Contents:
  • 1. WATER AND ITS SOLVENT PROPERTIES. Introduction
  • Liquid water
  • 2. LIQUID WATER AND THE HYDRATION OF IONS. The structure of liquid water
  • Ions and their hydration
  • Gibbs energies and enthalpies of formation of hydrated ions
  • Standard molar enthalpies of hydration of ions
  • The absolute value for the standard molar enthalpy of hydration of the proton
  • Absolute values of the standard molar enthalpies of hydration of ions
  • Standard molar entropies of hydration of ions
  • 3. ACIDS AND BASES; FORMS OF IONS IN AQUEOUS SOLUTION; ION HYDROLYSIS & COMPOUND SOLUBILITY. Acids and bases in aqueous solutions
  • Brønsted and Lowry acids and bases
  • pH and the pH scale
  • Factors influencing acidic and basic behaviour in aqueous solutions
  • Forms of ions in aqueous solution; hydrolysis
  • Solubilities of ionic compounds in water
  • 4. THERMODYNAMICS AND ELECTRODE POTENTIALS. Changes in standard Gibbs energy and their relation to standard electrode potentials
  • The hydrated electron and absolute values of reduction potentials
  • 5. THE STABILITIES OF IONS IN AQUEOUS SOLUTION. The limits of stability of ions in aqueous systems
  • Latimer and Volt-equivalent (Frost) diagrams
  • 6. PERIODICITY OF AQUEOUS CHEMISTRY I: S- AND P-BLOCK CHEMISTRY. Periodicity of the ions formed by the s- and p-block elements
  • The detailed aqueous chemistry of the s- and p-block elements
  • Summary of the s- and p-block periodicity
  • 7. PERIODICITY OF AQUEOUS CHEMISTRY II: D-BLOCK CHEMISTRY. The ions formed by the transition elements
  • Enthalpies of hydration of some transition element cations
  • Variations in the enthalpies of hydration of the +2 and +3 ions of the transition elements
  • Variations of ionic forms and redox behaviour across the first series of transition elements
  • General redox chemistry of the d-block elements
  • 8. PERIODICITY OF AQUEOUS CHEMISTRY III: F-BLOCK CHEMISTRY. The lanthanides
  • The actinides
  • Answers to problems
  • Subject index.