Metallomacrocycles : from structures to applications /
A comprehensive overview of metallomacrocycles from designing complex functional metallosupramolecular systems to their applications.
| Other Authors: | |
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| Format: | eBook |
| Language: | English |
| Published: |
Cambridge, England :
Royal Society of Chemistry,
[2019]
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| Series: | Monographs in supramolecular chemistry ;
no. 27. |
| Subjects: | |
| Online Access: | Connect to the full text of this electronic book |
Table of Contents:
- Cover; Metallomacrocycles: From Structures to Applications; Preface; Contents; Chapter 1
- Evolution of Metallomacrocycles From Macrocycles; 1.1 Macrocycles; 1.2 Coordination-driven Self-assembly; 1.3 Two-dimensional Assembly of Metallomacrocycles; 1.4 Characterization of Metallomacrocycles; 1.4.1 Mass Spectrometry; 1.4.2 X-ray Measurement; 1.5 The Essential Characteristic of Metallomacrocycles; 1.5.1 Charged Systems; 1.5.2 The Dynamic Characteristic of Metallomacrocycles; 1.6 Conclusion and Outlook; Acknowledgements; References.
- AcknowledgementsReferences; Chapter 4
- Self-assembled Chiral Metallomacrocycles; 4.1 Introduction; 4.2 Synthetic Strategies for Self-assembled Chiral Metallomacrocycles; 4.2.1 Introduction of Chiral Bridging Ligands; 4.2.2 Use of Chiral Metal Auxiliaries that Possess Chiral Capping Groups; 4.2.3 Use of Inherently Chiral Metal Centres Having Specific Coordination Geometries; 4.3 Applications of Self-assembled Chiral Metallomacrocycles; 4.3.1 Chiral Sensing; 4.3.2 Asymmetric Catalysis; 4.4 Conclusions; Acknowledgements; References.
- Chapter 2
- Design Principles of Self-assembled Metallomacrocycles2.1 Introduction; 2.2 The Directional-bonding Approach; 2.2.1 Molecular Rhomboids; 2.2.2 Molecular Triangles; 2.2.3 Molecular Squares; 2.2.4 Molecular Hexagons; 2.3 The Symmetry-interaction Approach; 2.4 The Weak-link Approach; 2.5 Conclusion; Acknowledgements; References; Chapter 3
- Self-organization in Coordination-driven Self-assembled Metallomacrocyles; 3.1 Introduction; 3.2 Two-component Self-organization Systems; 3.3 Three-component Self-organization Systems; 3.4 Multicomponent Self-organization Systems; 3.5 Conclusion.
- Chapter 5
- Half-sandwich Iridium- and Rhodium-based Organometallic MacrocyclesReferences; Chapter 6
- Supramolecular Transformations of Metallomacrocycles; 6.1 Introduction; 6.2 Supramolecular Transformations Between Metallomacrocycles and One-dimensional Metallosupramolecular Polymers; 6.3 Supramolecular Transformations Between Metallomacrocycles and Another Two-dimensional Metallomacrocycles; 6.4 Supramolecular Transformations Between Metallomacrocycles and 3D Metallocages; 6.5 Conclusion; Acknowledgements; References.
- Chapter 7
- Coordination-driven Self-assembly of Functionalized Self-assembled Metallomacrocycles7.1 Introduction; 7.1.1 Sites of Functionalization; 7.1.2 Pre- versus Post-self-assembly; 7.2 Photophysical Properties; 7.2.1 Introduction; 7.2.2 Covalently Append Dyes; 7.2.3 Sensor Applications; 7.2.4 Effects of Functional Groups on Photophysical Properties; 7.2.5 BODIPY-functionalized Metallomacrocycles; 7.3 Electrochemically Active Materials; 7.3.1 Introduction; 7.3.2 Functionalization with dppf Ligands; 7.3.3 Covalently Tethered Ferrocene; 7.3.4 Fc/Dendrimer Hybrid Materials.